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UNBICAT SIGNED

Unconventional Bifunctional Catalysts

Total Cost €

EC-Contrib. €

Partnership

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Outcomes and
results

UNBICAT project word cloud

Explore the words cloud of the UNBICAT project. It provides you a very rough idea of what is the project "UNBICAT" about.

activations reagents asymmetric activate context manner optimizing minimizing biologically central enriched constitutes neutral molecules literature synthesis free unconventional section worldwide incorporated substrate valuable library catalysis modern catalysts view compounds simultaneously societal electrophiles silyl organocatalysis sustainable photo waste suitable natural area demands activation progress solutions first dual desirable emerged privileged transformations explores chemically coordinate unknown bifunctional precedent enantio synthesize chemical environmental metal organocatalyst catalyst organocatalysts chemistry

Project "UNBICAT" data sheet

The following table provides information about the project.

Coordinator	UNIVERSIDAD AUTONOMA DE MADRID Organization address address: CALLE EINSTEIN 3 CIUDAD UNIV CANTOBLANCO RECTORADO city: MADRID postcode: 28049 website: http://www.uam.es contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.
Coordinator Country	Spain [ES]
Project website	http://www.uam.es/jose.aleman
Total cost	1˙987˙750 €
EC max contribution	1˙987˙750 € (100%)
Programme	1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
Code Call	ERC-2014-CoG
Funding Scheme	ERC-COG
Starting year	2015
Duration (year-month-day)	from 2015-09-01 to 2021-08-31

Partnership

Take a look of project's partnership.

#	participants	country	role	EC contrib. [€]
1	UNIVERSIDAD AUTONOMA DE MADRID UNIVERSIDAD AUTONOMA DE MADRID Organization address address: CALLE EINSTEIN 3 CIUDAD UNIV CANTOBLANCO RECTORADO city: MADRID postcode: 28049 website: http://www.uam.es contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	ES (MADRID)	coordinator	1˙987˙750.00

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Project objective

The development of sustainable chemical processes is one of the most important features in modern chemistry. It has become a key research area worldwide providing solutions to important societal demands by optimizing the use of natural resources and minimizing waste and environmental impact. Among the relevant methods for achieving this goal, catalysis represents a key and central approach. Both Organocatalysis and Metal Catalysis have emerged as solutions to the problems in this context. In this field, the progress of a novel bifunctional organocatalyst that could increase the number of different activations, and therefore the synthesis of valuable enantio-enriched molecules, would be highly desirable. Especially important, but still unknown, are the bifunctional-catalysts based on a Neutral Coordinate Organocatalyst and Photo-Organocatalysts. This proposal aims to develop two new unconventional approaches for the synthesis of bifunctional organocatalysts. The first one is based on the development of new Bifunctional Neutral Coordinate Organocatalyst and their application to the synthesis of biologically relevant compounds. I propose to use these bifunctional catalysts to promote the dual activation of silyl reagents and suitable electrophiles. This approach constitutes an unconventional way to synthesize asymmetric molecules and has no precedent in the literature. The second section of this proposal explores the photo-activation-bifunctional organocatalyst. I propose the design and application of new metal-free Bifunctional Photo-Organocatalysts which are able to chemically and photo-activate the substrate simultaneously in an asymmetric manner. This project has the potential to change the general view of asymmetric Neutral Coordinate Organocatalyst and Photo-catalysis as we know it today. These unconventional bifunctional would be incorporated into the privileged catalyst library for its applications in new asymmetric transformations.

Publications

List of publications.
year	authors and title	journal	last update
2017	Javier Luis-Barrera, VÃctor Laina-MartÃn, Thomas Rigotti, Francesca Peccati, Xavier Solans-Monfort, Mariona Sodupe, RubÃ©n Mas-BallestÃ©, Marta Liras, JosÃ© AlemÃ¡n Visible-Light Photocatalytic Intramolecular Cyclopropane Ring Expansion published pages: 7826-7830, ISSN: 1433-7851, DOI: 10.1002/anie.201703334	Angewandte Chemie International Edition 56/27	2019-10-14
2017	MarÃa Frias, RubÃ©n Mas-BallestÃ©, Saira Arias, Cuauhtemoc Alvarado, JosÃ© AlemÃ¡n Asymmetric Synthesis of Rauhutâ€“Currier type Products by a Regioselective Mukaiyama Reaction under Bifunctional Catalysis published pages: 672-679, ISSN: 0002-7863, DOI: 10.1021/jacs.6b07851	Journal of the American Chemical Society 139/2	2019-10-14
2018	Francisco Esteban, Wioleta CieÅ›lik, Enrique M. Arpa, Andrea Guerrero-Corella, Sergio DÃaz-Tendero, Josefina Perles, JosÃ© A. FernÃ¡ndez-Salas, Alberto Fraile, JosÃ© AlemÃ¡n Intramolecular Hydrogen Bond Activation: Thiourea-Organocatalyzed Enantioselective 1,3-Dipolar Cycloaddition of Salicylaldehyde-Derived Azomethine Ylides with Nitroalkenes published pages: 1884-1890, ISSN: 2155-5435, DOI: 10.1021/acscatal.7b03553	ACS Catalysis 8/3	2019-10-14
2016	Antonio Casado-SÃ¡nchez, RocÃo GÃ³mez-Ballesteros, Francisco Tato, Francisco J. Soriano, Gustavo Pascual-Coca, Silvia Cabrera, JosÃ© AlemÃ¡n Pt( ii ) coordination complexes as visible light photocatalysts for the oxidation of sulfides using batch and flow processes published pages: 9137-9140, ISSN: 1359-7345, DOI: 10.1039/C6CC02452A	Chem. Commun. 52/58	2019-10-14
2017	Andrea Guerrero-Corella, Ana MarÃa Martinez-Gualda, Fereshteh Ahmadi, Enrique Ming, Alberto Fraile, JosÃ© AlemÃ¡n Thiolâ€“ene/oxidation tandem reaction under visible light photocatalysis: synthesis of alkyl sulfoxides published pages: 10463-10466, ISSN: 1359-7345, DOI: 10.1039/C7CC05672A	Chemical Communications 53/75	2019-10-14
2018	JosÃ© AlemÃ¡n, Alberto Fraile, Andrea Guerrero, Francisco Esteban, Mario Parra, Manuel Iniesta, Ana Somer, Sergio Diaz-Tendero 2-Hydroxybenzophenone as Chemical Auxiliary for the Activation of Ketiminoesters in the Highly Enantioselective Addition to Nitroalkenes under Bifunctional Catalysis published pages: , ISSN: 1433-7851, DOI: 10.1002/anie.201800435	Angewandte Chemie International Edition	2019-10-14
2017	Alberto F. Garrido-Castro, Houcine Choubane, Mortada Daaou, M. Carmen Maestro, JosÃ© AlemÃ¡n Asymmetric radical alkylation of N-sulfinimines under visible light photocatalytic conditions published pages: 7764-7767, ISSN: 1359-7345, DOI: 10.1039/C7CC03724D	Chemical Communications 53/55	2019-10-14
2016	Vanesa Marcos, JosÃ© AlemÃ¡n Old tricks, new dogs: organocatalytic dienamine activation of Î±,Î²-unsaturated aldehydes published pages: 6812-6832, ISSN: 0306-0012, DOI: 10.1039/C6CS00438E	Chem. Soc. Rev. 45/24	2019-10-14

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