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MULTIPROSMM SIGNED

MULtiple PROperties Single Molecule Magnets

Total Cost €

EC-Contrib. €

Partnership

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MULTIPROSMM project word cloud

Explore the words cloud of the MULTIPROSMM project. It provides you a very rough idea of what is the project "MULTIPROSMM" about.

combines shaping silica polarized synthetic elaborate environment data cpl spincrossover trapping multiprosmm strategy lanthanide splitting sco isotopic smm liesst coupling dilutions chiral quantum optimizations internal light unprecedented magnetic regime sensitivity step playing enrichment cryogenic enhancement luminescence suitable spectroscopic stimuli designed mesoporous photography hyperfine coexistence nanoparticle storage intermediate magnet single final surfaces excited density multiple tool room decoration molecular circularly vanished molecule bistabilities energy ions performance temperature

Project "MULTIPROSMM" data sheet

The following table provides information about the project.

Coordinator	CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS Organization address address: RUE MICHEL ANGE 3 city: PARIS postcode: 75794 website: www.cnrs.fr contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.
Coordinator Country	France [FR]
Total cost	1˙505˙000 €
EC max contribution	1˙505˙000 € (100%)
Programme	1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
Code Call	ERC-2016-COG
Funding Scheme	ERC-COG
Starting year	2017
Duration (year-month-day)	from 2017-08-01 to 2022-07-31

Partnership

Take a look of project's partnership.

#	participants	country	role	EC contrib. [€]
1	CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS Organization address address: RUE MICHEL ANGE 3 city: PARIS postcode: 75794 website: www.cnrs.fr contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	FR (PARIS)	coordinator	1˙382˙500.00
2	EIDGENOESSISCHE TECHNISCHE HOCHSCHULE ZUERICH EIDGENOESSISCHE TECHNISCHE HOCHSCHULE ZUERICH Organization address address: Raemistrasse 101 city: ZUERICH postcode: 8092 website: https://www.ethz.ch/de.html contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	CH (ZUERICH)	participant	122˙500.00

Map

Project objective

The goal of the MULTIPROSMM project is to design systems able to present magnetic bistabilities under different stimuli (temperature, magnetic field or light) on an unprecedented large temperature range, i.e. very low temperature with Single Molecule Magnet (SMM) behaviour, intermediate temperature with Light Induced Excited State Trapping (LIESST) and high temperature with SpinCrossOver (SCO). On one hand, as a photography of the energy-splitting of the spectroscopic states, the lanthanide luminescence will be used as a key tool for the understanding of the magnetic properties of lanthanide ions. On the other hand, Circularly Polarized Luminescence (CPL) combines the sensitivity of the luminescence with crucial information on the chiral environment. A step by step synthetic strategy will be used to elaborate molecular systems in which the coexistence of i) SMM and SCO; ii) SMM and CPL and iii) SMM, SCO and CPL are operating. The enhancement of the magnetic properties is needed to step forward towards applications. To reach such optimizations, the quantum regime of the SMM and the internal magnetic field must be vanished playing with the hyperfine coupling and magnetic dilutions. Both isotopic enrichment and shaping (i.e. decoration of both mesoporous silica and nanoparticle surfaces) of the designed systems could allow high magnetic performance in multiple properties SMM. The final result could be a system suitable for very high density data storage on a wide temperature range (from cryogenic to room temperature).

Publications

List of publications.
year	authors and title	journal	last update
2019	Guglielmo Fernandez Garcia, Vincent Montigaud, Lucie Norel, Olivier Cador, Boris Le Guennic, Federico Totti, Fabrice Pointillart Redox-Active Dysprosium Single-Molecule Magnet: Spectro-Electrochemistry and Theoretical Investigations published pages: 46, ISSN: 2312-7481, DOI: 10.3390/magnetochemistry5030046	Magnetochemistry 5/3	2020-02-13
2020	Bertrand Lefeuvre, Jessica Flores Gonzalez, FrÃ©dÃ©ric Gendron, Vincent Dorcet, FranÃ§ois RiobÃ©, Vladimir Cherkasov, Olivier Maury, Boris Le Guennic, Olivier Cador, Viacheslav Kuropatov, Fabrice Pointillart Redox-Modulations of Photophysical and Single-molecule Magnet Properties in Ytterbium Complexes Involving Extended-TTF Triads published pages: 492, ISSN: 1420-3049, DOI: 10.3390/molecules25030492	Molecules 25/3	2020-02-13
2019	Olivier Cador, Boris Le Guennic, Fabrice Pointillart Electro-activity and magnetic switching in lanthanide-based single-molecule magnets published pages: 3398-3417, ISSN: 2052-1553, DOI: 10.1039/c9qi00875f	Inorganic Chemistry Frontiers 6/12	2020-02-13
2020	Olivier Cador, Boris Le Guennic, LahcÃ¨ne Ouahab, Fabrice Pointillart Decorated Tetrathiafulvalene-Based Ligands: Powerful Chemical Tools for the Design of Single-Molecule Magnets published pages: 148-164, ISSN: 1434-1948, DOI: 10.1002/ejic.201900981	European Journal of Inorganic Chemistry 2020/2	2020-02-13
2018	Bertrand Lefeuvre, Olivier Galangau, Jessica Flores Gonzalez, Vincent Montigaud, Vincent Dorcet, LahcÃ¨ne Ouahab, Boris Le Guennic, Olivier Cador, Fabrice Pointillart Field-Induced Dysprosium Single-Molecule Magnet Based on a Redox-Active Fused 1,10-Phenanthroline-Tetrathiafulvalene-1,10-Phenanthroline Bridging Triad published pages: , ISSN: 2296-2646, DOI: 10.3389/fchem.2018.00552	Frontiers in Chemistry 6	2019-10-08
2018	Haiet Douib, Louis Cornet, Jessica Flores Gonzalez, Elzbieta Trzop, Vincent Dorcet, Abdelkrim Gouasmia, LahcÃ¨ne Ouahab, Olivier Cador, Fabrice Pointillart Spin-Crossover and Field-Induced Single-Molecule Magnet Behaviour in Metal(II)-Dipyrazolylpyridine Complexes published pages: 4452-4457, ISSN: 1434-1948, DOI: 10.1002/ejic.201800819	European Journal of Inorganic Chemistry 2018/40	2019-10-08
2019	Balkaran Singh Sran, Jessica Flores Gonzalez, Vincent Montigaud, Boris Le Guennic, Fabrice Pointillart, Olivier Cador, Geeta Hundal Structural and magnetic investigations of a binuclear coordination compound of dysprosium( iii ) dinitrobenzoate published pages: , ISSN: 1477-9226, DOI: 10.1039/c8dt04253e	Dalton Transactions	2019-10-08
2019	FrÃ©dÃ©ric Gendron, Barry Moore II, Olivier Cador, Fabrice Pointillart, Jochen Autschbach, Boris Le Guennic Ab Initio Study of Circular Dichroism and Circularly Polarized Luminescence of Spin-Allowed and Spin-Forbidden Transitions: From Organic Ketones to Lanthanide Complexes published pages: 4140-4155, ISSN: 1549-9618, DOI: 10.1021/acs.jctc.9b00286	Journal of Chemical Theory and Computation 15/7	2019-09-02
2018	Jessica Flores Gonzalez, Vincent Montigaud, Nidal Saleh, Olivier Cador, Jeanne Crassous, Boris le Guennic, Fabrice Pointillart Slow Relaxation of the Magnetization in Bis-Decorated Chiral Helicene-Based Coordination Complexes of Lanthanides published pages: 39, ISSN: 2312-7481, DOI: 10.3390/magnetochemistry4030039	Magnetochemistry 4/3	2019-06-12
2018	Jessica Flores Gonzalez, Olivier Cador, LahcÃ¨ne Ouahab, Sergey Norkov, Viacheslav Kuropatov, Fabrice Pointillart Field-Induced Dysprosium Single-Molecule Magnet Involving a Fused o-Semiquinone-Extended-Tetrathiafulvalene-o-Semiquinone Bridging Triad published pages: 45, ISSN: 2304-6740, DOI: 10.3390/inorganics6020045	Inorganics 6/2	2019-06-12
2019	Olivier Galangau, Vincent Montigaud, Jessica Flores Gonzalez, Bertrand Lefeuvre, Vincent Dorcet, Boris Le Guennic, Olivier Cador, LahcÃ¨ne Ouahab, Fabrice Pointillart N3O6 versus N2O6 Coordinated Dysprosium Slow Magnetic Relaxation in a Tetrathiafulvalene-Based Dinuclear Complex published pages: , ISSN: 0277-5387, DOI: 10.1016/j.poly.2019.04.029	Polyhedron	2019-06-06
2019	Jessica Flores Gonzalez, Fabrice Pointillart, Olivier Cador Hyperfine coupling and slow magnetic relaxation in isotopically enriched Dy III mononuclear single-molecule magnets published pages: 1081-1086, ISSN: 2052-1553, DOI: 10.1039/c8qi01209a	Inorganic Chemistry Frontiers 6/4	2019-06-06
2018	Fabrice Pointillart, Jiang-Kun Ou-Yang, Guglielmo Fernandez Garcia, Vincent Montigaud, Jessica Flores Gonzalez, RÃ©mi Marchal, Ludovic Favereau, Federico Totti, Jeanne Crassous, Olivier Cador, LahcÃ¨ne Ouahab, Boris Le Guennic Tetrathiafulvalene-Based Helicene Ligand in the Design of a Dysprosium Field-Induced Single-Molecule Magnet published pages: , ISSN: 0020-1669, DOI: 10.1021/acs.inorgchem.8b02830	Inorganic Chemistry	2019-04-25

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