OrganoMag
Organometallic Single-Molecule Magnets
Total Cost €
0EC-Contrib. €
0Partnership
0Views
0OrganoMag project word cloud
Explore the words cloud of the OrganoMag project. It provides you a very rough idea of what is the project "OrganoMag" about.
Project "OrganoMag" data sheet
The following table provides information about the project.
| Coordinator |
THE UNIVERSITY OF MANCHESTER
Organization address contact info |
| Coordinator Country | United Kingdom [UK] |
| Project website | http://orcid.org/0000-0001-7190-4160 |
| Total cost | 183˙454 € |
| EC max contribution | 183˙454 € (100%) |
| Programme |
1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility) |
| Code Call | H2020-MSCA-IF-2014 |
| Funding Scheme | MSCA-IF-EF-ST |
| Starting year | 2015 |
| Duration (year-month-day) | from 2015-10-01 to 2017-09-30 |
Partnership
Take a look of project's partnership.
| # | ||||
|---|---|---|---|---|
| 1 | THE UNIVERSITY OF MANCHESTER | UK (MANCHESTER) | coordinator | 183˙454.00 |
Map
Project objective
In this project, we will develop new single-molecule magnets (SMMs) that combine the strong magnetic anisotropy of lanthanide ions with a series of novel radical ligands. Highly unusual di- and tri-metallic Ln-SMMs are proposed in which the metals are bridged by radicals with heavy Group 15 donor atoms (i.e. the pnictogens, phosphorus-bismuth). The SMM field is dominated by systems with diamagnetic ligands: our radical ligands are novel, hence their applications in single-molecule magnetism will be unprecedented. We will exploit the rich electrochemistry of the proposed ligands: our DFT calculations show that the target heavy pnictogen radical anions have huge spin densities on the donor atoms, hence the diffuse unpaired spin of the radicals will provide a way of switching off the quantum tunnelling mechanisms that otherwise prevent hysteresis. Ultimately, this project introduces the potential for creating SMMs that show hysteresis at unprecedentedly high temperatures.
Publications
| year | authors and title | journal | last update |
|---|---|---|---|
| 2017 |
Fu-Sheng Guo, Richard A. Layfield Strong direct exchange coupling and single-molecule magnetism in indigo-bridged lanthanide dimers published pages: 3130-3133, ISSN: 1359-7345, DOI: 10.1039/c7cc01046j |
Chemical Communications 53/21 | 2019-09-30 |
| 2017 |
Fu-Sheng Guo, Benjamin M. Day, Yan-Cong Chen, Ming-Liang Tong, Akseli Mansikkamäki, Richard A. Layfield A Dysprosium Metallocene Single-Molecule Magnet Functioning at the Axial Limit published pages: 11445-11449, ISSN: 1433-7851, DOI: 10.1002/anie.201705426 |
Angewandte Chemie International Edition 56/38 | 2019-09-30 |
Are you the coordinator (or a participant) of this project? Plaese send me more information about the "ORGANOMAG" project.
For instance: the website url (it has not provided by EU-opendata yet), the logo, a more detailed description of the project (in plain text as a rtf file or a word file), some pictures (as picture files, not embedded into any word file), twitter account, linkedin page, etc.
Send me an email (fabio@fabiodisconzi.com) and I put them in your project's page as son as possible.
Thanks. And then put a link of this page into your project's website.
The information about "ORGANOMAG" are provided by the European Opendata Portal: CORDIS opendata.