Explore the words cloud of the ELICOS project. It provides you a very rough idea of what is the project "ELICOS" about.
The following table provides information about the project.
Coordinator |
TECHNISCHE UNIVERSITAET MUENCHEN
Organization address contact info |
Coordinator Country | Germany [DE] |
Total cost | 2˙357˙901 € |
EC max contribution | 2˙357˙901 € (100%) |
Programme |
1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC)) |
Code Call | ERC-2014-ADG |
Funding Scheme | ERC-ADG |
Starting year | 2016 |
Duration (year-month-day) | from 2016-01-01 to 2020-12-31 |
Take a look of project's partnership.
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1 | TECHNISCHE UNIVERSITAET MUENCHEN | DE (MUENCHEN) | coordinator | 2˙357˙901.00 |
Photochemical reactions are induced by ultraviolet or visible light and they enable the construction of molecular skeletons that are difficult or even impossible to access by any other means. In order to secure a widespread application of these reactions in organic synthesis and in order to make the respective products available for high-tech applications, it is required that photochemical reactions can be performed enantioselectively, i.e. that the three-dimensional architecture of the product molecules is unambiguously defined. Despite some progress in recent years, this challenge has as yet remained unsolved. It is the objective of this proposal to develop catalytic methods that allow the enantioselective synthesis of a broad variety of compound classes by light-induced reactions. The mode of action of potential catalysts is based on energy transfer or on wavelength-selective excitation. In the former scenario, the substrate-catalyst complex will be held together by non-covalent interactions, which position the substrate for an efficient energy transfer and for an enantioselective approach of the reagent. In the latter approach, acid-base interactions in the substrate-catalyst complex will lead to a significant bathochromic absorption shift of the substrate, enabling a selective excitation within the complex and a subsequent enantioselective reaction pathway within a spatially defined chiral environment. Both approaches include the option to employ sunlight as the exclusive energy source to drive enantioselective processes without the need to apply external heat or pressure.
year | authors and title | journal | last update |
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2016 |
Florian Mayr, Richard Brimioulle, Thorsten Bach A Chiral Thiourea as a Template for Enantioselective Intramolecular [2 + 2] Photocycloaddition Reactions published pages: 6965-6971, ISSN: 0022-3263, DOI: 10.1021/acs.joc.6b01039 |
The Journal of Organic Chemistry 81/16 | 2019-07-02 |
2017 |
Thorsten Bach, Florian Mayr, Lisa-Marie Mohr, Elsa Rodriguez Synthesis of Chiral Thiourea-Thioxanthone Hybrids published pages: 5238-5250, ISSN: 0039-7881, DOI: 10.1055/s-0036-1590931 |
Synthesis 49/23 | 2019-07-02 |
2017 |
Thorsten Bach, Lisa-Marie Mohr Intermolecular [2+2] Photocycloaddition of β-Nitrostyrenes to Olefins upon Irradiation with Visible Light published pages: 2946-2950, ISSN: 0936-5214, DOI: 10.1055/s-0036-1588524 |
Synlett 28/20 | 2019-07-02 |
2018 |
Christoph Brenninger, Thorsten Bach α-Thio Carbocations (Thionium Ions) as Intermediates in Brønsted Acid-Catalyzed Reactions of Enone-Derived 1,3-Dithianes and 1,3-Dithiolanes published pages: 623-629, ISSN: 1022-5528, DOI: 10.1007/s11244-018-0905-6 |
Topics in Catalysis 61/7-8 | 2019-07-02 |
2018 |
Fabian M. Hörmann, Tim S. Chung, Elsa Rodriguez, Matthias Jakob, Thorsten Bach Evidence for Triplet Sensitization in the Visible-Light-Induced [2+2] Photocycloaddition of Eniminium Ions published pages: 827-831, ISSN: 1433-7851, DOI: 10.1002/anie.201710441 |
Angewandte Chemie International Edition 57/3 | 2019-07-02 |
2018 |
Saner Poplata, Thorsten Bach Enantioselective Intermolecular [2+2] Photocycloaddition Reaction of Cyclic Enones and Its Application in a Synthesis of (−)-Grandisol published pages: 3228-3231, ISSN: 0002-7863, DOI: 10.1021/jacs.8b01011 |
Journal of the American Chemical Society 140/9 | 2019-07-02 |
2016 |
Saner Poplata, Andreas Tröster, You-Quan Zou, Thorsten Bach Recent Advances in the Synthesis of Cyclobutanes by Olefin [2 + 2] Photocycloaddition Reactions published pages: 9748-9815, ISSN: 0009-2665, DOI: 10.1021/acs.chemrev.5b00723 |
Chemical Reviews 116/17 | 2019-07-02 |
2018 |
Christoph Brenninger, John D. Jolliffe, Thorsten Bach Chromophore Activation of α,β-Unsaturated Carbonyl Compounds and Its Application to Enantioselective Photochemical Reactions published pages: 14338-14349, ISSN: 1433-7851, DOI: 10.1002/anie.201804006 |
Angewandte Chemie International Edition 57/44 | 2019-07-02 |
2017 |
Christoph Brenninger, Alexander Pöthig, Thorsten Bach Brønsted Acid Catalysis in Visible-Light-Induced [2+2] Photocycloaddition Reactions of Enone Dithianes published pages: 4337-4341, ISSN: 1433-7851, DOI: 10.1002/anie.201700837 |
Angewandte Chemie International Edition 56/15 | 2019-07-02 |
2018 |
Sachin G. Modha, Alexander Pöthig, Andreas Dreuw, Thorsten Bach [6π] Photocyclization to cis -Hexahydrocarbazol-4-ones: Substrate Modification, Mechanism, and Scope published pages: 1139-1153, ISSN: 0022-3263, DOI: 10.1021/acs.joc.8b03144 |
The Journal of Organic Chemistry 84/3 | 2019-03-25 |
2018 |
Simone Stegbauer, Christian Jandl, Thorsten Bach Enantioselective Lewis Acid Catalyzed ortho Photocycloaddition of Olefins to Phenanthrene-9-carboxaldehydes published pages: 14593-14596, ISSN: 1433-7851, DOI: 10.1002/anie.201808919 |
Angewandte Chemie International Edition 57/44 | 2019-03-25 |
2017 |
Verena Edtmüller, Alexander Pöthig, Thorsten Bach Enantioselective photocyclisation reactions of 2-aryloxycyclohex-2-enones mediated by a chiral copper-bisoxazoline complex published pages: 5037-5048, ISSN: 0040-4020, DOI: 10.1016/j.tet.2017.05.005 |
Tetrahedron 73/33 | 2019-07-02 |
2018 |
You-Quan Zou, Fabian M. Hörmann, Thorsten Bach Iminium and enamine catalysis in enantioselective photochemical reactions published pages: 278-290, ISSN: 0306-0012, DOI: 10.1039/c7cs00509a |
Chemical Society Reviews 47/2 | 2019-07-02 |
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