Explore the words cloud of the SUSCAT project. It provides you a very rough idea of what is the project "SUSCAT" about.
The following table provides information about the project.
Coordinator |
WEIZMANN INSTITUTE OF SCIENCE
Organization address contact info |
Coordinator Country | Israel [IL] |
Project website | http://www.weizmann.ac.il/Organic_Chemistry/milstein/ |
Total cost | 2˙497˙975 € |
EC max contribution | 2˙497˙975 € (100%) |
Programme |
1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC)) |
Code Call | ERC-2015-AdG |
Funding Scheme | ERC-ADG |
Starting year | 2016 |
Duration (year-month-day) | from 2016-07-01 to 2021-06-30 |
Take a look of project's partnership.
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1 | WEIZMANN INSTITUTE OF SCIENCE | IL (REHOVOT) | coordinator | 2˙497˙975.00 |
The discovery of novel sustainable catalytic reactions is a major current goal. Based on recent discoveries in our group, we plan to develop unprecedented sustainable catalytic reactions with special emphasis on reactions catalyzed by complexes of earth-abundant metals. We have recently discovered an intriguing reaction, namely the oxidation of organic compounds using water, with no added oxidant, evolving H2. This simple, selective reaction, offers now a novel, conceptually new, environmentally benign approach in the field of oxidation of organic compounds, which we will explore.
We recently discovered a new mode of activation of multiple bonds by metal-ligand cooperation, including activation of CO2 and nitrile triple bonds, in which reversible C-C bond formation with the ligand is involved. Based on that, activation of nitriles has resulted in unprecedented C-C bond formation involving addition of simple aliphatic nitriles to various α,β-unsaturated carbonyl compounds. This mode of multiple bond activation may open a new approach to catalysis, “template catalysis”, which we plan to explore. In addition, the highly desirable, catalytic activation of the kinetically very stable, potent greenhouse gas N2O for the (so far elusive), efficient oxygen transfer to organic compounds, will be pursued. The use of CO2 in organic synthesis is an important timely topic. Based on its activation by metal ligand cooperation, new catalytic reactions of CO2 will be pursued, including unprecedented carbonylation of non-activated C-H bonds. Most reactions catalysed by metal complexes involve noble metals. Development of sustainable catalysis based on complexes of earth-abundant metals is of great interest. In all topics described above, catalysis by complexes of such metals will be emphasized. Moreover, based on recent results in our group, we plan to develop an unprecedented family of complexes of earth-abundant metals, and pursue novel sustainable catalysis, based on it.
year | authors and title | journal | last update |
---|---|---|---|
2016 |
Jonathan O. Bauer, Gregory Leitus, Yehoshoa Ben-David, David Milstein Direct Synthesis of Symmetrical Azines from Alcohols and Hydrazine Catalyzed by a Ruthenium Pincer Complex: Effect of Hydrogen Bonding published pages: 8415-8419, ISSN: 2155-5435, DOI: 10.1021/acscatal.6b02946 |
ACS Catalysis 6/12 | 2019-06-14 |
2017 |
Alexander Dauth, Urs Gellrich, Yael Diskin-Posner, Yehoshoa Ben-David, David Milstein The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity published pages: 2799-2807, ISSN: 0002-7863, DOI: 10.1021/jacs.6b13050 |
Journal of the American Chemical Society 139/7 | 2019-06-14 |
2017 |
Rong Zeng, Moran Feller, Yehoshoa Ben-David, David Milstein Hydrogenation and Hydrosilylation of Nitrous Oxide Homogeneously Catalyzed by a Metal Complex published pages: 5720-5723, ISSN: 0002-7863, DOI: 10.1021/jacs.7b02124 |
Journal of the American Chemical Society 139/16 | 2019-06-14 |
2017 |
Amit Kumar, Noel Angel Espinosa-Jalapa, Gregory Leitus, Yael Diskin-Posner, Liat Avram, David Milstein Direct Synthesis of Amides by Dehydrogenative Coupling of Amines with either Alcohols or Esters: Manganese Pincer Complex as Catalyst published pages: 14992-14996, ISSN: 1433-7851, DOI: 10.1002/anie.201709180 |
Angewandte Chemie International Edition 56/47 | 2019-06-05 |
2018 |
Uttam Kumar Das, Yehoshoa Ben-David, Yael Diskin-Posner, David Milstein N-Substituted Hydrazones by Manganese-Catalyzed Coupling of Alcohols with Hydrazine: Borrowing Hydrogen and Acceptorless Dehydrogenation in One System published pages: 2179-2182, ISSN: 1433-7851, DOI: 10.1002/anie.201712593 |
Angewandte Chemie International Edition 57/8 | 2019-06-05 |
2018 |
Prosenjit Daw, Amit Kumar, Noel Angel Espinosa-Jalapa, Yael Diskin-Posner, Yehoshoa Ben-David, David Milstein Synthesis of Pyrazines and Quinoxalines via Acceptorless Dehydrogenative Coupling Routes Catalyzed by Manganese Pincer Complexes published pages: 7734-7741, ISSN: 2155-5435, DOI: 10.1021/acscatal.8b02208 |
ACS Catalysis 8/9 | 2019-06-05 |
2017 |
Subrata Chakraborty, Uttam Kumar Das, Yehoshoa Ben-David, David Milstein Manganese Catalyzed α-Olefination of Nitriles by Primary Alcohols published pages: 11710-11713, ISSN: 0002-7863, DOI: 10.1021/jacs.7b06993 |
Journal of the American Chemical Society 139/34 | 2019-06-05 |
2018 |
Uttam Kumar Das, Subrata Chakraborty, Yael Diskin-Posner, David Milstein Direct Conversion of Alcohols into Alkenes by Dehydrogenative Coupling with Hydrazine/Hydrazone Catalyzed by Manganese published pages: 13444-13448, ISSN: 1433-7851, DOI: 10.1002/anie.201807881 |
Angewandte Chemie International Edition 57/41 | 2019-06-05 |
2018 |
Amit Kumar, Moran Feller, Yehoshoa Ben-David, Yael Diskin-Posner, David Milstein Formal oxidative addition of a C–H bond by a 16e iridium( i ) complex involves metal–ligand cooperation published pages: 5365-5368, ISSN: 1359-7345, DOI: 10.1039/c8cc01885e |
Chemical Communications 54/42 | 2019-06-05 |
2018 |
Subrata Chakraborty, Prosenjit Daw, Yehoshoa Ben David, David Milstein Manganese-Catalyzed α-Alkylation of Ketones, Esters, and Amides Using Alcohols published pages: 10300-10305, ISSN: 2155-5435, DOI: 10.1021/acscatal.8b03720 |
ACS Catalysis 8/11 | 2019-06-05 |
2018 |
You-Quan Zou, Subrata Chakraborty, Alexander Nerush, Dror Oren, Yael Diskin-Posner, Yehoshoa Ben-David, David Milstein Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal–Ligand Cooperation published pages: 8014-8019, ISSN: 2155-5435, DOI: 10.1021/acscatal.8b02902 |
ACS Catalysis 8/9 | 2019-06-05 |
2017 |
Jonathan O. Bauer, Subrata Chakraborty, David Milstein Manganese-Catalyzed Direct Deoxygenation of Primary Alcohols published pages: 4462-4466, ISSN: 2155-5435, DOI: 10.1021/acscatal.7b01729 |
ACS Catalysis 7/7 | 2019-06-05 |
2017 |
Uttam Kumar Das, Linda J. W. Shimon, David Milstein Imidazole synthesis by transition metal free, base-mediated deaminative coupling of benzylamines and nitriles published pages: 13133-13136, ISSN: 1359-7345, DOI: 10.1039/c7cc08322j |
Chemical Communications 53/98 | 2019-06-05 |
2018 |
Moran Feller, Eyal Ben-Ari, Yael Diskin-Posner, David Milstein CO 2 activation by metal − ligand-cooperation mediated by iridium pincer complexes published pages: 1679-1689, ISSN: 0095-8972, DOI: 10.1080/00958972.2018.1475662 |
Journal of Coordination Chemistry 71/11-13 | 2019-06-05 |
2017 |
Prosenjit Daw, Yehoshoa Ben-David, David Milstein Direct Synthesis of Benzimidazoles by Dehydrogenative Coupling of Aromatic Diamines and Alcohols Catalyzed by Cobalt published pages: 7456-7460, ISSN: 2155-5435, DOI: 10.1021/acscatal.7b02777 |
ACS Catalysis 7/11 | 2019-06-05 |
2018 |
Amit Kumar, Trevor Janes, Noel Angel Espinosa-Jalapa, David Milstein Selective Hydrogenation of Cyclic Imides to Diols and Amines and Its Application in the Development of a Liquid Organic Hydrogen Carrier published pages: 7453-7457, ISSN: 0002-7863, DOI: 10.1021/jacs.8b04581 |
Journal of the American Chemical Society 140/24 | 2019-06-05 |
2017 |
Noel Angel Espinosa-Jalapa, Amit Kumar, Gregory Leitus, Yael Diskin-Posner, David Milstein Synthesis of Cyclic Imides by Acceptorless Dehydrogenative Coupling of Diols and Amines Catalyzed by a Manganese Pincer Complex published pages: 11722-11725, ISSN: 0002-7863, DOI: 10.1021/jacs.7b08341 |
Journal of the American Chemical Society 139/34 | 2019-06-05 |
2018 |
Dror Oren, Yael Diskin-Posner, Liat Avram, Moran Feller, David Milstein Metal–Ligand Cooperation as Key in Formation of Dearomatized Ni II –H Pincer Complexes and in Their Reactivity toward CO and CO 2 published pages: 2217-2221, ISSN: 0276-7333, DOI: 10.1021/acs.organomet.8b00160 |
Organometallics 37/14 | 2019-06-05 |
2018 |
Amit Kumar, Trevor Janes, Noel Angel Espinosa-Jalapa, David Milstein Manganese Catalyzed Hydrogenation of Organic Carbonates to Methanol and Alcohols published pages: 12076-12080, ISSN: 1433-7851, DOI: 10.1002/anie.201806289 |
Angewandte Chemie International Edition 57/37 | 2019-06-05 |
2017 |
Subrata Chakraborty, David Milstein Selective Hydrogenation of Nitriles to Secondary Imines Catalyzed by an Iron Pincer Complex published pages: 3968-3972, ISSN: 2155-5435, DOI: 10.1021/acscatal.7b00906 |
ACS Catalysis 7/6 | 2019-06-05 |
2018 |
Rong Zeng, Moran Feller, Yael Diskin-Posner, Linda J. W. Shimon, Yehoshoa Ben-David, David Milstein CO Oxidation by N 2 O Homogeneously Catalyzed by Ruthenium Hydride Pincer Complexes Indicating a New Mechanism published pages: 7061-7064, ISSN: 0002-7863, DOI: 10.1021/jacs.8b03927 |
Journal of the American Chemical Society 140/23 | 2019-06-05 |
2018 |
Arup Mukherjee, David Milstein Homogeneous Catalysis by Cobalt and Manganese Pincer Complexes published pages: 11435-11469, ISSN: 2155-5435, DOI: 10.1021/acscatal.8b02869 |
ACS Catalysis 8/12 | 2019-06-05 |
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