Explore the words cloud of the 2O2ACTIVATION project. It provides you a very rough idea of what is the project "2O2ACTIVATION" about.
The following table provides information about the project.
Coordinator |
RHEINISCH-WESTFAELISCHE TECHNISCHE HOCHSCHULE AACHEN
Organization address contact info |
Coordinator Country | Germany [DE] |
Total cost | 1˙489˙822 € |
EC max contribution | 1˙489˙822 € (100%) |
Programme |
1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC)) |
Code Call | ERC-2016-STG |
Funding Scheme | ERC-STG |
Starting year | 2017 |
Duration (year-month-day) | from 2017-03-01 to 2022-02-28 |
Take a look of project's partnership.
# | ||||
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1 | RHEINISCH-WESTFAELISCHE TECHNISCHE HOCHSCHULE AACHEN | DE (AACHEN) | coordinator | 1˙080˙832.00 |
2 | TECHNISCHE UNIVERSITAET KAISERSLAUTERN | DE (KAISERSLAUTERN) | participant | 408˙989.00 |
The field of C-H bond activation has evolved at an exponential pace in the last 15 years. What appeals most in those novel synthetic techniques is clear: they bypass the pre-activation steps usually required in traditional cross-coupling chemistry by directly metalating C-H bonds. Many C-H bond functionalizations today however, rely on poorly atom and step efficient oxidants, leading to significant and costly chemical waste, thereby seriously undermining the overall sustainability of those methods. As restrictions in sustainability regulations will further increase, and the cost of certain chemical commodities will rise, atom efficiency in organic synthesis remains a top priority for research.
The aim of 2O2ACTIVATION is to develop novel technologies utilizing O2 as sole terminal oxidant in order to allow useful, extremely sustainable, thermodynamically challenging, dehydrogenative C-N and C-O bond forming coupling reactions. However, the moderate reactivity of O2 towards many catalysts constitutes a major challenge. 2O2ACTIVATION will pioneer the design of new catalysts based on the ultra-simple propene motive, capable of direct activation of O2 for C-H activation based cross-couplings. The project is divided into 3 major lines: O2 activation using propene and its analogues (propenoids), 1) without metal or halide, 2) with hypervalent halide catalysis, 3) with metal catalyzed C-H activation. The philosophy of 2O2ACTIVATION is to focus C-H functionalization method development on the oxidative event.
Consequently, 2O2ACTIVATION breakthroughs will dramatically shortcut synthetic routes through the use of inactivated, unprotected, and readily available building blocks; and thus should be easily scalable. This will lead to a strong decrease in the costs related to the production of many essential chemicals, while preserving the environment (water as terminal by-product). The resulting novels coupling methods will thus have a lasting impact on the chemical industry.
year | authors and title | journal | last update |
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2019 |
Christian K. Rank, Alexander W. Jones, Tatjana Wall, Patrick Di Martino-Fumo, Sarah Schröck, Markus Gerhards, Frederic W. Patureau An intermolecular C–H oxidizing strategy to access highly fused carbazole skeletons from simple naphthylamines published pages: , ISSN: 1359-7345, DOI: 10.1039/c9cc05240b |
Chemical Communications | 2019-11-07 |
2019 |
Congjun Yu, Frederic W. Patureau Regioselective Oxidative Arylation of Fluorophenols published pages: , ISSN: 1433-7851, DOI: 10.1002/anie.201910352 |
Angewandte Chemie International Edition | 2019-11-07 |
2019 |
Frederic W. Patureau The Phenol-Phenothiazine Coupling: an Oxidative Click Concept published pages: , ISSN: 1867-3880, DOI: 10.1002/cctc.201900152 |
ChemCatChem | 2019-10-08 |
2018 |
Annika Bernhardt, Harald Kelm, Frederic W. Patureau The Strong β−CF 3 Shielding Effect in Hexafluoroisopropanol and 100 Other Organic Solvents Revisited with 17 O NMR Spectroscopy published pages: 1547-1551, ISSN: 1867-3880, DOI: 10.1002/cctc.201701721 |
ChemCatChem 10/7 | 2019-06-13 |
2018 |
Rongwei Jin, Christina L. Bub, Frederic W. Patureau Phenothiazinimides: Atom-Efficient Electrophilic Amination Reagents published pages: 2884-2887, ISSN: 1523-7060, DOI: 10.1021/acs.orglett.8b00914 |
Organic Letters 20/10 | 2019-06-13 |
2017 |
A. Malekafzali, K. Malinovska, F. W. Patureau The cumene/O 2 system: a very simple tool for the radical chain oxidation of some functional groups published pages: 6981-6985, ISSN: 1144-0546, DOI: 10.1039/C7NJ01666B |
New Journal of Chemistry 41/15 | 2019-06-13 |
2018 |
Alexander W. Jones, Christian K. Rank, Yanik Becker, Christian Malchau, Ignacio Funes-Ardoiz, Feliu Maseras, Frederic W. Patureau Accelerated Ru-Cu Trinuclear Cooperative C−H Bond Functionalization of Carbazoles: A Kinetic and Computational Investigation published pages: , ISSN: 0947-6539, DOI: 10.1002/chem.201802886 |
Chemistry - A European Journal | 2019-06-13 |
2018 |
Monalisa Goswami, Alexander Konkel, Maryam Rahimi, Marie-Laure Louillat-Habermeyer, Harald Kelm, Rongwei Jin, Bas de Bruin, Frederic W. Patureau Mechanism of the Dehydrogenative Phenothiazination of Phenols published pages: 11936-11943, ISSN: 0947-6539, DOI: 10.1002/chem.201800730 |
Chemistry - A European Journal 24/46 | 2019-06-13 |
2018 |
Congjun Yu, Frederic W. Patureau Cu-Catalyzed Cross-Dehydrogenative ortho -Aminomethylation of Phenols published pages: 11807-11811, ISSN: 1433-7851, DOI: 10.1002/anie.201804829 |
Angewandte Chemie International Edition 57/36 | 2019-06-13 |
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