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CREATE SIGNED

Critical Raw materials Elimination by a top-down Approach To hydrogen and Electricity generation

Total Cost €

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EC-Contrib. €

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Partnership

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Project "CREATE" data sheet

The following table provides information about the project.

Coordinator
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS 

Organization address
address: RUE MICHEL ANGE 3
city: PARIS
postcode: 75794
website: www.cnrs.fr

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country France [FR]
 Project website http://www.create-energy-h2020.eu/
 Total cost 4˙480˙978 €
 EC max contribution 4˙318˙478 € (96%)
 Programme 1. H2020-EU.2.1.3. (INDUSTRIAL LEADERSHIP - Leadership in enabling and industrial technologies - Advanced materials)
 Code Call H2020-NMBP-2016-two-stage
 Funding Scheme RIA
 Starting year 2017
 Duration (year-month-day) from 2017-01-01   to  2020-06-30

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS FR (PARIS) coordinator 598˙123.00
2    TECHNION - ISRAEL INSTITUTE OF TECHNOLOGY IL (HAIFA) participant 699˙423.00
3    FUMATECH BWT GMBH DE (BIETIGHEIM BISSINGEN) participant 512˙375.00
4    AALTO KORKEAKOULUSAATIO SR FI (ESPOO) participant 474˙588.00
5    FORSCHUNGSZENTRUM JULICH GMBH DE (JULICH) participant 451˙551.00
6    UNIVERSITA DEGLI STUDI DI ROMA TOR VERGATA IT (ROMA) participant 403˙750.00
7    ITM POWER (TRADING) LIMITED UK (SHEFFIELD) participant 374˙200.00
8    EIFER EUROPAISCHES INSTITUT FUR ENERGIEFORSCHUNG EDF KIT EWIV DE (KARLSRUHE) participant 365˙781.00
9    FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA ES (TARRAGONA) participant 350˙625.00
10    PRETEXO FR (MONTPELLIER) participant 88˙059.00
11    NORTHEASTERN UNIVERSITY US (BOSTON MA) participant 0.00

Map

 Project objective

CREATE aims at developing innovative membrane electrode assemblies for low-temperature polymer-electrolyte fuel cell (FC) and electrolyzer (EL) with much reduced cost. This will be achieved via elimination or drastic reduction of critical raw materials in their catalysts, in particular platinum group metals (PGM).

Key issues with present low-temperature FC & EL are the high contents of PGM in devices based on proton-exchange-membrane (PEM) and the need for liquid electrolytes in alkaline FC and EL. To overcome this, we will shift from PEM-based cells to 1) pure anion-conducting polymer-electrolytes and 2) to bipolar-membrane polymer electrolytes. The latter comprises anion and proton conducting ionomers and a junction. Bipolar membranes allow adapting the pH at each electrode, thereby opening the door to improved performance or PGM-free catalysts. Both strategies carry the potentiality to eliminate or drastically reduce the need for PGM while maintaining the advantages of PEM-based devices.

In strategy 1, novel anion-exchange ionomers and membranes will be developed and interfaced with catalysts based on Earth-abundant metal oxides or metal-carbon composites for the oxygen reactions, and with ultralow PGM or PGM-free catalysts for the hydrogen reactions.

In strategy 2, novel bipolar membrane designs, or designs unexplored for FC & EL, will be developed and interfaced with catalysts for the oxygen reactions (high pH side of the bipolar membrane) and with catalysts for the hydrogen reactions (low pH side). The ionomers and oxygen reaction catalysts developed in strategy 1 will be equally useful for strategy 2, while identified PGM-free and ultralow-PGM catalysts will be implemented for the hydrogen reactions on the acidic side.

Polymer-electrolyte FC & EL based on those concepts will be evaluated for targeted applications, i.e. photovoltaic electricity storage, off-grid back-up power and H2 production. The targeted market is distributed small-scale systems.

 Deliverables

List of deliverables.
First generation of AEM and AEI materials for AEMFC and AEMEL Demonstrators, pilots, prototypes 2019-10-02 09:49:54
Set of CRM-free ORR catalyst and CRM-free or ultralow-PGM HOR catalyst with activity verified by RDE sent to WP5 for AEMFC testing Demonstrators, pilots, prototypes 2019-10-02 09:49:54
Project website Websites, patent fillings, videos etc. 2019-10-02 09:49:54
Set of CRM-free OER and HER catalyst with activity verified by RDE sent to WP5 for AEMEL testing Demonstrators, pilots, prototypes 2019-10-02 09:49:54

Take a look to the deliverables list in detail:  detailed list of CREATE deliverables.

 Publications

year authors and title journal last update
List of publications.
2018 Elena Davydova, Jérémie Zaffran, Kapil Dhaka, Maytal Toroker, Dario Dekel
Hydrogen Oxidation on Ni-Based Electrocatalysts: The Effect of Metal Doping
published pages: 454, ISSN: 2073-4344, DOI: 10.3390/catal8100454
Catalysts 8/10 2019-10-08
2019 Emanuela Sgreccia, Luca Pasquini, Gianfranco Ercolani, Philippe Knauth, Maria Luisa Di Vona
Stimuli-responsive amphoteric ion exchange polymers bearing carboxylic and amine groups grafted to a cross-linkable silica network
published pages: 255-262, ISSN: 0014-3057, DOI: 10.1016/j.eurpolymj.2019.01.003
European Polymer Journal 112 2019-10-08
2019 Haoran Yu, Elena S. Davydova, Uri Ash, Hamish A. Miller, Leonard Bonville, Dario R. Dekel, Radenka Maric
Palladium-ceria nanocatalyst for hydrogen oxidation in alkaline media: Optimization of the Pd–CeO2 interface
published pages: 820-826, ISSN: 2211-2855, DOI: 10.1016/j.nanoen.2018.12.098
Nano Energy 57 2019-10-08
2019 Tamar Zelovich, Leslie Vogt-Maranto, Michael A. Hickner, Stephen J. Paddison, Chulsung Bae, Dario R. Dekel, Mark E. Tuckerman
Hydroxide Ion Diffusion in Anion Exchange Membranes at Low Hydration: Insights from Ab initio Molecular Dynamics
published pages: , ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.9b01824
Chemistry of Materials 2019-10-02
2019 Marco Bellini, Maria V. Pagliaro, Anna Lenarda, Paolo Fornasiero, Marcello Marelli, Claudio Evangelisti, Massimo Innocenti, Qingying Jia, Sanjeev Mukerjee, Jasna Jankovic, Lianqin Wang, John R. Varcoe, Chethana B. Krishnamurthy, Ilya Grinberg, Elena Davydova, Dario R. Dekel, Hamish A. Miller, Francesco Vizza
Palladium–Ceria Catalysts with Enhanced Alkaline Hydrogen Oxidation Activity for Anion Exchange Membrane Fuel Cells
published pages: , ISSN: 2574-0962, DOI: 10.1021/acsaem.9b00657
ACS Applied Energy Materials 2019-10-02
2019 Nejc Hodnik, Serhiy Cherevko
Spot the difference at the nanoscale: identical location electron microscopy in electrocatalysis
published pages: 73-82, ISSN: 2451-9103, DOI: 10.1016/j.coelec.2019.03.007
Current Opinion in Electrochemistry 15 2019-10-02
2019 Jiantao Fan, Sapir Willdorf-Cohen, Eric M. Schibli, Zoe Paula, Wei Li, Thomas J. G. Skalski, Ania Tersakian Sergeenko, Amelia Hohenadel, Barbara J. Frisken, Emanuele Magliocca, William E. Mustain, Charles E. Diesendruck, Dario R. Dekel, Steven Holdcroft
Poly(bis-arylimidazoliums) possessing high hydroxide ion exchange capacity and high alkaline stability
published pages: , ISSN: 2041-1723, DOI: 10.1038/s41467-019-10292-z
Nature Communications 10/1 2019-10-02
2019 Elena Davydova, Florian D Speck, Michael T.Y. Paul, Dario R. Dekel, Serhiy Cherevko
Stability limits of Ni-based hydrogen oxidation electrocatalysts for anion exchange membrane fuel cells
published pages: , ISSN: 2155-5435, DOI: 10.1021/acscatal.9b01582
ACS Catalysis 2019-10-02
2019 Jingkun Li, Qingying Jia, Sanjeev Mukerjee, Moulay-Tahar Sougrati, Goran Drazic, Andrea Zitolo, Frédéric Jaouen
The Challenge of Achieving a High Density of Fe-Based Active Sites in a Highly Graphitic Carbon Matrix
published pages: 144, ISSN: 2073-4344, DOI: 10.3390/catal9020144
Catalysts 9/2 2019-10-02
2018 Dario R. Dekel
Unraveling mysteries of hydrogen electrooxidation in anion exchange membrane fuel cells
published pages: 182-188, ISSN: 2451-9103, DOI: 10.1016/j.coelec.2018.11.013
Current Opinion in Electrochemistry 12 2019-10-02
2019 Dario R. Dekel, Igal G. Rasin, Simon Brandon
Predicting performance stability of anion exchange membrane fuel cells
published pages: 118-123, ISSN: 0378-7753, DOI: 10.1016/j.jpowsour.2019.02.069
Journal of Power Sources 420 2019-10-02
2019 Pietro Giovanni Santori, Florian Dominik Speck, Jingkun Li, Andrea Zitolo, Qingying Jia, Sanjeev Mukerjee, Serhiy Cherevko, Frédéric Jaouen
Effect of Pyrolysis Atmosphere and Electrolyte pH on the Oxygen Reduction Activity, Stability and Spectroscopic Signature of FeN x Moieties in Fe-N-C Catalysts
published pages: F3311-F3320, ISSN: 0013-4651, DOI: 10.1149/2.0371907jes
Journal of The Electrochemical Society 166/7 2019-10-02
2018 Noga Ziv, William E. Mustain, Dario R. Dekel
The Effect of Ambient Carbon Dioxide on Anion-Exchange Membrane Fuel Cells
published pages: 1136-1150, ISSN: 1864-5631, DOI: 10.1002/cssc.201702330
ChemSusChem 11/7 2019-10-02
2018 Ulrike Krewer, Christine Weinzierl, Noga Ziv, Dario R. Dekel
Impact of carbonation processes in anion exchange membrane fuel cells
published pages: 433-446, ISSN: 0013-4686, DOI: 10.1016/j.electacta.2017.12.093
Electrochimica Acta 263 2019-10-02
2018 Chang Hyuck Choi, Hyung-Kyu Lim, Min Wook Chung, Gajeon Chon, Nastaran Ranjbar Sahraie, Abdulrahman Altin, Moulay-Tahar Sougrati, Lorenzo Stievano, Hyun Seok Oh, Eun Soo Park, Fang Luo, Peter Strasser, Goran Dražić, Karl J. J. Mayrhofer, Hyungjun Kim, Frédéric Jaouen
The Achilles\' heel of iron-based catalysts during oxygen reduction in an acidic medium
published pages: , ISSN: 1754-5692, DOI: 10.1039/C8EE01855C
Energy & Environmental Science 2019-10-02
2018 Srdjan Pusara, Simcha Srebnik, Dario R. Dekel
Molecular Simulation of Quaternary Ammonium Solutions at Low Hydration Levels
published pages: 11204-11213, ISSN: 1932-7447, DOI: 10.1021/acs.jpcc.8b00752
The Journal of Physical Chemistry C 122/21 2019-10-02
2018 Dario R. Dekel, Igal G. Rasin, Miles Page, Simon Brandon
Steady state and transient simulation of anion exchange membrane fuel cells
published pages: 191-204, ISSN: 0378-7753, DOI: 10.1016/j.jpowsour.2017.07.012
Journal of Power Sources 375 2019-10-02
2018 Elena S. Davydova, Sanjeev Mukerjee, Frédéric Jaouen, Dario R. Dekel
Electrocatalysts for Hydrogen Oxidation Reaction in Alkaline Electrolytes
published pages: 6665-6690, ISSN: 2155-5435, DOI: 10.1021/acscatal.8b00689
ACS Catalysis 8/7 2019-10-02
2018 Noga Ziv, Dario R. Dekel
A practical method for measuring the true hydroxide conductivity of anion exchange membranes
published pages: 109-113, ISSN: 1388-2481, DOI: 10.1016/j.elecom.2018.01.021
Electrochemistry Communications 88 2019-10-02
2018 Charles E. Diesendruck, Dario R. Dekel
Water – A key parameter in the stability of anion exchange membrane fuel cells
published pages: , ISSN: 2451-9103, DOI: 10.1016/j.coelec.2018.03.019
Current Opinion in Electrochemistry 2019-10-02
2018 Travis J. Omasta, Xiong Peng, Hamish A. Miller, Francesco Vizza, Lianqin Wang, John R. Varcoe, Dario R. Dekel, William E. Mustain
Beyond 1.0 W cm −2 Performance without Platinum: The Beginning of a New Era in Anion Exchange Membrane Fuel Cells
published pages: J3039-J3044, ISSN: 0013-4651, DOI: 10.1149/2.0071815jes
Journal of The Electrochemical Society 165/15 2019-10-02
2018 Sapir Willdorf-Cohen, Abhishek N. Mondal, Dario R. Dekel, Charles E. Diesendruck
Chemical stability of poly(phenylene oxide)-based ionomers in an anion exchange-membrane fuel cell environment
published pages: , ISSN: 2050-7488, DOI: 10.1039/C8TA05785K
Journal of Materials Chemistry A 2019-10-02
2017 Marc Ledendecker, Jared Mondschein, Olga Kasian, Simon Geiger, Daniel Göhl, Max Schalenbach, Aleksandar Zeradjanin, Serhiy Cherevko, Raymond E. Schaak, Karl Mayrhofer
Stability and activity of non-noble based catalysts toward the hydrogen evolution reaction - feasible electrocatalysts in acidic medium?
published pages: , ISSN: 1433-7851, DOI: 10.1002/anie.201704021
Angewandte Chemie International Edition 2019-10-02
2017 Hamish A. Miller, Francesco Vizza, Marcello Marelli, Anicet Zadick, Laetitia Dubau, Marian Chatenet, Simon Geiger, Serhiy Cherevko, Huong Doan, Ryan K. Pavlicek, Sanjeev Mukerjee, Dario R. Dekel
Highly active nanostructured palladium-ceria electrocatalysts for the hydrogen oxidation reaction in alkaline medium
published pages: 293-305, ISSN: 2211-2855, DOI: 10.1016/j.nanoen.2017.01.051
Nano Energy 33 2019-10-02
2017 Dario R. Dekel, Michal Amar, Sapir Willdorf, Monica Kosa, Shubhendu Dhara, Charles E. Diesendruck
Effect of Water on the Stability of Quaternary Ammonium Groups for Anion Exchange Membrane Fuel Cell Applications
published pages: 4425-4431, ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.7b00958
Chemistry of Materials 29/10 2019-10-02

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