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CREATE SIGNED

Critical Raw materials Elimination by a top-down Approach To hydrogen and Electricity generation

Total Cost €

EC-Contrib. €

Partnership

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Outcomes and
results

CREATE project word cloud

Explore the words cloud of the CREATE project. It provides you a very rough idea of what is the project "CREATE" about.

ionomers raw group bipolar strategy materials oxides create pure photovoltaic market carry composites performance electricity electrolytes storage opening conducting anion catalysts pem equally membranes alkaline el carbon ultralow proton grid potentiality ph platinum exchange earth reaction innovative oxygen adapting h2 advantages drastic reduce metal power electrolyzer contents cell temperature drastically critical distributed membrane liquid hydrogen abundant maintaining free eliminate reactions junction electrode designs acidic pgm electrolyte door assemblies thereby polymer latter elimination off overcome fc unexplored strategies fuel small metals back cells interfaced shift

Project "CREATE" data sheet

The following table provides information about the project.

Coordinator	CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS Organization address address: RUE MICHEL ANGE 3 city: PARIS postcode: 75794 website: www.cnrs.fr contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.
Coordinator Country	France [FR]
Project website	http://www.create-energy-h2020.eu/
Total cost	4˙480˙978 €
EC max contribution	4˙318˙478 € (96%)
Programme	1. H2020-EU.2.1.3. (INDUSTRIAL LEADERSHIP - Leadership in enabling and industrial technologies - Advanced materials)
Code Call	H2020-NMBP-2016-two-stage
Funding Scheme	RIA
Starting year	2017
Duration (year-month-day)	from 2017-01-01 to 2020-06-30

Partnership

Take a look of project's partnership.

#	participants	country	role	EC contrib. [€]
1	CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE CNRS Organization address address: RUE MICHEL ANGE 3 city: PARIS postcode: 75794 website: www.cnrs.fr contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	FR (PARIS)	coordinator	598˙123.00
2	TECHNION - ISRAEL INSTITUTE OF TECHNOLOGY TECHNION - ISRAEL INSTITUTE OF TECHNOLOGY Organization address address: SENATE BUILDING TECHNION CITY city: HAIFA postcode: 32000 website: www.technion.ac.il contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	IL (HAIFA)	participant	699˙423.00
3	FUMATECH BWT GMBH FUMATECH BWT GMBH Organization address address: CARL BENZ STRASSE 4 city: BIETIGHEIM BISSINGEN postcode: 74321 website: www.fumatech.de contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	DE (BIETIGHEIM BISSINGEN)	participant	512˙375.00
4	AALTO KORKEAKOULUSAATIO SR AALTO KORKEAKOULUSAATIO SR Organization address address: OTAKAARI 1 city: ESPOO postcode: 2150 website: http://www.aalto.fi/en/ contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	FI (ESPOO)	participant	474˙588.00
5	FORSCHUNGSZENTRUM JULICH GMBH FORSCHUNGSZENTRUM JULICH GMBH Organization address address: WILHELM JOHNEN STRASSE city: JULICH postcode: 52428 website: www.fz-juelich.de contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	DE (JULICH)	participant	451˙551.00
6	UNIVERSITA DEGLI STUDI DI ROMA TOR VERGATA UNIVERSITA DEGLI STUDI DI ROMA TOR VERGATA Organization address address: VIA CRACOVIA 50 city: ROMA postcode: 133 website: www.uniroma2.it contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	IT (ROMA)	participant	403˙750.00
7	ITM POWER (TRADING) LIMITED ITM POWER (TRADING) LIMITED Organization address address: ATLAS WAY 22 city: SHEFFIELD postcode: S4 7QQ website: www.itm-power.com contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	UK (SHEFFIELD)	participant	374˙200.00
8	EIFER EUROPAISCHES INSTITUT FUR ENERGIEFORSCHUNG EDF KIT EWIV EIFER EUROPAISCHES INSTITUT FUR ENERGIEFORSCHUNG EDF KIT EWIV Organization address address: EMMY NOETHER STRASSE 11 city: KARLSRUHE postcode: 76131 website: www.eifer.org contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	DE (KARLSRUHE)	participant	365˙781.00
9	FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA Organization address address: AVENIDA PAISSOS CATALANS 16 city: TARRAGONA postcode: 43007 website: www.iciq.es contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	ES (TARRAGONA)	participant	350˙625.00
10	PRETEXO PRETEXO Organization address address: 58 AVENUE D'OCCITANIE BAT J2 APT 193 city: MONTPELLIER postcode: 34090 website: www.pretexo.com contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	FR (MONTPELLIER)	participant	88˙059.00
11	NORTHEASTERN UNIVERSITY NORTHEASTERN UNIVERSITY Organization address address: HUNTINGTON AVENUE 360 960 RP city: BOSTON MA postcode: 2115 website: n.a. contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	US (BOSTON MA)	participant	0.00

Map

Project objective

CREATE aims at developing innovative membrane electrode assemblies for low-temperature polymer-electrolyte fuel cell (FC) and electrolyzer (EL) with much reduced cost. This will be achieved via elimination or drastic reduction of critical raw materials in their catalysts, in particular platinum group metals (PGM).

Key issues with present low-temperature FC & EL are the high contents of PGM in devices based on proton-exchange-membrane (PEM) and the need for liquid electrolytes in alkaline FC and EL. To overcome this, we will shift from PEM-based cells to 1) pure anion-conducting polymer-electrolytes and 2) to bipolar-membrane polymer electrolytes. The latter comprises anion and proton conducting ionomers and a junction. Bipolar membranes allow adapting the pH at each electrode, thereby opening the door to improved performance or PGM-free catalysts. Both strategies carry the potentiality to eliminate or drastically reduce the need for PGM while maintaining the advantages of PEM-based devices.

In strategy 1, novel anion-exchange ionomers and membranes will be developed and interfaced with catalysts based on Earth-abundant metal oxides or metal-carbon composites for the oxygen reactions, and with ultralow PGM or PGM-free catalysts for the hydrogen reactions.

In strategy 2, novel bipolar membrane designs, or designs unexplored for FC & EL, will be developed and interfaced with catalysts for the oxygen reactions (high pH side of the bipolar membrane) and with catalysts for the hydrogen reactions (low pH side). The ionomers and oxygen reaction catalysts developed in strategy 1 will be equally useful for strategy 2, while identified PGM-free and ultralow-PGM catalysts will be implemented for the hydrogen reactions on the acidic side.

Polymer-electrolyte FC & EL based on those concepts will be evaluated for targeted applications, i.e. photovoltaic electricity storage, off-grid back-up power and H2 production. The targeted market is distributed small-scale systems.

Deliverables

List of deliverables.
First generation of AEM and AEI materials for AEMFC and AEMEL	Demonstrators, pilots, prototypes	2019-10-02 09:49:54
Set of CRM-free ORR catalyst and CRM-free or ultralow-PGM HOR catalyst with activity verified by RDE sent to WP5 for AEMFC testing	Demonstrators, pilots, prototypes	2019-10-02 09:49:54
Project website	Websites, patent fillings, videos etc.	2019-10-02 09:49:54
Set of CRM-free OER and HER catalyst with activity verified by RDE sent to WP5 for AEMEL testing	Demonstrators, pilots, prototypes	2019-10-02 09:49:54

Take a look to the deliverables list in detail: detailed list of CREATE deliverables.

Publications

List of publications.
year	authors and title	journal	last update
2018	Elena Davydova, JÃ©rÃ©mie Zaffran, Kapil Dhaka, Maytal Toroker, Dario Dekel Hydrogen Oxidation on Ni-Based Electrocatalysts: The Effect of Metal Doping published pages: 454, ISSN: 2073-4344, DOI: 10.3390/catal8100454	Catalysts 8/10	2019-10-08
2019	Emanuela Sgreccia, Luca Pasquini, Gianfranco Ercolani, Philippe Knauth, Maria Luisa Di Vona Stimuli-responsive amphoteric ion exchange polymers bearing carboxylic and amine groups grafted to a cross-linkable silica network published pages: 255-262, ISSN: 0014-3057, DOI: 10.1016/j.eurpolymj.2019.01.003	European Polymer Journal 112	2019-10-08
2019	Haoran Yu, Elena S. Davydova, Uri Ash, Hamish A. Miller, Leonard Bonville, Dario R. Dekel, Radenka Maric Palladium-ceria nanocatalyst for hydrogen oxidation in alkaline media: Optimization of the Pdâ€“CeO2 interface published pages: 820-826, ISSN: 2211-2855, DOI: 10.1016/j.nanoen.2018.12.098	Nano Energy 57	2019-10-08
2019	Tamar Zelovich, Leslie Vogt-Maranto, Michael A. Hickner, Stephen J. Paddison, Chulsung Bae, Dario R. Dekel, Mark E. Tuckerman Hydroxide Ion Diffusion in Anion Exchange Membranes at Low Hydration: Insights from Ab initio Molecular Dynamics published pages: , ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.9b01824	Chemistry of Materials	2019-10-02
2019	Marco Bellini, Maria V. Pagliaro, Anna Lenarda, Paolo Fornasiero, Marcello Marelli, Claudio Evangelisti, Massimo Innocenti, Qingying Jia, Sanjeev Mukerjee, Jasna Jankovic, Lianqin Wang, John R. Varcoe, Chethana B. Krishnamurthy, Ilya Grinberg, Elena Davydova, Dario R. Dekel, Hamish A. Miller, Francesco Vizza Palladiumâ€“Ceria Catalysts with Enhanced Alkaline Hydrogen Oxidation Activity for Anion Exchange Membrane Fuel Cells published pages: , ISSN: 2574-0962, DOI: 10.1021/acsaem.9b00657	ACS Applied Energy Materials	2019-10-02
2019	Nejc Hodnik, Serhiy Cherevko Spot the difference at the nanoscale: identical location electron microscopy in electrocatalysis published pages: 73-82, ISSN: 2451-9103, DOI: 10.1016/j.coelec.2019.03.007	Current Opinion in Electrochemistry 15	2019-10-02
2019	Jiantao Fan, Sapir Willdorf-Cohen, Eric M. Schibli, Zoe Paula, Wei Li, Thomas J. G. Skalski, Ania Tersakian Sergeenko, Amelia Hohenadel, Barbara J. Frisken, Emanuele Magliocca, William E. Mustain, Charles E. Diesendruck, Dario R. Dekel, Steven Holdcroft Poly(bis-arylimidazoliums) possessing high hydroxide ion exchange capacity and high alkaline stability published pages: , ISSN: 2041-1723, DOI: 10.1038/s41467-019-10292-z	Nature Communications 10/1	2019-10-02
2019	Elena Davydova, Florian D Speck, Michael T.Y. Paul, Dario R. Dekel, Serhiy Cherevko Stability limits of Ni-based hydrogen oxidation electrocatalysts for anion exchange membrane fuel cells published pages: , ISSN: 2155-5435, DOI: 10.1021/acscatal.9b01582	ACS Catalysis	2019-10-02
2019	Jingkun Li, Qingying Jia, Sanjeev Mukerjee, Moulay-Tahar Sougrati, Goran Drazic, Andrea Zitolo, FrÃ©dÃ©ric Jaouen The Challenge of Achieving a High Density of Fe-Based Active Sites in a Highly Graphitic Carbon Matrix published pages: 144, ISSN: 2073-4344, DOI: 10.3390/catal9020144	Catalysts 9/2	2019-10-02
2018	Dario R. Dekel Unraveling mysteries of hydrogen electrooxidation in anion exchange membrane fuel cells published pages: 182-188, ISSN: 2451-9103, DOI: 10.1016/j.coelec.2018.11.013	Current Opinion in Electrochemistry 12	2019-10-02
2019	Dario R. Dekel, Igal G. Rasin, Simon Brandon Predicting performance stability of anion exchange membrane fuel cells published pages: 118-123, ISSN: 0378-7753, DOI: 10.1016/j.jpowsour.2019.02.069	Journal of Power Sources 420	2019-10-02
2019	Pietro Giovanni Santori, Florian Dominik Speck, Jingkun Li, Andrea Zitolo, Qingying Jia, Sanjeev Mukerjee, Serhiy Cherevko, FrÃ©dÃ©ric Jaouen Effect of Pyrolysis Atmosphere and Electrolyte pH on the Oxygen Reduction Activity, Stability and Spectroscopic Signature of FeN x Moieties in Fe-N-C Catalysts published pages: F3311-F3320, ISSN: 0013-4651, DOI: 10.1149/2.0371907jes	Journal of The Electrochemical Society 166/7	2019-10-02
2018	Noga Ziv, William E. Mustain, Dario R. Dekel The Effect of Ambient Carbon Dioxide on Anion-Exchange Membrane Fuel Cells published pages: 1136-1150, ISSN: 1864-5631, DOI: 10.1002/cssc.201702330	ChemSusChem 11/7	2019-10-02
2018	Ulrike Krewer, Christine Weinzierl, Noga Ziv, Dario R. Dekel Impact of carbonation processes in anion exchange membrane fuel cells published pages: 433-446, ISSN: 0013-4686, DOI: 10.1016/j.electacta.2017.12.093	Electrochimica Acta 263	2019-10-02
2018	Chang Hyuck Choi, Hyung-Kyu Lim, Min Wook Chung, Gajeon Chon, Nastaran Ranjbar Sahraie, Abdulrahman Altin, Moulay-Tahar Sougrati, Lorenzo Stievano, Hyun Seok Oh, Eun Soo Park, Fang Luo, Peter Strasser, Goran DraÅ¾iÄ‡, Karl J. J. Mayrhofer, Hyungjun Kim, FrÃ©dÃ©ric Jaouen The Achilles\' heel of iron-based catalysts during oxygen reduction in an acidic medium published pages: , ISSN: 1754-5692, DOI: 10.1039/C8EE01855C	Energy & Environmental Science	2019-10-02
2018	Srdjan Pusara, Simcha Srebnik, Dario R. Dekel Molecular Simulation of Quaternary Ammonium Solutions at Low Hydration Levels published pages: 11204-11213, ISSN: 1932-7447, DOI: 10.1021/acs.jpcc.8b00752	The Journal of Physical Chemistry C 122/21	2019-10-02
2018	Dario R. Dekel, Igal G. Rasin, Miles Page, Simon Brandon Steady state and transient simulation of anion exchange membrane fuel cells published pages: 191-204, ISSN: 0378-7753, DOI: 10.1016/j.jpowsour.2017.07.012	Journal of Power Sources 375	2019-10-02
2018	Elena S. Davydova, Sanjeev Mukerjee, FrÃ©dÃ©ric Jaouen, Dario R. Dekel Electrocatalysts for Hydrogen Oxidation Reaction in Alkaline Electrolytes published pages: 6665-6690, ISSN: 2155-5435, DOI: 10.1021/acscatal.8b00689	ACS Catalysis 8/7	2019-10-02
2018	Noga Ziv, Dario R. Dekel A practical method for measuring the true hydroxide conductivity of anion exchange membranes published pages: 109-113, ISSN: 1388-2481, DOI: 10.1016/j.elecom.2018.01.021	Electrochemistry Communications 88	2019-10-02
2018	Charles E. Diesendruck, Dario R. Dekel Water â€“ A key parameter in the stability of anion exchange membrane fuel cells published pages: , ISSN: 2451-9103, DOI: 10.1016/j.coelec.2018.03.019	Current Opinion in Electrochemistry	2019-10-02
2018	Travis J. Omasta, Xiong Peng, Hamish A. Miller, Francesco Vizza, Lianqin Wang, John R. Varcoe, Dario R. Dekel, William E. Mustain Beyond 1.0Â W cm âˆ’2 Performance without Platinum: The Beginning of a New Era in Anion Exchange Membrane Fuel Cells published pages: J3039-J3044, ISSN: 0013-4651, DOI: 10.1149/2.0071815jes	Journal of The Electrochemical Society 165/15	2019-10-02
2018	Sapir Willdorf-Cohen, Abhishek N. Mondal, Dario R. Dekel, Charles E. Diesendruck Chemical stability of poly(phenylene oxide)-based ionomers in an anion exchange-membrane fuel cell environment published pages: , ISSN: 2050-7488, DOI: 10.1039/C8TA05785K	Journal of Materials Chemistry A	2019-10-02
2017	Marc Ledendecker, Jared Mondschein, Olga Kasian, Simon Geiger, Daniel GÃ¶hl, Max Schalenbach, Aleksandar Zeradjanin, Serhiy Cherevko, Raymond E. Schaak, Karl Mayrhofer Stability and activity of non-noble based catalysts toward the hydrogen evolution reaction - feasible electrocatalysts in acidic medium? published pages: , ISSN: 1433-7851, DOI: 10.1002/anie.201704021	Angewandte Chemie International Edition	2019-10-02
2017	Hamish A. Miller, Francesco Vizza, Marcello Marelli, Anicet Zadick, Laetitia Dubau, Marian Chatenet, Simon Geiger, Serhiy Cherevko, Huong Doan, Ryan K. Pavlicek, Sanjeev Mukerjee, Dario R. Dekel Highly active nanostructured palladium-ceria electrocatalysts for the hydrogen oxidation reaction in alkaline medium published pages: 293-305, ISSN: 2211-2855, DOI: 10.1016/j.nanoen.2017.01.051	Nano Energy 33	2019-10-02
2017	Dario R. Dekel, Michal Amar, Sapir Willdorf, Monica Kosa, Shubhendu Dhara, Charles E. Diesendruck Effect of Water on the Stability of Quaternary Ammonium Groups for Anion Exchange Membrane Fuel Cell Applications published pages: 4425-4431, ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.7b00958	Chemistry of Materials 29/10	2019-10-02

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