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SWITCHCATALYSIS

Switchable catalytic activity of spin crossover materials

Total Cost €

EC-Contrib. €

Partnership

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Outcomes and
results

SWITCHCATALYSIS project word cloud

Explore the words cloud of the SWITCHCATALYSIS project. It provides you a very rough idea of what is the project "SWITCHCATALYSIS" about.

electronic host crossover functional researcher structural photonic reorganizations enzymes university molecular spin transfer creation intensively purposes materials photocatalytic switches metallic drastic composites competence asked dependent johannes nanoparticles physical group switchable works centres cover fundamental experiments provoked sco catalysis transition optimal expertise complexes combine representative gutenberg question combination conjugates conduce influence background create efficient accompanying versatile hosting facilities mechanical domain realization laboratory catalytic scientific inclusion deals redox catalysts

Project "SWITCHCATALYSIS" data sheet

The following table provides information about the project.

Coordinator	JOHANNES GUTENBERG-UNIVERSITAT MAINZ Organization address address: SAARSTRASSE 21 city: MAINZ postcode: 55122 website: www.uni-mainz.de contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.
Coordinator Country	Germany [DE]
Project website	http://www.ak-tremel.chemie.uni-mainz.de/Dateien/Switch
Total cost	159˙460 €
EC max contribution	159˙460 € (100%)
Programme	1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
Code Call	H2020-MSCA-IF-2014
Funding Scheme	MSCA-IF-EF-ST
Starting year	2015
Duration (year-month-day)	from 2015-06-01 to 2017-05-31

Partnership

Take a look of project's partnership.

#	participants	country	role	EC contrib. [€]
1	JOHANNES GUTENBERG-UNIVERSITAT MAINZ JOHANNES GUTENBERG-UNIVERSITAT MAINZ Organization address address: SAARSTRASSE 21 city: MAINZ postcode: 55122 website: www.uni-mainz.de contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	DE (MAINZ)	coordinator	159˙460.00

Map

Project objective

Spin crossover (SCO) is an intensively studied and highly versatile representative of molecular switches. The change of numerous physical properties during the spin transition has provoked a wide inclusion of SCO materials into various electronic, photonic and mechanical experiments. The main question asked in this project is how the drastic electronic and structural reorganizations accompanying spin transition will influence the catalytic activity of SCO complexes and composites. These studies will cover the redox catalytic activity of SCO molecular complexes, nanoparticles and composites, photocatalytic properties of SCO complexes, catalysis by conjugates with enzymes, and other switchable materials with catalytic activity. The expected results will allow the creation of switchable catalysts and will contribute to the fundamental knowledge on the spin-dependent catalytic activity of metallic centres. This project aims to combine the background of an experienced researcher that works in the domain of spin crossover materials, and the competence of a hosting group that deals with functional nanoparticles including their catalytic and photocatalytic activities. This combination of expertise supported by the facilities of Johannes Gutenberg University will create the optimal conditions for the realization of scientific purposes included in this project and will conduce to the efficient knowledge transfer between the experienced researcher and the host laboratory.

Publications

List of publications.
year	authors and title	journal	last update
2017	Il\'ya A. Gural\'skiy, Sergii I. Shylin, Vadim Ksenofontov, Wolfgang Tremel Spin-State Dependent Redox Catalytic Activity of a Switchable Iron(II) Complex published pages: , ISSN: 1434-1948, DOI: 10.1002/ejic.201700454	European Journal of Inorganic Chemistry 2017	2019-07-24
2016	Il\'ya A. Gural\'skiy, Sergii I. Shylin, Bohdan O. Golub, Vadim Ksenofontov, Igor O. Fritsky, Wolfgang Tremel High temperature spin crossover in [Fe(pyrazine){Ag(CN) 2 } 2 ] and its solvate published pages: 9012-9016, ISSN: 1144-0546, DOI: 10.1039/C6NJ01472K	New J. Chem. 40/11	2019-07-24
2016	Il\'ya A. Gural\'skiy, Bohdan O. Golub, Sergii I. Shylin, Vadim Ksenofontov, Helena J. Shepherd, Paul R. Raithby, Wolfgang Tremel, Igor O. Fritsky Cooperative High-Temperature Spin Crossover Accompanied by a Highly Anisotropic Structural Distortion published pages: 3191-3195, ISSN: 1434-1948, DOI: 10.1002/ejic.201600406	European Journal of Inorganic Chemistry 2016/19	2019-07-24

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