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p-TYPE SIGNED

Transparent p-type semiconductors for efficient solar energy capture, conversion and storage.

Total Cost €

EC-Contrib. €

Partnership

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Outcomes and
results

p-TYPE project word cloud

Explore the words cloud of the p-TYPE project. It provides you a very rough idea of what is the project "p-TYPE" about.

royal solar vastly catalysts candidates radiation assemble sacrificing prospect efficient red preparing materials theoretical conventionally dye energy transparency efficiency dyes spectral measured single harvesting optimising modified cells efficiencies society fuel nir synthesise semiconductor match 33 sensitized realistic few almost amount generation ptype convert criteria h2o poor nio adsorption differently converting obtain hodgkin co2 band 43 combine semiconductors utilised worldwide alternative limited photoelectrochemical 70 carbon dsc sunlight charge transparent perovskite reagents type fellow conductivity select tandem 35 breakthrough characterising dscs voltage tio2 light sacrificial 20 independent free valence limit dorothy storing minutes photocurrent device collection libraries

Project "p-TYPE" data sheet

The following table provides information about the project.

Coordinator	UNIVERSITY OF NEWCASTLE UPON TYNE Organization address address: KINGS GATE city: NEWCASTLE UPON TYNE postcode: NE1 7RU website: http://www.ncl.ac.uk/ contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.
Coordinator Country	United Kingdom [UK]
Total cost	1˙499˙840 €
EC max contribution	1˙499˙840 € (100%)
Programme	1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
Code Call	ERC-2016-STG
Funding Scheme	ERC-STG
Starting year	2017
Duration (year-month-day)	from 2017-01-01 to 2022-12-31

Partnership

Take a look of project's partnership.

#	participants	country	role	EC contrib. [€]
1	UNIVERSITY OF NEWCASTLE UPON TYNE UNIVERSITY OF NEWCASTLE UPON TYNE Organization address address: KINGS GATE city: NEWCASTLE UPON TYNE postcode: NE1 7RU website: http://www.ncl.ac.uk/ contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	UK (NEWCASTLE UPON TYNE)	coordinator	1˙499˙840.00

Map

Project objective

This proposal will develop new transparent p-type semiconductors that will make dye-sensitized solar cells (DSC) a vastly more efficient and a realistic prospect for carbon-free energy generation worldwide. Two key challenges will be addressed: (1) a means of converting NIR radiation to increase the amount of sunlight utilised from 35% to over 70%; (2) a means of storing the energy. Almost all the research in the field is based on dye or “perovskite” sensitized TiO2 (n-type) solar cells, which are limited by their poor spectral response in the red-NIR. pTYPE approaches the problem differently: tandem DSCs will be developed which combine a n-type and a p-type DSC in a single p/n device. This increases the theoretical efficiency from 33% to 43% by extending the spectral response without sacrificing the voltage. The device will be modified with catalysts to convert H2O or CO2 and sunlight into fuel without using sacrificial reagents that limit the efficiency of current systems. An efficient tandem DSC has not yet been developed because p-type DSCs are much less efficient than n-type cells. As an independent Royal Society Dorothy Hodgkin fellow I increased the photocurrent by developing new dyes. This project will exploit this breakthrough by increasing the voltage, which is currently limited by the NiO semiconductor conventionally used. I will rapidly synthesise libraries of alternative p-type semiconductors; select promising candidates based on key criteria which can be measured on a single sample within minutes: transparency and dye adsorption (for high light harvesting efficiency by the dye), conductivity (for high charge collection efficiency) and valence band potential (for high voltage); assemble the new materials in tandem DSCs. As one of the few researchers experienced in preparing, characterising and optimising each aspect of this photoelectrochemical system, I aim to match the efficiency from TiO2 with p-type DSCs to obtain tandem efficiencies above 20%.

Deliverables

List of deliverables.
Data Management Plan	Open Research Data Pilot	2019-05-31 18:17:17

Take a look to the deliverables list in detail: detailed list of p-TYPE deliverables.

Publications

List of publications.
year	authors and title	journal	last update
2019	Ankita Kolay, Nathan T. Z. Potts, Kripasindhu Sardar, Elizabeth A. Gibson, Melepurath Deepa A dual-function photoelectrochemical solar cell which assimilates light-harvesting, charge-transport and photoelectrochromic nanomaterials in a tandem design published pages: 514-528, ISSN: 2398-4902, DOI: 10.1039/c8se00548f	Sustainable Energy & Fuels 3/2	2019-09-05
2019	Elisabetta Benazzi, Gareth H. Summers, Fiona A. Black, Igor V. Sazanovich, Ian P. Clark, Elizabeth A. Gibson Assembly, charge-transfer and solar cell performance with porphyrin-C 60 on NiO for p-type dye-sensitized solar cells published pages: 20180338, ISSN: 1364-503X, DOI: 10.1098/rsta.2018.0338	Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 377/2152	2019-09-05
2018	Claus Hierlinger, Heather V. Flint, David B. Cordes, Alexandra M.Z. Slawin, Elizabeth A. Gibson, Denis Jacquemin, VÃ©ronique Guerchais, Eli Zysman-Colman A panchromatic, near infrared Ir(III) emitter bearing a tripodal C^N^C ligand as a dye for dye-sensitized solar cells published pages: 109-115, ISSN: 0277-5387, DOI: 10.1016/j.poly.2017.12.003	Polyhedron 140	2019-06-13
2019	Elisabetta Benazzi, John Mallows, Gareth H. Summers, Fiona A. Black, Elizabeth A. Gibson Developing photocathode materials for p-type dye-sensitized solar cells published pages: 10409-10445, ISSN: 2050-7534, DOI: 10.1039/c9tc01822k	Journal of Materials Chemistry C 7/34	2019-09-05
2019	Anil Reddy Marri, Fiona A. Black, John Mallows, Elizabeth A. Gibson, John Fielden Pyridinium p-DSSC dyes: An old acceptor learns new tricks published pages: 508-517, ISSN: 0143-7208, DOI: 10.1016/j.dyepig.2019.02.044	Dyes and Pigments 165	2019-09-05

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