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METACYL SIGNED

Catalytic META C-H ACYLation of arenes

Total Cost €

EC-Contrib. €

Partnership

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METACYL project word cloud

Explore the words cloud of the METACYL project. It provides you a very rough idea of what is the project "METACYL" about.

acylation bonds almost arenes insertion first contrast mild chemistry strategy co efficient activation carbonylative ones carbonylation unexplored degree synthetic sp2 group combining economical accessible unreactive crafts heteroarenes compounds employing protocols pivoting meta organic synthesis striking directing activations completely hardly friedel flow atom molecular transient green breakthrough demonstrating unprecedented sophistication continuous para ortho acylations

Project "METACYL" data sheet

The following table provides information about the project.

Coordinator	UNIVERSITA DEGLI STUDI DI PARMA Organization address address: VIA UNIVERSITA 12 city: PARMA postcode: 43100 website: www.unipr.it contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.
Coordinator Country	Italy [IT]
Total cost	183˙473 €
EC max contribution	183˙473 € (100%)
Programme	1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
Code Call	H2020-MSCA-IF-2019
Funding Scheme	MSCA-IF-EF-ST
Starting year	2020
Duration (year-month-day)	from 2020-09-01 to 2022-08-31

Partnership

Take a look of project's partnership.

#	participants	country	role	EC contrib. [€]
1	UNIVERSITA DEGLI STUDI DI PARMA UNIVERSITA DEGLI STUDI DI PARMA Organization address address: VIA UNIVERSITA 12 city: PARMA postcode: 43100 website: www.unipr.it contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	IT (PARMA)	coordinator	183˙473.00

Map

Project objective

Carbonylative C-H activations can lead to an unprecedented degree of molecular sophistication by combining the atom-economical insertion of CO with the green activation of unreactive C-H bonds. In striking contrast to ortho C-H acylation of arenes and heteroarenes (directing-group strategy) and para C-H ones (Friedel-Crafts chemistry), meta C-H acylations are almost completely unexplored. This proposal aims at the development of the first example of meta C-H acylation via mild carbonylation of arenes. Pivoting on this breakthrough, it will be possible to accomplish synthetic methods 1) for the efficient synthesis of hardly accessible organic compounds, 2) for the activation and carbonylation of meta C(sp2)-H bonds, 3) by employing transient directing group and 4) demonstrating the application of these protocols under continuous flow conditions.

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The information about "METACYL" are provided by the European Opendata Portal: CORDIS opendata.