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S-CAGE SIGNED

Smart Coordination Polymers with Compartmentalized Pockets for Adaptive Guest Entrance

Total Cost €

EC-Contrib. €

Partnership

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S-CAGE project word cloud

Explore the words cloud of the S-CAGE project. It provides you a very rough idea of what is the project "S-CAGE" about.

species mechanism robustness serve entities internal followed unequivocal interacting location benefit compartments gases tuned materials room insights entrances generation periodically channels diffraction applicability strategy interactions combination frameworks performances visualization accommodate comprehension cps confined magnetic gain nature polymers molecules ideal zeolites characterization framework versatility permit separation horizons 2d specially direct designed entrance 1d compartmentalized diversity structural pores guests pockets guest cage dynamic ing gas crystalline volatile goals stability magnetism chemical interaction 3d easily mofs unprecedented deep absence permanent interplay depending sensing spaces prove pressure discrete dense space voids modern modes enhanced solids

Project "S-CAGE" data sheet

The following table provides information about the project.

Coordinator	UNIVERSITAT DE VALENCIA Organization address address: AVENIDA BLASCO IBANEZ 13 city: VALENCIA postcode: 46010 website: www.uv.es contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.
Coordinator Country	Spain [ES]
Total cost	1˙998˙750 €
EC max contribution	1˙998˙750 € (100%)
Programme	1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
Code Call	ERC-2016-COG
Funding Scheme	ERC-COG
Starting year	2017
Duration (year-month-day)	from 2017-05-01 to 2022-04-30

Partnership

Take a look of project's partnership.

#	participants	country	role	EC contrib. [€]
1	UNIVERSITAT DE VALENCIA UNIVERSITAT DE VALENCIA Organization address address: AVENIDA BLASCO IBANEZ 13 city: VALENCIA postcode: 46010 website: www.uv.es contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	ES (VALENCIA)	coordinator	1˙998˙750.00

Map

Project objective

The S-CAGE project aims to develop a new generation of crystalline solids with periodically-organized discrete voids, or compartments, that would benefit from the combination of the high stability and robustness of dense materials with the structural diversity and versatility (and therefore large applicability) of open frameworks. These coordination polymers (CPs) will be capable of interacting with guest species in the absence of large channels or permanent pores due to the presence of dynamic entrances. This could open new horizons towards the design of unprecedented materials as an enhanced interplay between the guests and the frameworks will be achieved resulting from the confined space of the compartmentalized pockets.

The main goals of S-CAGE will be:

i) Chemical design of compartmentalized 1D, 2D and 3D coordination polymers. These materials will be designed in such a way that they will provide ideal room to accommodate different guest molecules, which can be easily tuned depending on the target guest.

ii) Advanced structural characterization, including modern diffraction studies under pressure of gas and volatile guests. This strategy will provide unequivocal prove of the location of the guest molecules in the internal voids and gain insights of the mechanism of entrance. The direct visualization of the modes of interactions of different gases will permit a deep comprehension of the nature of their interaction.

iii) Gas separation studies. My goal will be the development of materials that could specially serve for gas separation and improve the performances of zeolites and MOFs by implementation of dynamic entities into the framework.

iv) Sensing capabilities through changes in magnetic properties. The chemical design followed in S-CAGE will result in magnetic CPs with confined spaces which should enhance the interaction of the guest molecules with the framework, and thus a change in their magnetism is expected.

Publications

List of publications.
year	authors and title	journal	last update
2019	Eduardo Andres-Garcia, Javier LÃ³pez-Cabrelles, Lide Oar-Arteta, Beatriz Roldan-Martinez, Marta Cano-Padilla, Jorge Gascon, Guillermo MÃnguez Espallargas, Freek Kapteijn Cation influence in adsorptive propane/propylene separation in ZIF-8 (SOD) topology published pages: 848-856, ISSN: 1385-8947, DOI: 10.1016/j.cej.2019.04.094	Chemical Engineering Journal 371	2020-02-06
2019	Manuel Souto, JoaquÃn Calbo, Samuel MaÃ±as-Valero, Aron Walsh, Guillermo MÃnguez Espallargas Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metalâ€“organic framework published pages: 1883-1893, ISSN: 2190-4286, DOI: 10.3762/bjnano.10.183	Beilstein Journal of Nanotechnology 10	2020-01-30
2019	Javier Castellsâ€Gil, Samuel MaÃ±asâ€Valero, IÃ±igo J. VitÃ³ricaâ€YrezÃ¡bal, Duarte Ananias, JoÃ£o Rocha, Raul Santiago, Stefan T. Bromley, JosÃ© J. BaldovÃ, Eugenio Coronado, Manuel Souto, Guillermo MÃnguez Espallargas Electronic, Structural and Functional Versatility in Tetrathiafulvaleneâ€Lanthanide Metalâ€“Organic Frameworks published pages: 12636-12643, ISSN: 0947-6539, DOI: 10.1002/chem.201902855	Chemistry â€“ A European Journal 25/54	2020-01-30
2019	MarÃa Cabrero-Antonino, Sonia Remiro-BuenamaÃ±ana, Manuel Souto, Antonio A. GarcÃa-Valdivia, Duane Choquesillo-Lazarte, Sergio NavalÃ³n, Antonio RodrÃguez-DiÃ©guez, Guillermo MÃnguez Espallargas, Hermenegildo GarcÃa Design of cost-efficient and photocatalytically active Zn-based MOFs decorated with Cu 2 O nanoparticles for CO 2 methanation published pages: 10932-10935, ISSN: 1359-7345, DOI: 10.1039/c9cc04446a	Chemical Communications 55/73	2020-01-30
2019	MarÃa Vicent-Morales, IÃ±igo J. VitÃ³rica-YrezÃ¡bal, Manuel Souto, Guillermo MÃnguez Espallargas Influence of interpenetration on the flexibility of MUV-2 published pages: 3031-3035, ISSN: 1466-8033, DOI: 10.1039/c9ce00233b	CrystEngComm 21/19	2020-01-30
2019	Javier LÃ³pez-Cabrelles, Jorge Romero, Gonzalo AbellÃ¡n, MÃ³nica GimÃ©nez-MarquÃ©s, Miguel Palomino, Susana Valencia, Fernando Rey, Guillermo MÃnguez Espallargas Solvent-Free Synthesis of ZIFs: A Route toward the Elusive Fe(II) Analogue of ZIF-8 published pages: 7173-7180, ISSN: 0002-7863, DOI: 10.1021/jacs.9b02686	Journal of the American Chemical Society 141/17	2020-01-30
2018	Julia Miguel-Donet, Javier LÃ³pez-Cabrelles, NÃ©stor Calvoâ€…Galve, Eugenio Coronado, Guillermo MÃnguezâ€…Espallargas Two Consecutive Magneto-Structural Gas-Solid Transformations in Non-Porous Molecular Materials published pages: 12426-12432, ISSN: 0947-6539, DOI: 10.1002/chem.201802510	Chemistry - A European Journal 24/47	2019-10-08
2018	Guillermo MÃnguez Espallargas, Eugenio Coronado Magnetic functionalities in MOFs: from the framework to the pore published pages: 533-557, ISSN: 0306-0012, DOI: 10.1039/c7cs00653e	Chemical Society Reviews 47/2	2019-10-08
2018	Javier Castells-Gil, JosÃ© J. BaldovÃ, Carlos MartÃ-Gastaldo, Guillermo MÃnguez Espallargas Implementation of slow magnetic relaxation in a SIM-MOF through a structural rearrangement published pages: 14734-14740, ISSN: 1477-9226, DOI: 10.1039/c8dt03421d	Dalton Transactions 47/41	2019-10-08
2018	J. LÃ³pez-Cabrelles, S. MaÃ±as-Valero, I. J. VitÃ³rica-YrezÃ¡bal, P. J. Bereciartua, J. A. RodrÃguez-VelamazaÌn, J. C. Waerenborgh, B. J. C. Vieira, D. Davidovikj, P. G. Steeneken, H. S. J. van der Zant, G. MÃnguez Espallargas, E. Coronado Isoreticular two-dimensional magnetic coordination polymers prepared through pre-synthetic ligand functionalization published pages: 1001-1007, ISSN: 1755-4330, DOI: 10.1038/s41557-018-0113-9	Nature Chemistry 10/10	2019-10-08
2018	Manuel Souto, Andrea Santiago-Portillo, Miguel Palomino, IÃ±igo J. VitÃ³rica-YrezÃ¡bal, Bruno J. C. Vieira, JoÃ£o C. Waerenborgh, Susana Valencia, Sergio NavalÃ³n, Fernando Rey, Hermenegildo GarcÃa, Guillermo MÃnguez Espallargas A highly stable and hierarchical tetrathiafulvalene-based metalâ€“organic framework with improved performance as a solid catalyst published pages: 2413-2418, ISSN: 2041-6520, DOI: 10.1039/c7sc04829g	Chemical Science 9/9	2019-10-08
2017	MÃ³nica GimÃ©nez-MarquÃ©s, NÃ©stor Calvo Galve, Miguel Palomino, Susana Valencia, Fernando Rey, GermÃ¡n Sastre, IÃ±igo J. VitÃ³rica-YrezÃ¡bal, MÃ³nica JimÃ©nez-Ruiz, J. Alberto RodrÃguez-VelamazÃ¡n, Miguel A. GonzÃ¡lez, JosÃ© L. JordÃ¡, Eugenio Coronado, Guillermo MÃnguez Espallargas Gas confinement in compartmentalized coordination polymers for highly selective sorption published pages: 3109-3120, ISSN: 2041-6520, DOI: 10.1039/c6sc05122g	Chemical Science 8/4	2019-10-08
2018	Manuel Souto, Jorge Romero, JoaquÃn Calbo, IÃ±igo J. VitÃ³rica-YrezÃ¡bal, JosÃ© L. Zafra, Juan Casado, Enrique OrtÃ, Aron Walsh, Guillermo MÃnguez Espallargas Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metalâ€“Organic Framework published pages: 10562-10569, ISSN: 0002-7863, DOI: 10.1021/jacs.8b05890	Journal of the American Chemical Society 140/33	2019-10-08

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