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IonPEFC

Advanced catalyst electrodes from Ionic liquid modified PtNi nanowire arrays for PEFCs

Total Cost €

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EC-Contrib. €

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Partnership

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 IonPEFC project word cloud

Explore the words cloud of the IonPEFC project. It provides you a very rough idea of what is the project "IonPEFC" about.

transitional    cycles    driving    nanoparticle    operation    gap    nanostructure    stable    industrial    liquid    ionic    hydrophobic    modify    nanowire    conductivity    acid    context    environment    chemistry    international    super    alloyed    situ    employing    effect    difficulty    leaching    diffusivity    washing    conventional    limit    post    substantial    modified    thin    synthesize    ptni    oxygen    film    recent    electrochemical    arrays    engineering    compare    material    protic    nanostructures    structure    nanowires    protect    performance    catalysts    ni    ils    property    durability    synthesis    thermal    annealing    caused    fuel    pt    relationships    pure    dissolution    acidic    life    area    il    catalyst    prepared    cells    improvements    stability    involve    ing    unconventional    pefc    metals    surface    mainly    solubility    automotive    cell    single    electrodes    precious    nonstructures    morphology    loading    extended    proton    ionpefc    enhancement   

Project "IonPEFC" data sheet

The following table provides information about the project.

Coordinator
THE UNIVERSITY OF BIRMINGHAM 

Organization address
address: Edgbaston
city: BIRMINGHAM
postcode: B15 2TT
website: www.bham.ac.uk

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
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 Coordinator Country United Kingdom [UK]
 Project website https://www.birmingham.ac.uk/research/activity/chemical-engineering/energy-chemical/fuel-cells/people/phd/Huixin-Zhang.aspx
 Total cost 195˙454 €
 EC max contribution 195˙454 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2016
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2017
 Duration (year-month-day) from 2017-08-03   to  2019-08-02

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    THE UNIVERSITY OF BIRMINGHAM UK (BIRMINGHAM) coordinator 195˙454.00

Map

 Project objective

Recent developments in PEFC research have seen a significant enhancement of catalyst activities and a reduction of cost at a reduced loading of precious metals by employing novel Pt-based extended surface area nanostructures alloyed with transitional metals, but the low stability caused by the easy dissolution of transitional metals in acidic PEFC environment, and the large difficulty to be integrated into devices due to the unconventional morphology of extended surface area nanostructures as Pt/C nanoparticle catalysts limit them mainly to pure material research, resulting in an increasing gap with real high performance devices.

IonPEFC will bring together the chemistry of nanostructure and ionic liquid (IL) synthesis with the engineering of fuel cells to develop PEFC electrodes with thin film catalyst nonstructures from PtNi nanowire arrays modified by protic ILs, targeting an improved understanding of structure-property relationships of electrodes to build high performance and robust PEFC devices. This will involve 4 research objectives: 1. To develop electrodes with thin film catalyst nanostructures from PtNi nanowire arrays based on the in-situ growing approach and to study the effect of post acid washing and annealing on the surface properties of PtNi nanowires. 2. To synthesize super hydrophobic, electrochemical and thermal stable ILs with high proton conductivity, oxygen solubility and diffusivity. The as-prepared ILs will be used to modify PtNi nanowire electrodes obtained to protect catalyst surface from Ni leaching in fuel cell operation. 3. To test in single cells the as-prepared and IL modified PtNi nanowire electrodes, and compare with conventional Pt/C electrodes. 4. To evaluate the long-term durability of the electrodes under real life-context at different European and international automotive driving cycles with the industrial partner.

It is expected that substantial performance and durability improvements will result from this research.

 Publications

year authors and title journal last update
List of publications.
2019 Min Wang, Huixin Zhang, Gnanavel Thirunavukkarasu, Ihtasham Salam, John R. Varcoe, Peter Mardle, Xiaoying Li, Shichun Mu, Shangfeng Du
Ionic Liquid-Modified Microporous ZnCoNC-Based Electrocatalysts for Polymer Electrolyte Fuel Cells
published pages: 2104-2110, ISSN: 2380-8195, DOI: 10.1021/acsenergylett.9b01407
ACS Energy Letters 4/9 2020-01-27
2019 Huixin Zhang, Jinying Liang, Bangwang Xia, Yang Li, Shangfeng Du
Ionic liquid modified Pt/C electrocatalysts for cathode application in proton exchange membrane fuel cells
published pages: , ISSN: 2095-0179, DOI: 10.1007/s11705-019-1838-8
Frontiers of Chemical Science and Engineering 2020-01-27

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