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LiDeNiAc SIGNED

Ligand Design for Nitrogen Activation

Total Cost €

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EC-Contrib. €

0

Partnership

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 LiDeNiAc project word cloud

Explore the words cloud of the LiDeNiAc project. It provides you a very rough idea of what is the project "LiDeNiAc" about.

profile    opportunity    skills    host    sharpen    homogenous    contrast    ammonia    combining    bacteria    materials    intensive    last    solution    links    manner    bosch    potent    industrially    line    complexes    plants    ligands    class    assimilated    n2    collaborative    emissions    applicants    feed    chemistry    atmospheric    environmental    plays    optimize    leadership    molybdenum    reactive    massive    co2    researcher    electronic    metals    donor    vital    activation    population    fix    interdisciplinary    crops    sustainable    utilize    accompanied    acquire    career    global    structure    resource    synthesized    incorporating    training    vanadium    dinitrogen    sub    haber    phosphaalkenes    metal    benefit    polydendate    subsequent    quality    efficient    platform    energy    valent    mild    renewable    inorganic    catalysis    usually    transition    stabilize    disciplines    lower    tested    functionalization    flagship    nitrogen    sufficient    harsh    comprehensively    bio    explore   

Project "LiDeNiAc" data sheet

The following table provides information about the project.

Coordinator
LEIBNIZ - INSTITUT FUR KATALYSE EV AN DER UNIVERSITAT ROSTOCK 

Organization address
address: ALBERT-EINSTEIN-STRASSE 29A
city: ROSTOCK
postcode: 18059
website: www.catalysis.de

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Germany [DE]
 Total cost 171˙460 €
 EC max contribution 171˙460 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2017
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2018
 Duration (year-month-day) from 2018-06-01   to  2020-05-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    LEIBNIZ - INSTITUT FUR KATALYSE EV AN DER UNIVERSITAT ROSTOCK DE (ROSTOCK) coordinator 171˙460.00

Map

 Project objective

Nitrogen plays a vital role in the production of sufficient crops to feed a growing global population. While atmospheric nitrogen cannot be directly assimilated by plants, bacteria can fix nitrogen under mild conditions to provide bio-available ammonia. In contrast, industrially ammonia is produced under harsh conditions in the Haber Bosch process, which is energy intensive and accompanied by massive emissions of CO2. Therefore, this project seeks to explore more sustainable pathways of dinitrogen activation and its subsequent functionalization. The utilization of renewable N2 is also in line with the “Resource-efficient Europe” flagship initiatives to optimize the use of materials in order to lower the environmental impact. Systems capable of dinitrogen activation in homogenous solution usually build on highly reduced transition metal complexes. In the proposed studies a novel class of polydendate ligands incorporating phosphaalkenes as a design feature will be synthesized to provide a potent platform for further functionalization. The experienced researcher will utilize these ligands as a donor to stabilize low-valent, highly reactive complexes of the bio-relevant metals molybdenum and vanadium. In a last step these systems will be tested in the activation of dinitrogen and their electronic structure will be comprehensively characterized, in a collaborative manner within the host institute, providing the applicant with high-quality technical training. The project links various sub-disciplines of chemistry and is therefore clearly interdisciplinary, combining the applicants experience in inorganic chemistry with the host-institute’s leadership in catalysis. It is therefore expected that the proposed studies represent an opportunity for the experienced researcher to acquire new skills in the design of ligands for novel complexes capable of nitrogen activation, which is expected to further sharpen the researcher's profile and to benefit his future career.

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The information about "LIDENIAC" are provided by the European Opendata Portal: CORDIS opendata.

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