CANIOC

Chemical bonding and aromaticity in novel inorganic and organometallic clusters

Coordinatore	UNIVERSITAT DE GIRONA    more  Organization address address: PLACA SANT DOMENEC 9 EDIFICI LES ALIGUES city: GIRONA postcode: 17071 contact info Titolo: Dr. Nome: Montserrat Cognome: Estopa Bagot Email: send email Telefono: +34 972 419 745 Fax: +34 972 418 896
Nazionalità Coordinatore	Spain [ES]
Totale costo	90˙000 €
EC contributo	90˙000 €
Programma	FP7-PEOPLE Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)
Code Call	FP7-PEOPLE-2009-IRSES
Funding Scheme	MC-IRSES
Anno di inizio	2011
Periodo (anno-mese-giorno)	2011-01-01   -   2014-12-31

 Partecipanti

#	participant	country	role	EC contrib. [€]
1	UNIVERSITAT DE GIRONA  Organization address address: PLACA SANT DOMENEC 9 EDIFICI LES ALIGUES city: GIRONA postcode: 17071 contact info Titolo: Dr. Nome: Montserrat Cognome: Estopa Bagot Email: send email Telefono: +34 972 419 745 Fax: +34 972 418 896	ES (GIRONA)	coordinator	64˙800.00
2	STICHTING VU-VUMC  Organization address address: DE BOELELAAN 1105 city: AMSTERDAM postcode: 1081 HV contact info Titolo: Dr. Nome: Yvonne Cognome: Kops Email: send email Telefono: +31 20 5987500	NL (AMSTERDAM)	participant	25˙200.00
3	VERENIGING VOOR CHRISTELIJK HOGER ONDERWIJS WETENSCHAPPELIJK ONDERZOEK EN PATIENTENZORG  Organization address address: De Boelelaan 1105 city: AMSTERDAM postcode: 1081 HV contact info Titolo: Prof. Nome: Matthias Cognome: Bickelhaupt Email: send email Telefono: +31 205987617	NL (AMSTERDAM)	participant	0.00

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 Obiettivo del progetto (Objective)

'Clusters behave as a link between the atom and the bulk material. They exhibit characteristics of both forms of matter, depending on their size and their molecular and electronic structures. Such molecules can be potentially useful for technical applications as specific and very efficient catalysts, drugs, and other novel materials with as yet unimagined properties. As an example, the continued miniaturization of electronic devices is pushing towards the nano- and molecular scales. In this sense, silicon clusters can be very important in the future development of the electronic industry. Other clusters are expected to have relevant catalytic or magnetic properties. All-metal and semi-metal clusters have been recently discovered. The unusual stability of all these clusters comes from their aromatic character. Indeed, the aromaticity is a key property of these compounds since it explains their stability and reactivity. As compared to the classical aromatic organic molecules, that possess only π-electron delocalization, the aromaticity in inorganic clusters is more complex. These compounds have σ- and π- (or even δ-) electron delocalization, thus giving rise to the so-called multifold aromaticity. All-metal and semimetal aromatic clusters represent one of the “new frontiers” of chemistry (the first of such clusters was discovered in 2001). It is expected that understanding the origin of aromaticity in these systems will help us to comprehend the factors that govern structural patterns and stability in solids. In addition, these novel materials are expected to have as-yet unimagined properties such as, for instance, nanodevices, intense non linear optical properties, high catalytic power and efficiency, and utility as possible drugs.'