Explore the words cloud of the IILSCFLP project. It provides you a very rough idea of what is the project "IILSCFLP" about.
The following table provides information about the project.
Coordinator |
IMPERIAL COLLEGE OF SCIENCE TECHNOLOGY AND MEDICINE
Organization address contact info |
Coordinator Country | United Kingdom [UK] |
Total cost | 195˙454 € |
EC max contribution | 195˙454 € (100%) |
Programme |
1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility) |
Code Call | H2020-MSCA-IF-2014 |
Funding Scheme | MSCA-IF-EF-ST |
Starting year | 2015 |
Duration (year-month-day) | from 2015-10-01 to 2017-09-30 |
Take a look of project's partnership.
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1 | IMPERIAL COLLEGE OF SCIENCE TECHNOLOGY AND MEDICINE | UK (LONDON) | coordinator | 195˙454.00 |
Hydrogen (H2) is an important reagent for the chemical industry as well as representing a promising carbon-free fuel source when made from renewable sources. H2 needs to be activated for these applications, generally using rare, expensive and often toxic transition metal catalysts. Metal-free H2 activation has recently been demonstrated using the concept of ‘frustrated Lewis pairs’ (FLPs) based on main group elements such as phosphorous and boron rather than transition metals. FLPs are somewhat limited in scope due to the highly reactive Lewis acids (LAs) and bases (LBs) required for H2 activation which can lead to side reactions with substrates and solvents. The use of less reactive FLPs is restricted by the H2 activation step. This project addresses this problem by using the unique solvating ability of ionic liquids (ILs) to control the reactivity of FLPs for H2 activation. Many FLPs form ions when they react with H2. To promote H2 activation, it is essential that the reverse reaction (ion recombination to form H2) is prevented. The high ion dissociation power of ILs should prevent the recombination of these ions, leading to more efficient H2 activation. The impact of ILs on H2 activation by FLPs will be investigated in the context of synthesis and fuel cell applications. Successful use of ILs for this purpose would substantially increase the scope of FLP catalysts, reducing the reliance on transition metals thereby decreasing the potential cost and environmental impact of H2 activation processes. This project would represent the first study on the effect of ILs on FLP reactivity and combines the collective expertise of Prof. Welton (ILs) and Dr Ashley (FLPs) at Imperial College (IC) with the applicant’s background in ILs, kinetics and intermolecular interactions, while providing the applicant with productive collaborative partners and advanced training in catalysis, electrochemistry, IL and FLP chemistry to propel him towards an independent research career.
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The information about "IILSCFLP" are provided by the European Opendata Portal: CORDIS opendata.
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