Supramol SIGNED
Towards Artificial Enzymes: Bio-inspired Oxidations in Photoactive Metal-Organic Frameworks
Total Cost €
0EC-Contrib. €
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Project "Supramol" data sheet
The following table provides information about the project.
| Coordinator |
THE PROVOST, FELLOWS, FOUNDATION SCHOLARS & THE OTHER MEMBERS OF BOARD OF THE COLLEGE OF THE HOLY & UNDIVIDED TRINITY OF QUEEN ELIZABETH NEAR DUBLIN
Organization address contact info |
| Coordinator Country | Ireland [IE] |
| Total cost | 1˙979˙366 € |
| EC max contribution | 1˙979˙366 € (100%) |
| Programme |
1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC)) |
| Code Call | ERC-2014-CoG |
| Funding Scheme | ERC-COG |
| Starting year | 2015 |
| Duration (year-month-day) | from 2015-09-01 to 2020-08-31 |
Partnership
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| # | ||||
|---|---|---|---|---|
| 1 | THE PROVOST, FELLOWS, FOUNDATION SCHOLARS & THE OTHER MEMBERS OF BOARD OF THE COLLEGE OF THE HOLY & UNDIVIDED TRINITY OF QUEEN ELIZABETH NEAR DUBLIN | IE (DUBLIN) | coordinator | 1˙979˙366.00 |
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Project objective
Metal-organic frameworks (MOFs) are key compounds related to energy storage and conversion, as their unprecedented surface areas make them promising materials for gas storage and catalysis purposes. We believe that their modular construction principles allow the replication of key features of natural enzymes thus demonstrating how cavity size, shape, charge and functional group availability influence the performances in catalytic reactions. This proposal addresses the question of how such novel, bio-inspired metallo-supramolecular systems can be prepared and exploited for sustainable energy applications. A scientific breakthrough that demonstrates the efficient conversion of light into chemical energy would be one of the greatest scientific achievements with unprecedented impact to future generations. We focus on the following key aspects:
a) MOFs containing novel, catalytically active complexes with labile coordination sites will be synthesised using rigid organic ligands that allow us to control the topologies, cavity sizes and surface areas. We will incorporate photosensitizers to develop robust porous MOFs in which light-absorption initiates electron-transfer events that lead to the activation of a catalytic centre. In addition, photoactive molecules will serve as addressable ligands whereby reversible, photo-induced structural transformations impose changes to porosity and chemical attributes at the active sites.
b) Catalytic studies will focus on important oxidations of alkenes and alcohols. These reactions are relevant to H2-based energy concepts as the anodic liberation of protons and electrons can be coupled to their cathodic recombination to produce H2. The studies will provide proof-of-concept for the development of photocatalytic systems for the highly endergonic H2O oxidation reaction that will be explored using most stable MOFs. Further, gas storage and magnetic properties that may also be influenced by light-irradiation will be analysed.
Publications
| year | authors and title | journal | last update |
|---|---|---|---|
| 2019 |
Debobroto Sensharma, Nianyong Zhu, Swetanshu Tandon, Sebastien Vaesen, Graeme W. Watson, Wolfgang Schmitt Flexible Metal–Organic Frameworks for Light-Switchable CO 2 Sorption Using an Auxiliary Ligand Strategy published pages: 9766-9772, ISSN: 0020-1669, DOI: 10.1021/acs.inorgchem.9b00768 |
Inorganic Chemistry 58/15 | 2020-01-29 |
| 2019 |
Tian Wen, Wolfgang Schmitt, Lei Zhang An Fe( iii )-doped coordination polymer of Mn 13 -clusters with improved activity for the oxygen reduction reaction published pages: 4794-4797, ISSN: 1477-9226, DOI: 10.1039/c9dt00199a |
Dalton Transactions 48/15 | 2020-01-29 |
| 2019 |
Colm Healy, Friedrich W. Steuber, Paul Wix, Lauren K. Macreadie, Amal Cherian Kathalikkattil, Wolfgang Schmitt Assembly, disassembly and reassembly: a “top-down†synthetic strategy towards hybrid, mixed-metal {Mo 10 Co 6 } POM clusters published pages: 3018-3027, ISSN: 1477-9226, DOI: 10.1039/c9dt00075e |
Dalton Transactions 48/9 | 2020-01-29 |
| 2019 |
Aramballi J. Savyasachi, David F. Caffrey, Kevin Byrne, Gerard Tobin, Bruno D’Agostino, Wolfgang Schmitt, Thorfinnur Gunnlaugsson Self-assembled bright luminescent hierarchical materials from a tripodal benzoate antenna and heptadentate Eu(III) and Tb(III) cyclen complexes published pages: 171-184, ISSN: 2095-0179, DOI: 10.1007/s11705-018-1762-3 |
Frontiers of Chemical Science and Engineering 13/1 | 2020-01-29 |
| 2018 |
Debobroto Sensharma, Paul Wix, Amal Cherian Kathalikkattil, Wolfgang Schmitt Passing it up the ranks: hierarchical ion-size dependent supramolecular response in 1D coordination polymers published pages: 5127-5131, ISSN: 1466-8033, DOI: 10.1039/c8ce01211c |
CrystEngComm 20/35 | 2020-01-29 |
| 2019 |
Michael John Craig, Gabriel Coulter, Eoin Dolan, JoaquÃn Soriano-López, Eric Mates-Torres, Wolfgang Schmitt, Max GarcÃa-Melchor Universal scaling relations for the rational design of molecular water oxidation catalysts with near-zero overpotential published pages: , ISSN: 2041-1723, DOI: 10.1038/s41467-019-12994-w |
Nature Communications 10/1 | 2020-01-29 |
| 2018 |
Tian Wen, Lei Zhang, Wolfgang Schmitt A Mn 13 -cluster based coordination polymer as a co-catalyst of CdS for enhanced visible-light driven H 2 evolution published pages: 10857-10860, ISSN: 1477-9226, DOI: 10.1039/c8dt01755g |
Dalton Transactions 47/32 | 2020-01-29 |
| 2019 |
Luana Martins, Lauren K. Macreadie, Debobroto Sensharma, Sebastien Vaesen, Xia Zhang, John J. Gough, Mariah O\'Doherty, Nian-Yong Zhu, Manuel Rüther, John E. O\'Brien, A. Louise Bradley, Wolfgang Schmitt Light-harvesting, 3rd generation Ru II /Co II MOF with a large, tubular channel aperture published pages: 5013-5016, ISSN: 1359-7345, DOI: 10.1039/c9cc00206e |
Chemical Communications 55/34 | 2020-01-29 |
| 2019 |
Daniel T. Payne, Whitney A. Webre, Yoshitaka Matsushita, Nianyong Zhu, Zdenĕk Futera, Jan Labuta, Wipakorn Jevasuwan, Naoki Fukata, John S. Fossey, Francis D’Souza, Katsuhiko Ariga, Wolfgang Schmitt, Jonathan P. Hill Multimodal switching of a redox-active macrocycle published pages: , ISSN: 2041-1723, DOI: 10.1038/s41467-019-08978-5 |
Nature Communications 10/1 | 2020-01-29 |
| 2019 |
Guanghua Jin, Debobroto Sensharma, Nianyong Zhu, Sebastien Vaesen, Wolfgang Schmitt A highly augmented, (12,3)-connected Zr-MOF containing hydrated coordination sites for the catalytic transformation of gaseous CO 2 to cyclic carbonates published pages: 15487-15492, ISSN: 1477-9226, DOI: 10.1039/c9dt02117e |
Dalton Transactions 48/41 | 2020-01-29 |
| 2017 |
Ayuk M. Ako, Chris S. Hawes, Brendan Twamley, Wolfgang Schmitt Facile adaptation of 1D Mn( ii ) chain motifs to form 3D azo-pyridine-based coordination polymers published pages: 994-1000, ISSN: 1466-8033, DOI: 10.1039/C6CE02493A |
CrystEngComm 19/6 | 2019-06-06 |
| 2018 |
Amy D. Lynes, Chris S. Hawes, Kevin Byrne, Wolfgang Schmitt, Thorfinnur Gunnlaugsson Coordination chemistry of flexible benzene-1,3,5-tricarboxamide derived carboxylates; notable structural resilience and vaguely familiar packing motifs published pages: 5259-5268, ISSN: 1477-9226, DOI: 10.1039/C8DT00439K |
Dalton Transactions 47/15 | 2019-06-06 |
| 2017 |
Marcel Klein-Hitpaß, Amy D. Lynes, Chris S. Hawes, Kevin Byrne, Wolfgang Schmitt, Thorfinnur Gunnlaugsson A Schiff-base cross-linked supramolecular polymer containing diiminophenol compartments and its interaction with copper(II) ions published pages: 93-102, ISSN: 1061-0278, DOI: 10.1080/10610278.2017.1362108 |
Supramolecular Chemistry 30/2 | 2019-06-06 |
| 2018 |
Colm Healy, Wolfgang Schmitt Multicomponent halide templating: The effect of structure-directing agents on the assembly of molecular and extended coordination compounds published pages: 67-85, ISSN: 0010-8545, DOI: 10.1016/j.ccr.2018.05.014 |
Coordination Chemistry Reviews 371 | 2019-06-06 |
| 2017 |
Amy D. Lynes, Chris S. Hawes, Edward N. Ward, Benjamin Haffner, Matthias E. Möbius, Kevin Byrne, Wolfgang Schmitt, Robert Pal, Thorfinnur Gunnlaugsson Benzene-1,3,5-tricarboxamide n-alkyl ester and carboxylic acid derivatives: tuneable structural, morphological and thermal properties published pages: 1427-1438, ISSN: 1466-8033, DOI: 10.1039/C7CE00206H |
CrystEngComm 19/10 | 2019-06-06 |
| 2016 |
Nianyong Zhu, Debobroto Sensharma, Paul Wix, Matthew J. Lennox, Tina Düren, Wai-Yeung Wong, Wolfgang Schmitt Framework Isomerism: Highly Augmented Copper(II)-Paddlewheel-ÂBased MOF with Unusual (3,4)-Net Topology published pages: 1939-1943, ISSN: 1434-1948, DOI: 10.1002/ejic.201501194 |
European Journal of Inorganic Chemistry 2016/13-14 | 2019-06-06 |
| 2016 |
Chris S. Hawes, Kevin Byrne, Wolfgang Schmitt, Thorfinnur Gunnlaugsson Flexible Porous Coordination Polymers from Divergent Photoluminescent 4-Oxo-1,8-naphthalimide Ligands published pages: 11570-11582, ISSN: 0020-1669, DOI: 10.1021/acs.inorgchem.6b02137 |
Inorganic Chemistry 55/21 | 2019-06-06 |
| 2017 |
Bartosz Marzec, Lei Zhang, Nianyong Zhu, Wolfgang Schmitt Bio-inspired synthetic approaches: from hierarchical, hybrid supramolecular assemblies to CaCO 3 -based microspheres published pages: , ISSN: 1477-9226, DOI: 10.1039/C7DT00914C |
Dalton Trans. | 2019-06-06 |
| 2016 |
Lei Zhang, Theresa Chimamkpam, Camelia I. Onet, Nianyong Zhu, Rodolphe Clérac, Wolfgang Schmitt Anion-directed supramolecular chemistry modulating the magnetic properties of nanoscopic Mn coordination clusters: from polynuclear high-spin complexes to SMMs published pages: 17705-17713, ISSN: 1477-9226, DOI: 10.1039/C6DT02642G |
Dalton Trans. 45/44 | 2019-06-06 |
| 2017 |
Chris S. Hawes, Amy D. Lynes, Kevin Byrne, Wolfgang Schmitt, Gavin Ryan, Matthias E. Möbius, Thorfinnur Gunnlaugsson A resilient and luminescent stimuli-responsive hydrogel from a heterotopic 1,8-naphthalimide-derived ligand published pages: 5989-5992, ISSN: 1359-7345, DOI: 10.1039/c7cc03482b |
Chemical Communications 53/44 | 2019-06-06 |
| 2017 |
Colm Healy, Brendan Twamley, Munuswamy Venkatesan, Sebastian Schmidt, Thorfinnur Gunnlaugsson, Wolfgang Schmitt Hetero-metallic, functionalizable polyoxomolybdate clusters via a “top-down†synthetic method published pages: 10660-10663, ISSN: 1359-7345, DOI: 10.1039/C7CC05498J |
Chemical Communications 53/77 | 2019-06-06 |
| 2018 |
JoaquÃn Soriano-López, Wolfgang Schmitt, Max GarcÃa-Melchor Computational modelling of water oxidation catalysts published pages: 22-30, ISSN: 2451-9103, DOI: 10.1016/j.coelec.2017.10.001 |
Current Opinion in Electrochemistry 7 | 2019-06-06 |
| 2018 |
Debobroto Sensharma, Sebastien Vaesen, Colm Healy, Jens Hartmann, Amal Cherian Kathalikkattil, Paul Wix, Friedrich Steuber, Nianyong Zhu, Wolfgang Schmitt CO 2 Adsorption in SIFSIX-14-Cu-i: High Performance, Inflected Isotherms, and Water-Triggered Release via Reversible Structural Transformation published pages: 1993-1997, ISSN: 1434-1948, DOI: 10.1002/ejic.201800217 |
European Journal of Inorganic Chemistry 2018/19 | 2019-06-06 |
| 2017 |
Kevin Byrne, Muhammad Zubair, Nianyong Zhu, Xiao-Ping Zhou, Daniel S. Fox, Hongzhou Zhang, Brendan Twamley, Matthew J. Lennox, Tina Düren, Wolfgang Schmitt Ultra-large supramolecular coordination cages composed of endohedral Archimedean and Platonic bodies published pages: 15268, ISSN: 2041-1723, DOI: 10.1038/ncomms15268 |
Nature Communications 8 | 2019-06-06 |
| 2016 |
Theresa O. Chimamkpam, Rodolphe Clérac, Dmitri Mitcov, Brendan Twamley, Munuswamy Venkatesan, Wolfgang Schmitt Structural variation in cation-assisted assembly of high-nuclearity Mn arsonate and phosphonate wheels published pages: 1349-1353, ISSN: 1477-9226, DOI: 10.1039/C5DT04820F |
Dalton Trans. 45/4 | 2019-06-06 |
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