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MOFMAP

Tailored Metal-Organic Framework: From Hybrid to Multifunctional Flame Retardant Polymer Nanocomposites

Total Cost €

EC-Contrib. €

Partnership

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Outcomes and
results

MOFMAP project word cloud

Explore the words cloud of the MOFMAP project. It provides you a very rough idea of what is the project "MOFMAP" about.

delay chemical new environmentally interaction thermal heat released property matrices gas loading stage flammable excellent electronic fe multfunctional employed effect pore additives smoke generation mof antistatic compounds conductivities metal first container room hinder intensity serve ignition hybrid retardant gases temperature nanocomposites decomposed combining functionalized combined surpassing intrinsic host catalytic function groups release slow aerospace transportation simultaneously stored polymer fire retardants innovative organic functional polymeric format introducing materials particles chosen rate time graphene char decrease mechanical layer functions construct enhanced combustion conductivity construction hybridization mil framework promise flame 101

Project "MOFMAP" data sheet

The following table provides information about the project.

Coordinator	FUNDACION IMDEA MATERIALES Organization address address: CALLE ERIC KANDEL 2 PARQUE CIENTIFICO Y TECNOLOGICO TECNOGETAFE city: GETAFE postcode: 28906 website: www.materials.imdea.org contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.
Coordinator Country	Spain [ES]
Project website	http://www.materials.imdea.org/groups/hppn/project/mofmap/
Total cost	170˙121 €
EC max contribution	170˙121 € (100%)
Programme	1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
Code Call	H2020-MSCA-IF-2015
Funding Scheme	MSCA-IF-EF-ST
Starting year	2017
Duration (year-month-day)	from 2017-01-09 to 2019-01-08

Partnership

Take a look of project's partnership.

#	participants	country	role	EC contrib. [€]
1	FUNDACION IMDEA MATERIALES FUNDACION IMDEA MATERIALES Organization address address: CALLE ERIC KANDEL 2 PARQUE CIENTIFICO Y TECNOLOGICO TECNOGETAFE city: GETAFE postcode: 28906 website: www.materials.imdea.org contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	ES (GETAFE)	coordinator	170˙121.00

Map

Project objective

The main objective of this work is to develop new generation polymer-based multi-functional nanocomposites by combining functionalized Metal-Organic Framework (MOF) and graphene hybrid into polymeric matrices via an innovative approach. In this work, MOF is employed to develop multfunctional flame retardant polymer nanocomposites for the first time. The environmentally friendly framework MIL-101-Fe is chosen as the host framework. By introducing functional groups into the framework, MOF particles can be combined with both graphene and polymeric matrices via chemical interaction, to construct polymer nanocomposites which have multi-functions including improved antistatic property, mechanical reinforcement, enhanced thermal conductivity and excellent flame retardant properties, simultaneously. By loading non-flammable gas and/or effective flame retardant into the pore system, MOF can serve as flame retardants container at room temperature. By hybridization with MOF, the intrinsic function of graphene such as electronic and thermal conductivities will be combined into the MOF/graphene hybrid. Far different from present flame retardant additives, in proposed polymer nanocomposites, functionalized MOF hybrid will hinder or slow down the combustion process in different format through the whole combustion process, surpassing other flame retardant systems. At the early fire stage (Ignition), the non-flammable gases stored in MOF will be released to delay the ignition; at the developing fire stage, the graphene layer and char formation will delay the time to developed combustion; at the developed fire stage, the catalytic effect of metal compounds generated by decomposed MOF will decrease the heat release rate, fire growth intensity, smoke production, etc. The new knowledge and new materials developed in this proposal has the promise to be applied in developing new generation products in the fields of the construction, transportation, aerospace, etc, in the future.

Publications

List of publications.
year	authors and title	journal	last update
2019	Nerea PÃ©rez, Xiao-Lin Qi, Shibin Nie, Pablo AcuÃ±a, Ming-Jun Chen, De-Yi Wang Flame Retardant Polypropylene Composites with Low Densities published pages: 152, ISSN: 1996-1944, DOI: 10.3390/ma12010152	Materials 12/1	2019-07-26
2018	Xiao-Lin QI, Shuang HU, De-Yi WANG Multifunctional polymer composites with metal-organic framework published pages: , ISSN: , DOI:		2019-07-26

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The information about "MOFMAP" are provided by the European Opendata Portal: CORDIS opendata.