Explore the words cloud of the SINMOF project. It provides you a very rough idea of what is the project "SINMOF" about.
The following table provides information about the project.
Coordinator |
KATHOLIEKE UNIVERSITEIT LEUVEN
Organization address contact info |
Coordinator Country | Belgium [BE] |
Project website | http://sinmof.blogspot.com/ |
Total cost | 160˙800 € |
EC max contribution | 160˙800 € (100%) |
Programme |
1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility) |
Code Call | H2020-MSCA-IF-2016 |
Funding Scheme | MSCA-IF-EF-ST |
Starting year | 2017 |
Duration (year-month-day) | from 2017-06-01 to 2019-05-31 |
Take a look of project's partnership.
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1 | KATHOLIEKE UNIVERSITEIT LEUVEN | BE (LEUVEN) | coordinator | 160˙800.00 |
SINMOF is a pioneering and structured effort to comprehensively address the introduction of different immobilised isolated catalytic active sites in solid hybrid materials to overcome the metal losses occurring with state-of-the-art homogeneous catalysts employed in the pharmaceutical industry. The convenient use of hybrid metal-organic framework materials (MOFs) respect to traditional state-of-the-art porous solid materials is due to (a) self-deactivation-resistant design of the active sites by (b) ultrastable catalytic site isolation. In the SINMOF project we will (1) design novel multifunctional MOFs as next generation catalysts for the synthesis of pharmaceutically active compounds in an economically and environmentally beneficial way; (2) apply MOF hybrid solids as heterogeneous catalysts to avoid the use of homogeneous metal catalysts in novel synthetic strategies of pharmaceuticals with the indole core and finally (3) derive structure-activity and selectivity relationships at the smallest possible length scales and with the highest possible sensitivities employing fluorescence microscopy. Using a two-stage research methodology, SINMOF will finally provide the most active and stable MOF catalyst for the synthesis of the indole-based neurotransmitter Sumatriptan and the anticancerigen spirooxindole SAR405838. The combined expertise of the fellow and host ensures the best chance for successfully completing the SINMOF objectives in a mutually beneficial manner. On one side, internal collaborations at the host institution will allow the access to state-of-the-art fluorescence microscopy methods, to get new insights into the molecular mechanisms underlying the novel catalytic systems. On the other side, a secondment at a world-leading research center in the homogeneous catalysis field will train the researcher in order to individuate the best molecular features for model homogeneous catalysts to be translated into selective heterogeneous MOF catalytic system.
year | authors and title | journal | last update |
---|---|---|---|
2018 |
Cédric Van Goethem, Matthias Mertens, Francisco G. Cirujano, Jin W. Seo, Dirk De Vos, Ivo F. J. Vankelecom Improved MOF nanoparticle recovery and purification using crosslinked PVDF membranes published pages: 7370-7373, ISSN: 1359-7345, DOI: 10.1039/c8cc04326d |
Chemical Communications 54/53 | 2020-01-21 |
2019 |
Chunmei Jia, Francisco G. Cirujano, Bart Bueken, Birgit Claes, Dries Jonckheere, Kevin M. Van Geem, Dirk De Vos Geminal Coordinatively Unsaturated Sites on MOFâ€808 for the Selective Uptake of Phenolics from a Real Bioâ€Oil Mixture published pages: 1256-1266, ISSN: 1864-5631, DOI: 10.1002/cssc.201802692 |
ChemSusChem 12/6 | 2020-01-21 |
2019 |
Chunmei Jia, Bart Bueken, Francisco G. Cirujano, Kevin M. Van Geem, Dirk De Vos Phenolics isolation from bio-oil using the metal–organic framework MIL-53(Al) as a highly selective adsorbent published pages: 6245-6248, ISSN: 1359-7345, DOI: 10.1039/c9cc02177a |
Chemical Communications 55/44 | 2020-01-21 |
2017 |
Maxime Stalpaert, Francisco G. Cirujano, Dirk E. De Vos Tetrabutylphosphonium Bromide Catalyzed Dehydration of Diols to Dienes and Its Application in the Biobased Production of Butadiene published pages: 5802-5809, ISSN: 2155-5435, DOI: 10.1021/acscatal.7b01765 |
ACS Catalysis 7/9 | 2020-01-21 |
2019 |
Carlos Marquez, Francisco G. Cirujano, Simon Smolders, Cédric Van Goethem, Ivo Vankelecom, Dirk De Vos, Trees De Baerdemaeker Metal ion exchange in Prussian blue analogues: Cu( ii )-exchanged Zn–Co PBAs as highly selective catalysts for A 3 coupling published pages: 3946-3954, ISSN: 1477-9226, DOI: 10.1039/c9dt00388f |
Dalton Transactions 48/12 | 2020-01-21 |
2018 |
Carlos Marquez, Francisco G. Cirujano, Cédric Van Goethem, Ivo Vankelecom, Dirk De Vos, Trees De Baerdemaeker Tunable Prussian blue analogues for the selective synthesis of propargylamines through A 3 coupling published pages: 2061-2065, ISSN: 2044-4753, DOI: 10.1039/c8cy00073e |
Catalysis Science & Technology 8/8 | 2020-01-21 |
2017 |
Francisco G Cirujano, Elena Lópezâ€Maya, Marleny RodrÃguezâ€Albelo, Elisa Barea, Jorge AR Navarro, Dirk E De Vos Selective Oneâ€Pot Twoâ€Step C− C Bond Formation using Metal–Organic Frameworks with Mild Basicity as Heterogeneous Catalysts published pages: , ISSN: 1867-3899, DOI: |
chemcatchem | 2020-01-21 |
2017 |
FG Cirujano MOFs vs. zeolites: carbonyl activation with M (IV) catalytic sites published pages: , ISSN: 2044-4761, DOI: |
Catalysis Science & Technology | 2020-01-21 |
2017 |
Francisco G Cirujano, Ignacio Luz, Mustapha Soukri, Cedric Van Goethem, Ivo FJ Vankelecom, Marty Lail, Dirk E De Vos Boosting the catalytic performance of metal–organic frameworks for steroid transformations by confinement within a mesoporous scaffold published pages: , ISSN: 1521-3773, DOI: |
Angewandte Chemie Int Ed | 2020-01-21 |
2018 |
Francisco G Cirujano, Maxime Stalpaert, Dirk E De Vos Ionic liquids vs. microporous solids as reusable reaction media for the catalytic C–H functionalization of indoles with alcohols published pages: , ISSN: 1463-9270, DOI: |
Green chemistry | 2020-01-21 |
2018 |
Francisco G Cirujano, Elena López-Maya, JAR Navarro, Dirk E De Vos Pd (II)–Ni (II) Pyrazolate Framework as Active and Recyclable Catalyst for the Hydroamination of Terminal Alkynes published pages: , ISSN: 1022-5528, DOI: |
Topics in Catalysis | 2020-01-21 |
2019 |
F G Cirujano Engineered MOFs and Enzymes for the Synthesis of Active Pharmaceutical Ingredients published pages: , ISSN: 1867-3899, DOI: |
chemcatchem | 2020-01-21 |
2018 |
Francisco G Cirujano, Pedro Leo, Jannick Vercammen, Simon Smolders, Gisela Orcajo, Dirk E De Vos MOFs Extend the Lifetime of Pd (II) Catalyst for Room Temperature Alkenylation of Enamineâ€Like Arenes published pages: , ISSN: 1615-4169, DOI: |
Advanced Synthesis & Catalysis | 2020-01-21 |
2019 |
Nuria Martin, Michiel Dusselier, Dirk E De Vos, Francisco G Cirujano Metal-Organic Framework Derived Metal Oxide Clusters in Porous Aluminosilicates: A Catalyst Design for the Synthesis of Bioactive aza-Heterocycles published pages: , ISSN: 2155-5435, DOI: |
ACS Catalysi | 2020-01-21 |
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