ADSORPLAYERS

"Adsorbed Layers of Natural Organic Macromolecules on Solid Substrates: Structure, Interactions, and Mechanisms of Growth"

 Coordinatore UNIVERSITE DE GENEVE 

 Organization address address: Rue du General Dufour 24
city: GENEVE
postcode: 1211

contact info
Titolo: Prof.
Nome: Michal
Cognome: Borkovec
Email: send email
Telefono: +41 22 3796405
Fax: +41 22 3796069

 Nazionalità Coordinatore Switzerland [CH]
 Totale costo 184˙709 €
 EC contributo 184˙709 €
 Programma FP7-PEOPLE
Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)
 Code Call FP7-PEOPLE-2012-IEF
 Funding Scheme MC-IEF
 Anno di inizio 2013
 Periodo (anno-mese-giorno) 2013-05-01   -   2015-04-30

 Partecipanti

# participant  country  role  EC contrib. [€] 
1    UNIVERSITE DE GENEVE

 Organization address address: Rue du General Dufour 24
city: GENEVE
postcode: 1211

contact info
Titolo: Prof.
Nome: Michal
Cognome: Borkovec
Email: send email
Telefono: +41 22 3796405
Fax: +41 22 3796069

CH (GENEVE) coordinator 184˙709.40

Mappa


 Word cloud

Esplora la "nuvola delle parole (Word Cloud) per avere un'idea di massima del progetto.

layer    organic    engineered    surface    physicochemical    forces    fouling    surfaces    mechanism    structure    substances    force    adsorption    environmental    water   

 Obiettivo del progetto (Objective)

'Surface adsorption of organic substances in aqueous solutions is a ubiquitous mechanism that affects many environmental processes, such as fate and transport of contaminants. In engineered systems, adsorption of organic molecules causes fouling and prompts biofilm formation. Fouling is a major impediment to the successful development of membrane technology to increase the supply of safe water. Control of surface adsorption in aquatic systems requires fundamental knowledge of the physicochemical interactions at water-solid interfaces. The objective of this study is to understand the mechanism of adsorption of humic substances and polysaccharides onto surfaces with well-defined surface composition. In particular, the substrate chemistry will be tailored to represent environmentally relevant surfaces. Surface adsorption/desorption will be investigated either by optical reflectometry or surface plasmon resonance under varying physicochemical conditions. The layer structure, hydration, and conformational properties will be analyzed by surface topography and using the quartz crystal microbalance (QCM). The atomic force microscope (AFM) will be used to image the lateral structure of the adsorbed layers, while the interaction forces involving the dissolved natural compounds and surfaces will be studied by direct force measurements. Using the latter technique, both the adhesion mechanism and the mechanical properties of the organic layer will be investigated using a colloidal probe and tip-surface geometry, respectively. This protocol will allow systematic investigation of the physicochemical determinants of film development and conformation. The experimental data will be analyzed in the light of extended DLVO models. The complex systems are expected to give rise to nonelectrostatic forces originating from acid/base and hydrogen bonding. This work will have implications on manifold environmental processes, including the control of fouling in engineered systems.'

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