MONOPHOSPHINESC3SYMM

Synthesis of chiral C3-symmetric tricyclic monophosphines and their application as chiral ligands in organometallic catalysis

Coordinatore	FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA    more  Organization address address: AVINGUDA PAISOS CATALANS 16 city: TARRAGONA postcode: 43007 contact info Titolo: Dr. Nome: Ana Margarita Cognome: Segura Hoogendam Email: send email Telefono: 34977920200 Fax: 34977920224
Nazionalità Coordinatore	Spain [ES]
Totale costo	151˙369 €
EC contributo	151˙369 €
Programma	FP7-PEOPLE Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)
Code Call	FP7-PEOPLE-2007-2-1-IEF
Funding Scheme	MC-IEF
Anno di inizio	2008
Periodo (anno-mese-giorno)	2008-10-01   -   2010-09-30

 Partecipanti

#	participant	country	role	EC contrib. [€]
1	FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA  Organization address address: AVINGUDA PAISOS CATALANS 16 city: TARRAGONA postcode: 43007 contact info Titolo: Dr. Nome: Ana Margarita Cognome: Segura Hoogendam Email: send email Telefono: 34977920200 Fax: 34977920224	ES (TARRAGONA)	coordinator	0.00

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 Obiettivo del progetto (Objective)

'The primary scientific objectives of this project are twofold, 1) to develop a methodology to access novel enantiomerically pure chiral C3 symmetric tricyclic monophosphines and, 2) to verify their utility as chiral ligands in transition metal catalysed asymmetric reactions. This project will involve both organic and organometallic chemistry. Organic chemistry will be used for the preparation of these novel C3 symmetric tricyclic monophosphines using known methodologies such as the ring-closing-metathesis reaction, 1,4 addition reactions and the Heck reaction. Organometallic chemistry will be used for the synthesis, isolation, purification and characterisation of novel chiral transition metal catalysts based on these phosphines. The chemical and physico-chemical characteristics of these catalysts will be studied and these catalysts will be tested in asymmetric transformations. In particular, attention will be turned toward palladium-catalysed asymmetric allylic alkylation reactions, palladium-catalysed asymmetric hydrosilylation of alkenes with trichlorosilane and ruthenium-catalysed asymmetric ring-closing-metathesis reactions.'