HICAT

Hierarchically Organized Metal Organic Catalysts for Continuous and Multi-batch Processes

Coordinatore	EVONIK INDUSTRIES AG    more  Organization address address: RELLINGHAUSER STRASSE 1-11 city: ESSEN postcode: 45128 contact info Titolo: Dr. Nome: Juergen Cognome: Czwalinna Email: send email Telefono: +49 2365 49 86652 Fax: +49 2365 49 86650
Nazionalità Coordinatore	Germany [DE]
Totale costo	3˙865˙214 €
EC contributo	2˙647˙217 €
Programma	FP7-NMP Specific Programme "Cooperation": Nanosciences, Nanotechnologies, Materials and new Production Technologies
Code Call	FP7-NMP-2007-SMALL-1
Funding Scheme	CP-FP
Anno di inizio	2008
Periodo (anno-mese-giorno)	2008-09-01   -   2011-08-31

 Partecipanti

#	participant	country	role	EC contrib. [€]
1	EVONIK INDUSTRIES AG  Organization address address: RELLINGHAUSER STRASSE 1-11 city: ESSEN postcode: 45128 contact info Titolo: Dr. Nome: Juergen Cognome: Czwalinna Email: send email Telefono: +49 2365 49 86652 Fax: +49 2365 49 86650	DE (ESSEN)	coordinator	0.00
2	EVONIK DEGUSSA GmbH  Organization address address: Rellinghauser Str. 1-11 city: Essen postcode: 45128 contact info Titolo: Dr. Nome: Juergen Cognome: Czwalinna Email: send email Telefono: +49 2365 49 86652 Fax: +49 2365 49 86650	DE (Essen)	participant	0.00
3	EVONIK MEMBRANE EXTRACTION TECHNOLOGY LIMITED  Organization address address: "Unit 25, Talina Centre, Bagley's Lane" city: LONDON postcode: SW6 2BW contact info Titolo: Dr. Nome: Andrew Timothy Cognome: Boam Email: send email Telefono: -77513129 Fax: -77513130	UK (LONDON)	participant	0.00
4	FOUNDATION FOR RESEARCH AND TECHNOLOGY HELLAS  Organization address address: N PLASTIRA STR 100 city: HERAKLION postcode: 70013 contact info Titolo: Ms. Nome: Zinovia Cognome: Papatheodorou Email: send email Telefono: ++30 2810 391522 Fax: ++30 2810 391555	EL (HERAKLION)	participant	0.00
5	HYBRID CATALYSIS BV  Organization address address: DEN DOLECH 2 city: EINDHOVEN postcode: 5612 AZ contact info Titolo: Dr. Nome: Hendrikus C.L. Cognome: Abbenhuis Email: send email Telefono: +31 40 2474927 Fax: +31 40 2455054	NL (EINDHOVEN)	participant	0.00
6	IMPERIAL COLLEGE OF SCIENCE, TECHNOLOGY AND MEDICINE  Organization address address: SOUTH KENSINGTON CAMPUS EXHIBITION ROAD city: LONDON postcode: SW7 2AZ contact info Titolo: Mr. Nome: Shaun Cognome: Power Email: send email Telefono: -75948749 Fax: -75948585	UK (LONDON)	participant	0.00
7	INSTITUTE OF ORGANIC CHEMISTRY - POLISH ACADEMY OF SCIENCES  Organization address address: ul. Kasprzaka 44/52 city: WARSZAWA postcode: 01-224 contact info Titolo: Dr. Nome: Karol Cognome: Grela Email: send email Telefono: -2434 Fax: -7287	PL (WARSZAWA)	participant	0.00
8	TECHNISCHE UNIVERSITEIT EINDHOVEN  Organization address address: DEN DOLECH 2 city: EINDHOVEN postcode: 5612 AZ contact info Titolo: Dr. Nome: Paul (P.M.L.O.) Cognome: Scholte Email: send email Telefono: -2473009 Fax: -2444330	NL (EINDHOVEN)	participant	0.00
9	UNIVERSIDAD NACIONAL DE EDUCACION A DISTANCIA  Organization address address: CALLE BRAVO MURILLO 38 PLANTA 7 city: MADRID postcode: 28015 contact info Titolo: Ms. Nome: Paloma Cognome: Centeno Email: send email Telefono: -913987375 Fax: -913988401	ES (MADRID)	participant	0.00

Mappa

 Word cloud

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 Obiettivo del progetto (Objective)

'Hierarchically organised metal organic catalysts shall be developed which can be easily recycled in multi-batch processes or which can be used in continuous processes without loosing the original advantages of the corresponding homogeneous soluble metal organic catalysts - high selectivity, activity and stability. The catalysts will be constructed using components at the nano-scale in a bottom-up approach. Hereby, catalytically active metal complexes will be linked with nanoparticles such as polymeric microgels, hyperbranched polymers or hybrid systems consisting of silsesquioxanes attached to hyperbranched polymers. Further hierarchical organisation of HiCat catalysts will be accomplished by interconnected networks formed from the assemblies of catalytic nanoparticles using end-functional T-responsive polymers that can interact with functionalities on the surface of the nanoparticles as binding agents. Recycling of the catalyst-nanoparticle entities in multi-batch operation will be studied utilizing the change of solubility of the polymer supported catalysts by external stimuli. Based on polymer-nanoparticles linked by T-responsive polymers, new types of films and membranes with graded porosity can be prepared by varying the size of the nanoparticles and the length of T-sensitive polymers. This opens new opportunities for integration of catalytic steps and separation within the hierarchically structured system and, hence for continuous reactor operation. The proposal combines the superiority of homogeneous metal-organic catalysts often possessing nearly 100 % selectivity with the advantage of efficient separation by grabbing a new concept for building up hierarchically organised catalytic systems. Structural principles of tailor-made ligands will be transferred into tailor-made functional surfaces of nanoparticles. For proof of principle of the concept, three types of reactions will be studied: olefin metathesis, CX coupling and enantioselective hydrogenation.'

Introduzione (Teaser)

Catalysis is one of the most common and important industrial processes. EU-funded scientists have incorporated novel catalysts in functionalised membranes for combined and highly effective catalysis and separation.