MECOFUPO

Metal-containing Functional Polymers through Subcomponent Self-Assembly

Coordinatore	THE CHANCELLOR, MASTERS AND SCHOLARS OF THE UNIVERSITY OF CAMBRIDGE    more  Organization address address: The Old Schools, Trinity Lane city: CAMBRIDGE postcode: CB2 1TN contact info Titolo: Ms. Nome: Edna Cognome: Murphy Email: send email Telefono: +44 1223 333543 Fax: +44 1223 332988
Nazionalità Coordinatore	United Kingdom [UK]
Totale costo	0 €
EC contributo	171˙300 €
Programma	FP7-PEOPLE Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)
Code Call	FP7-PEOPLE-IEF-2008
Funding Scheme	MC-IEF
Anno di inizio	2009
Periodo (anno-mese-giorno)	2009-05-01   -   2011-04-30

 Partecipanti

#	participant	country	role	EC contrib. [€]
1	THE CHANCELLOR, MASTERS AND SCHOLARS OF THE UNIVERSITY OF CAMBRIDGE  Organization address address: The Old Schools, Trinity Lane city: CAMBRIDGE postcode: CB2 1TN contact info Titolo: Ms. Nome: Edna Cognome: Murphy Email: send email Telefono: +44 1223 333543 Fax: +44 1223 332988	UK (CAMBRIDGE)	coordinator	171˙300.62

Mappa

 Word cloud

Esplora la "nuvola delle parole (Word Cloud) per avere un'idea di massima del progetto.

 Obiettivo del progetto (Objective)

'This research proposal comprises two projects grouped around the idea of generating new polymeric materials using the technique of subcomponent self-assembly, which allows the preparation of complex structures from simple building blocks that come together around metal-ion templates via coordinative and covalent bond formation. The success of Part A will result in the preparation of double-helical polymers consisting of two self-assembled organic polymer strands that wind around a linear array of copper(I) ions. Initial studies have validated the concepts behind our synthetic strategy, and electrochemical measurements together with DFT calculations indicate a high level of electronic delocalization between the copper ions indicating that these polymers could serve as electrically conductive “molecular wires”. Part B will generate a different series of modular metal-organic polymers, consisting of a poly(imine)chain built up using a high-yielding imine exchange reaction. This chain will be bound to and stabilised by copper(I) ions that are also linked to ancillary ligands that fit snugly around the polymer chain using the idea of “steric complimentarity”. Once we have worked out the scope of the chemical reactions underpinning the formation of these polymers, a wide variety of different polymeric materials are predicted to be accessible. Key properties of these materials, such as strength, flexibility, and conductivity, will be tuneable through the incorporation of different monomer units. The self-assembly reactions used to generate these polymers will be carried out in aqueous solution. Water will be the only by-product of many of the condensation reactions that generate polymers. Our objectives in undertaking this project are twofold: to generate new polymeric materials that might possess useful properties (such as electrical conductivity and the ability to self-repair through dynamic reassembly), and to advance the knowledge of molecular self-assembly.'