JBGIM

Functional Nanoscale Coordination Polymers: Controlled Growth by Metal-Containing Block Copolymer Templated Self-Assembly

Coordinatore	UNIVERSITY OF BRISTOL    more  Organization address address: TYNDALL AVENUE SENATE HOUSE city: BRISTOL postcode: BS8 1TH contact info Titolo: Ms. Nome: Johanna Cognome: Rule Email: send email Telefono: -9288769 Fax: -9250973
Nazionalità Coordinatore	United Kingdom [UK]
Totale costo	173˙240 €
EC contributo	173˙240 €
Programma	FP7-PEOPLE Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)
Code Call	FP7-PEOPLE-2009-IIF
Funding Scheme	MC-IIF
Anno di inizio	2010
Periodo (anno-mese-giorno)	2010-07-12   -   2012-07-11

 Partecipanti

#	participant	country	role	EC contrib. [€]
1	UNIVERSITY OF BRISTOL  Organization address address: TYNDALL AVENUE SENATE HOUSE city: BRISTOL postcode: BS8 1TH contact info Titolo: Ms. Nome: Johanna Cognome: Rule Email: send email Telefono: -9288769 Fax: -9250973	UK (BRISTOL)	coordinator	173˙240.80

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 Obiettivo del progetto (Objective)

'Coordination polymers are infinite arrays of bridging ligands bound to two or more transition metal ions. The potential application of coordination polymers in the areas of materials and nanoscience is significant as their properties can be tuned through variation of the transition metal ions and bridging ligands. To date, research in the area of functional nanoscale coordination polymers has been limited to amorphous (spherical) and crystalline (non-spherical) examples and the controlled growth of coordination polymers has not been realized. We propose the use of metal-containing diblock copolymer templates, which self-assemble in a number of different morphologies depending on the volume fraction of the blocks, to influence the structure of coordination polymers on the nanoscale, and for the first time demonstrate control over their size and shape. Our approaches will afford multifunctional materials with highly tunable properties, and the incorporation of diblock copolymers will allow for the rational design and controlled growth of nanoscale coordination polymers. This highly interdisciplinary and multidisciplinary research proposal requires a wide range of skills and this is exactly the mix possessed by the applicant (ligand design, coordination chemistry, stable-radical chemistry, electrochemistry, and molecule-based magnetism) and the host laboratory (polymer chemistry, materials chemistry, and nanoscience). The proposed research will bring a promising young researcher to Europe, and will lead to a new area of functional polymer and materials research where a range of potential applications are envisioned.'