Opendata, web and dolomites

SolHyPro

Water splitting by solar energy: From lab-scale to prototype devices

Total Cost €

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EC-Contrib. €

0

Partnership

0

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 SolHyPro project word cloud

Explore the words cloud of the SolHyPro project. It provides you a very rough idea of what is the project "SolHyPro" about.

fabrication    electron    threshold    photovoltaic    technique    lab    hole    oxygen    ready    material    photoanods    harvesting    oxidation    efficient    stable    environmentally    energy    functional    device    alkaline    hydrogen    tailoring    accounted    surface    successfully    splitting    scaling    coupling    personally    me    leadership    recombination    produces    laboratory    supressing    prototype    gained    grain    consists    cooperation    below    limited    spectrum    drawbacks    solar    film    photovoltage    photoanode    optimize    renewable    germany    carrier    tandem    owing    cell    optimal    length    entirely    ceramic    issue    roughness    thin    bandgap    10x10cm2    adhesion    chemically    microstructural    water    ev    solutions    poses    society    favorable    expertise    deposition    hematite    sequence    pvcomb    metal    microstructure    catalytic    defects    leap    good    impacts    performance    efficiency    boundaries    photoelectrolytic    layers    resolved    photoelectrolysis   

Project "SolHyPro" data sheet

The following table provides information about the project.

Coordinator
TECHNION - ISRAEL INSTITUTE OF TECHNOLOGY 

Organization address
address: SENATE BUILDING TECHNION CITY
city: HAIFA
postcode: 32000
website: www.technion.ac.il

contact info
title: n.a.
name: n.a.
surname: n.a.
function: n.a.
email: n.a.
telephone: n.a.
fax: n.a.

 Coordinator Country Israel [IL]
 Project website https://emd.net.technion.ac.il/
 Total cost 170˙509 €
 EC max contribution 170˙509 € (100%)
 Programme 1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
 Code Call H2020-MSCA-IF-2014
 Funding Scheme MSCA-IF-EF-ST
 Starting year 2015
 Duration (year-month-day) from 2015-06-01   to  2017-05-31

 Partnership

Take a look of project's partnership.

# participants  country  role  EC contrib. [€] 
1    TECHNION - ISRAEL INSTITUTE OF TECHNOLOGY IL (HAIFA) coordinator 170˙509.00

Map

 Project objective

Hematite is a promising photoanode material for harvesting solar energy by splitting water into hydrogen and oxygen. It has a favorable bandgap energy (2.1 eV), good catalytic activity for water oxidation, low cost, is chemically stable in alkaline solutions and environmentally friendly. However, its water splitting efficiency is limited by electron-hole recombination length and it produces a below threshold photovoltage. The key to increasing the recombination length is supressing defects such as grain boundaries or surface roughness of the photoanode. The second issue is successfully resolved by coupling the photoelectrolytic cell to a photovoltaic cell, a so-called tandem cell with theoretically higher efficiency owing to optimal use of the solar spectrum. Both of these drawbacks are accounted for in this project. The aim of this project is to optimize the water photoelectrolysis performance of the photoelectrolysis-photovoltaic tandem-cell device by tailoring the microstructure of the thin film hematite photoanods, and up scaling from the laboratory scale to a prototype device. Fabrication of an efficient water-splitting cell is challenging as it consists of several thin film layers. Each of these layers impacts on the performance of the water-splitting tandem-cell. Up scaling from the lab scale to the prototype scale (10x10cm2) will be carried out in cooperation with PVComB in Germany. This poses entirely different challenges, creating the need for an adapted fabrication sequence and deposition conditions that ensure the adhesion of the ceramic and metal thin film layers. At the end of this project, I personally will have gained expertise in advanced microstructural analysis technique and also in the leadership role, which will enable me to take the next step in my carrier. And, we will have built a fully functional, fabrication-ready device for hydrogen production directly from solar energy. A great leap forward into a society based on renewable resources.

 Publications

year authors and title journal last update
List of publications.
2016 Daniel A. Grave, Hen Dotan, Yossi Levy, Yifat Piekner, Barbara Scherrer, Kirtiman Deo Malviya, Avner Rothschild
Heteroepitaxial hematite photoanodes as a model system for solar water splitting
published pages: 3052-3060, ISSN: 2050-7488, DOI: 10.1039/C5TA07094E
J. Mater. Chem. A 4/8 2019-07-23

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