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BRISOACTIONS

To understand the redox variations and interactions between hydro-, bio- and atmosphere: the power of bromine stable isotopes.

Total Cost €

EC-Contrib. €

Partnership

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Outcomes and
results

BRISOACTIONS project word cloud

Explore the words cloud of the BRISOACTIONS project. It provides you a very rough idea of what is the project "BRISOACTIONS" about.

chlorine 06 flow bromine understand chemical continue fractionation reflect first deposited fluid 21 ion geochemistry compositions migration reservoirs never h2 unexpected surface cycles porous 40 media geological br isotope permil isotopes ions fluids observations redox data 48 smaller subsurface filtration considerably transport halogen storage oxidation compare historical stable interesting moment magnitude considering ancient small composition cl variations hardly proxies history geochemical earth oceans co2 evaporites positive deep ratios impossible 6 hydrocarbons modern

Project "BRISOACTIONS" data sheet

The following table provides information about the project.

Coordinator	INSTITUT DE PHYSIQUE DU GLOBE DE PARIS Organization address address: RUE JUSSIEU 1 city: PARIS postcode: 75238 website: http://www.ipgp.fr contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.
Coordinator Country	France [FR]
Project website	http://www.eggenkamp.info/BRISOACTIONS/
Total cost	185˙076 €
EC max contribution	185˙076 € (100%)
Programme	1. H2020-EU.1.3.2. (Nurturing excellence by means of cross-border and cross-sector mobility)
Code Call	H2020-MSCA-IF-2015
Funding Scheme	MSCA-IF-EF-CAR
Starting year	2016
Duration (year-month-day)	from 2016-09-01 to 2018-08-31

Partnership

Take a look of project's partnership.

#	participants	country	role	EC contrib. [€]
1	INSTITUT DE PHYSIQUE DU GLOBE DE PARIS INSTITUT DE PHYSIQUE DU GLOBE DE PARIS Organization address address: RUE JUSSIEU 1 city: PARIS postcode: 75238 website: http://www.ipgp.fr contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	FR (PARIS)	coordinator	185˙076.00

Map

Project objective

The stable isotope geochemistry of chlorine (Cl) and bromine (Br) are considerably different. While most Cl isotope data are in the range from -1.21 to .40‰, Br isotope data are from -0.06 to 1.48‰. Interesting is that Br isotope variations are of the same magnitude as Cl isotope variations. Also Br isotope values of ancient evaporites are very positive (.6‰), impossible to explain from oceans with a modern isotope composition. These data are unexpected considering the small fractionation factors for Br compared to Cl. The research we propose aims at understanding these observations and developing halogen stable isotopes to study fluid transport processes in porous media. This research has a great potential to understand the history and the migration of fluids in deep porous reservoirs which are considered for geological storage of CO2, H2 and hydrocarbons. First we aim to study historical variations of Br isotope compositions in the earth's surface reservoirs. We will study Br isotope variations in ancient evaporites that reflect Br isotope ratios of the oceans at the moment they were deposited. Second to study the geochemical processes that affect Cl and Br isotope variations. Isotope fractionation during ion-filtration that has never been studied in detail. This process is important to understand subsurface fluid flow and fractionation of ions and isotopes during fluid transport. We aim at studying Cl and Br isotope variations during this process. Also redox processes have hardly been studied. Oxidation processes can increase Br isotopes values more than Cl in spite of Br's much smaller isotope fractionation factors. Third to understand our observations we will compare the data obtained during this study with the geochemical cycles of Cl and Br. This will allow us to develop future research to continue to improve our knowledge on Cl and Br isotope variations as proxies to understand chemical cycles on earth, especially in fluids in deep porous reservoirs.

Publications

List of publications.
year	authors and title	journal	last update
2018	H.G.M. Eggenkamp, P. Louvat A simple distillation method to extract bromine from natural water and salt samples for isotope analysis by multi-collector inductively coupled plasma mass spectrometry published pages: 612-618, ISSN: 0951-4198, DOI: 10.1002/rcm.8080	Rapid Communications in Mass Spectrometry 32/8	2019-07-26
2018	Alejandro RodrÃguez, Manfred J. van Bergen, H.G.M. Eggenkamp Experimental evaporation of hyperacid brines: Effects on chemical composition and chlorine isotope fractionation published pages: 467-484, ISSN: 0016-7037, DOI: 10.1016/j.gca.2017.10.032	Geochimica et Cosmochimica Acta 222	2019-07-26
2017	Thomas Giunta, Jabrane Labidi, Hans G.M. Eggenkamp Chlorine isotope fractionation between chloride (Cl âˆ’ ) and dichlorine (Cl 2 ) published pages: 375-382, ISSN: 0016-7037, DOI: 10.1016/j.gca.2017.07.003	Geochimica et Cosmochimica Acta 213	2019-07-26
2019	H.G.M. Eggenkamp, P. Louvat, J. Griffioen, P. Agrinier Chlorine and bromine isotope evolution within a fully developed Upper Permian natural salt sequence published pages: 316-326, ISSN: 0016-7037, DOI: 10.1016/j.gca.2018.11.010	Geochimica et Cosmochimica Acta 245	2019-07-26

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