ASADO-CH

Development and application of Artificial Systems for Activation of DiOxygen and C-H bonds

Coordinatore	STOCKHOLMS UNIVERSITET    more  Organization address address: Universitetsvaegen 10 city: STOCKHOLM postcode: 10691 contact info Titolo: Dr. Nome: Göran Cognome: Widmalm Email: send email Telefono: +46 8163742 Fax: +46 8154908
Nazionalità Coordinatore	Sweden [SE]
Totale costo	100˙000 €
EC contributo	100˙000 €
Programma	FP7-PEOPLE Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)
Code Call	FP7-PEOPLE-2013-CIG
Funding Scheme	MC-CIG
Anno di inizio	2014
Periodo (anno-mese-giorno)	2014-03-01   -   2018-02-28

 Partecipanti

#	participant	country	role	EC contrib. [€]
1	STOCKHOLMS UNIVERSITET  Organization address address: Universitetsvaegen 10 city: STOCKHOLM postcode: 10691 contact info Titolo: Dr. Nome: Göran Cognome: Widmalm Email: send email Telefono: +46 8163742 Fax: +46 8154908	SE (STOCKHOLM)	coordinator	100˙000.00

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 Obiettivo del progetto (Objective)

'The excision of C-H bonds from an aliphatic carbon chain to produce functionalized compounds is a general pathway in biosynthetic transformations for which there are no simple and mild laboratory substitutes. Moreover, their source materials (like dioxygen) are abundant and have proved to be sustainable for millions of years. This proposal targets the invention of new bioinspired processes for C-H oxidation, arylation and dehydrogenation. To achieve this goal, invention of both new suprabiotic iron catalysts and new directed radical C-H functionalization methods will be mandatory. As a result, the conversion of a relatively inert aliphatic system to its functionalized counterpart will revolutionize the field of Organic Synthesis. Direct application in the modification of cheap materials into medicinally relevant compounds (some of them currently on the market) is planned.'