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METCOPH

Metallocomplexes of macrocyclic compounds for photonic devices

Total Cost €

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EC-Contrib. €

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Partnership

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Outcomes and
results

METCOPH project word cloud

Explore the words cloud of the METCOPH project. It provides you a very rough idea of what is the project "METCOPH" about.

emitting transient simultaneous metals mutual temperatures ambient detection selective science resolution organic amplification transistors rely physics oleds cooperation chemical temperature diverse newly lasers intensify mmc synthesized interdisciplinary nanotechnology combines extended investigation light mmcs driving excitation luminescence fundamental compounds cells consolidate fabrication characterisation expertise site metcoph spectroscopy efforts objects spectroscopic singlet triplet scattering sensing lecs macrocyclic mechanisms solid core gained groups countries photochemistry microscopy photophysical quantum absorption mentioned metallocomplexes respective transistor basic involve ideas engineering electrochemical revealed raman physical multidisciplinary steady pulsed single sensors photonic complementary ranging optical manipulation chemistry switching force competence atomic functional ligands cw technologies incorporating gathering

Project "METCOPH" data sheet

The following table provides information about the project.

Coordinator	INSTYTUT CHEMII FIZYCZNEJ POLSKIEJ AKADEMII NAUK Organization address address: KASPRZAKA 44/52 city: WARSZAWA postcode: 1224 website: http://www.ichf.edu.pl contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.
Coordinator Country	Poland [PL]
Project website	http://risemetcoph.eu/
Total cost	688˙500 €
EC max contribution	688˙500 € (100%)
Programme	1. H2020-EU.1.3.3. (Stimulating innovation by means of cross-fertilisation of knowledge)
Code Call	H2020-MSCA-RISE-2014
Funding Scheme	MSCA-RISE
Starting year	2015
Duration (year-month-day)	from 2015-01-01 to 2018-12-31

Partnership

Take a look of project's partnership.

#	participants	country	role	EC contrib. [€]
1	INSTYTUT CHEMII FIZYCZNEJ POLSKIEJ AKADEMII NAUK INSTYTUT CHEMII FIZYCZNEJ POLSKIEJ AKADEMII NAUK Organization address address: KASPRZAKA 44/52 city: WARSZAWA postcode: 1224 website: http://www.ichf.edu.pl contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	PL (WARSZAWA)	coordinator	360˙000.00
2	UNIVERSITAET REGENSBURG UNIVERSITAET REGENSBURG Organization address address: UNIVERSITATSSTRASSE 31 city: REGENSBURG postcode: 93053 website: http://www.uni-regensburg.de/ contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	DE (REGENSBURG)	participant	247˙500.00
3	TEL AVIV UNIVERSITY TEL AVIV UNIVERSITY Organization address address: RAMAT AVIV city: TEL AVIV postcode: 69978 website: http://www.tau.ac.il/ contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	IL (TEL AVIV)	participant	81˙000.00
4	B.I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus B.I. Stepanov Institute of Physics of the National Academy of Sciences of Belarus Organization address address: Nezavisimosti Ave 68 city: Minsk postcode: 220072 website: n.a. contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	BY (Minsk)	partner	0.00
5	V.I.Vernadskii Institute of General and Inorganic Chemistry NAS of Ukraine V.I.Vernadskii Institute of General and Inorganic Chemistry NAS of Ukraine Organization address address: ACADEMICIAN PALLADIN AVENUE 32/34 city: KYIV postcode: 3142 website: n.a. contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	UA (KYIV)	partner	0.00

Map

Project objective

The key objective of the METCOPH multidisciplinary project is to intensify and consolidate cooperation between several research groups from member states and third countries on topics within the field of fundamental interdisciplinary science. The project combines the basic ideas of organic chemistry, solid state physics, photochemistry and spectroscopy of metallocomplexes of macrocyclic compounds (MMC) for applications in quantum information processing, sensing, switching and amplification. The project aims at focusing mutual efforts of five research groups with extended and complementary competence in their respective research fields and at gathering multidisciplinary and complementary expertise in chemical engineering and investigation of spectroscopy and photochemistry of MMCs for future design of photonic devices (e.g. organic light emitting devices – OLEDs, light emitting electrochemical cells – LECs, sensors, light emitting transistors) based on above mentioned compounds. The physical and chemical mechanisms of manipulation of optical response for these novel compounds will be revealed and analyzed with involving diverse spectroscopic approaches including steady-state and transient absorption, site-selective high-resolution luminescence, Raman scattering, atomic force microscopy and single-objects detection methods at different temperatures ranging from 1.2 K to ambient temperature. The expected results involve fabrication and chemical/photophysical characterisation of MMCs based on various core metals and incorporating various functional organic ligands. One of the key technologies will rely on driving optical transistor with CW and pulsed lasers and will make use of simultaneous excitation of singlet and triplet states of the metallocomplexes of macrocyclic compounds. The new information gained for these newly synthesized MMC systems will have impact on the engineering of novel functional MMCs for application in nanotechnology and photonic devices.

Deliverables

List of deliverables.
Progress Report II.	Documents, reports	2019-09-02 13:50:58
Quantum-chemical calculations of the MMCs	Documents, reports	2019-09-02 13:50:58
Scaling of properties of the single emitting MMCs	Other	2019-09-02 13:50:58
Fluorescence and phosphorescence data	Documents, reports	2019-09-02 13:50:57
Luminescent pincer complexes	Documents, reports	2019-09-02 13:50:57
Vibrational assignment of investigated compounds	Documents, reports	2019-09-02 13:50:57
Data of the conformational stability of the MMC	Documents, reports	2019-09-02 13:50:57
A set of energy level diagrams describing the excitation energy deactivation channels in the case of MMCs	Documents, reports	2019-09-02 13:50:57
MMCs with out-of-plane ligands	Documents, reports	2019-09-02 13:50:57
Photostable luminescent MMCs	Documents, reports	2019-09-02 13:50:57
Free-base organic core and cyclometalating ligands	Documents, reports	2019-09-02 13:50:57
Progress Report I.	Documents, reports	2019-09-02 13:50:57

Take a look to the deliverables list in detail: detailed list of METCOPH deliverables.

Publications

List of publications.
year	authors and title	journal	last update
2018	Aleksandr Starukhin, Aleksander Gorski, Michal Kijak Influence of solid matrices on spectral features of metalloporphyrins published pages: 3013, ISSN: 2100-014X, DOI: 10.1051/epjconf/201819003013	EPJ Web of Conferences 190	2019-09-02
2018	Aleksandr Starukhin, Aleksander Gorski, Tatsiana Pavich, Valerii Kniukshto Spectral features of conjugated bichromophores: porphyrins with curcumin published pages: 4023, ISSN: 2100-014X, DOI: 10.1051/epjconf/201819004023	EPJ Web of Conferences 190	2019-09-02
2018	A. O. Savostianov, I. Yu. Eremchev, A. A. Gorshelev, A. V. Naumov, A. S. Starukhin Wide-Range Spectral Diffusion in Single Mg-Tetraazaporphyrin Molecules in a Polymer Matrix at Cryogenic Temperatures published pages: 406-411, ISSN: 0021-3640, DOI: 10.1134/s002136401807007x	JETP Letters 107/7	2019-09-02
2018	A. S. Starukhin, A. V. Gorski, M. Z. Kijak Spectral Distortions of Metalloporphyrin Forms at Low Temperatures published pages: 1560-1564, ISSN: 1062-8738, DOI: 10.3103/s1062873818120225	Bulletin of the Russian Academy of Sciences: Physics 82/12	2019-09-02
2018	Aleksandr Savostianov, Ivan Eremchev, Alexei Gorshelev, Sergei Orlov, Oleg Korotayev, Andrei Naumov, Aleksandr Starukhin Structural and time-domain peculiarities of the fluorescence excitation spectra of single Mg-TAP in a polymer at low temperatures published pages: 4019, ISSN: 2100-014X, DOI: 10.1051/epjconf/201819004019	EPJ Web of Conferences 190	2019-09-02
2018	Alexandr Gorski, Valery Knyukshto, Eduard Zenkevich, Alexander Starukhin, MichaÅ‚ Kijak, JÄ™drzej Solarski, Alexander Semeikin, Tatjana Lyubimova Temperature dependent steric hindrance effects in triplet state relaxation of meso-phenyl-substituted Pd-octaethylporphyrins published pages: 101-111, ISSN: 1010-6030, DOI: 10.1016/j.jphotochem.2017.09.002	Journal of Photochemistry and Photobiology A: Chemistry 354	2019-09-02
2018	Alexandr Gorski, Valery Knyukshto, Eduard Zenkevich, Alexander Starukhin, MichaÅ‚ Kijak, JÄ™drzej Solarski, Alexander Semeikin, Tatjana Lyubimova Temperature dependent steric hindrance effects in triplet state relaxation of meso -phenyl-substituted Pd-octaethylporphyrins published pages: 101-111, ISSN: 1010-6030, DOI: 10.1016/j.jphotochem.2017.09.002	Journal of Photochemistry and Photobiology A: Chemistry 354	2019-09-02
2017	A. Starukhin, V. Knyukshto, A. Gorski, V. Chernii, I. Tretyakova, M. Kijak, P. Kowalska Spectral manifestation of substitution of out-of-plane ligands in metallophtalocyanines published pages: 3044, ISSN: 2100-014X, DOI: 10.1051/epjconf/201713203044	EPJ Web of Conferences 132	2019-09-02
2017	Marsel Z. Shafikov, Alfiya F. Suleymanova, RafaÅ‚ Czerwieniec, and Hartmut Yersin Design Strategy for Ag(I)-Based Thermally Activated Delayed Fluorescence Reaching an Efficiency Breakthrough published pages: , ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.6b05175	Chemistry of Materials	2019-09-02
2017	A. Gorski, A. Starukhin, S. Stavrov, S. Gawinkowski, J. Waluk Resonance Raman spectroscopy study of protonated porphyrin published pages: 350-355, ISSN: 1386-1425, DOI: 10.1016/j.saa.2016.09.038	Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 173	2019-09-02
2016	RafaÅ‚ Czerwieniec, Markus J. Leitl, Herbert H.H. Homeier, Hartmut Yersin Cu(I) complexes â€“ Thermally activated delayed fluorescence. Photophysical approach and material design published pages: 2â€“28, ISSN: 0010-8545, DOI: 10.1016/j.ccr.2016.06.016	Coordination Chemistry Reviews	2019-09-02
2017	A. Starukhin, V. Knyukshto, V. Plavskii, A. Gorski, J. Solarski Wavelength dependence of the efficiency of singlet oxygen generation upon photoexcitation of photosensitizers published pages: 2019, ISSN: 2100-014X, DOI: 10.1051/epjconf/201713202019	EPJ Web of Conferences 132	2019-09-02
2015	Ya.M.Dovbii, V.Ya.Chernii, I.M.Tretyakova, A.V.Gorski, A.S.Starukhin, S.V.Volkov SYNTHESIS OF DEHYDROACETIC ACID DERIVATIVES WITH CHROMOPHORICCHAINS AND THEIR COMPLEXES WITH ZIRCONIUM PHTHALOCYANINE published pages: 79-82, ISSN: 0041-6045, DOI:	Ukrainian Chemistry Journal 12	2019-09-02
2017	V. Kovalska, S. Chernii, M. Losytskyy, J. Ostapko, I. Tretyakova, A. Gorski, V. Chernii, S. Yarmoluk Activity of Zn and Mg phthalocyanines and porphyrazines in amyloid aggregation of insulin published pages: e2660, ISSN: 0952-3499, DOI: 10.1002/jmr.2660	Journal of Molecular Recognition 30 August 2017	2019-09-02
2017	A. Starukhin, A. Gorski, V. Knyukshto, M. Kijak, I. Tretyakova, Y. Dovbii, V. Chernii Photophysical Features of Phthalocyanines Metallocomplexes with Out-of-Plane Ligands published pages: 109-114, ISSN: 2331-6535, DOI: 10.13189/ujpa.2017.110403	Universal Journal of Physics and Application 11/4	2019-09-02
2016	Vladyslava Kovalska, Svitlana Chernii, Mykhaylo Losytskyy, Yan Dovbii, Iryna Tretyakova, Rafal Czerwieniec, Victor Chernii, Sergiy Yarmoluk, Sergiy Volkov Î²-ketoenole dyes: Synthesis and study as fluorescent sensors for protein amyloid aggregates published pages: 274-281, ISSN: 0143-7208, DOI: 10.1016/j.dyepig.2016.04.053	Dyes and Pigments 132	2019-09-02

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