CORYPHEE

Cold Rydbergs: photoionization, electronic spectroscopy and electrostatic trapping

 Coordinatore EIDGENOESSISCHE TECHNISCHE HOCHSCHULE ZURICH 

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 Nazionalità Coordinatore Switzerland [CH]
 Totale costo 1˙192˙395 €
 EC contributo 1˙192˙395 €
 Programma FP7-IDEAS-ERC
Specific programme: "Ideas" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)
 Code Call ERC-2008-AdG
 Funding Scheme ERC-AG
 Anno di inizio 2008
 Periodo (anno-mese-giorno) 2008-11-01   -   2013-10-31

 Partecipanti

# participant  country  role  EC contrib. [€] 
1    EIDGENOESSISCHE TECHNISCHE HOCHSCHULE ZURICH

 Organization address address: Raemistrasse 101
city: ZUERICH
postcode: 8092

contact info
Titolo: Prof.
Nome: Frédéric
Cognome: Merkt
Email: send email
Telefono: -6324370
Fax: -6321024

CH (ZUERICH) hostInstitution 0.00

Mappa


 Word cloud

Esplora la "nuvola delle parole (Word Cloud) per avere un'idea di massima del progetto.

spectroscopic    cold    rotational    nuclear    ab    samples    structure    cations    rydberg    molecular    initio    levels    molecules    atoms    spins    quantum    traps    hyperfine    gt    vibrational    trapped   

 Obiettivo del progetto (Objective)

Spectroscopic investigation of high (n >>20) molecular Rydberg states below and above the first adiabatic ionization threshold will be carried out with the aims of 1) obtaining fully resolved information on the vibrational, rotational, spin-orbit and hyperfine structures of these highly excited electronic states, 2) characterizing the role of nuclear spins in molecular photoionization, 3) determining the hyperfine structure of fundamental molecular cations at kHz resolution and accuracy by Rydberg series extrapolation, 4) measuring intervals between rovibrational levels of these molecular cations at sub MHz precision, 5) gaining a complete understanding, and providing an adequate description and classification, of angular momentum coupling (including nuclear spins) in high molecular Rydberg states, 6) testing theoretical predictions of the energy level structure of Rydberg molecules by ab initio multichannel quantum defect theory (MQDT) and of the rotational, vibrational and hyperfine levels of molecular cations by ab initio quantum chemistry and QED. The spectroscopic measurements using tunable narrow-band vacuum-ultraviolet and millimeter wave radiation sources will be performed on cold samples in supersonic beams as well as on trapped samples of translationally cold Rydberg atoms and molecules. To this end, our recent approach to trap H atoms in Rydberg states electrostatically (Hogan and Merkt, Phys. Rev. Lett. 100, 043001 (2008)) will be extended to molecules, and the possibility of transfering the trapped species from electrostatic traps to magnetic and optical traps will be explored.

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