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SynCatMatch SIGNED

MATching zeolite SYNthesis with CATalytic activity

Total Cost €

EC-Contrib. €

Partnership

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Outcomes and
results

SynCatMatch project word cloud

Explore the words cloud of the SynCatMatch project. It provides you a very rough idea of what is the project "SynCatMatch" about.

molecular reuse relatively synthesised reaction summary host methodology 3000tm guest tailor ranging reactions retains efficient desired cavities reactants gas porous maximizing 1 recognition separation ease made solid catalysis zeolites mimics industrial efficiency clear energy agents synthesis pattern catalytic structure lower advantages pores accepted single boosting creates additional error selectivity manufacturing catalysts catalyst consumption trial chosen synthesise industrially interactions zeolite catalyze components transition organic fewer directing recovery spectrum adsorption obtain ing sustainable

Project "SynCatMatch" data sheet

The following table provides information about the project.

Coordinator	AGENCIA ESTATAL CONSEJO SUPERIOR DEINVESTIGACIONES CIENTIFICAS Organization address address: CALLE SERRANO 117 city: MADRID postcode: 28006 website: http://www.csic.es contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.
Coordinator Country	Spain [ES]
Project website	http://itq.upv-csic.es/
Total cost	2˙470˙519 €
EC max contribution	2˙470˙519 € (100%)
Programme	1. H2020-EU.1.1. (EXCELLENT SCIENCE - European Research Council (ERC))
Code Call	ERC-2014-ADG
Funding Scheme	ERC-ADG
Starting year	2015
Duration (year-month-day)	from 2015-06-01 to 2020-05-31

Partnership

Take a look of project's partnership.

#	participants	country	role	EC contrib. [€]
1	AGENCIA ESTATAL CONSEJO SUPERIOR DEINVESTIGACIONES CIENTIFICAS AGENCIA ESTATAL CONSEJO SUPERIOR DEINVESTIGACIONES CIENTIFICAS Organization address address: CALLE SERRANO 117 city: MADRID postcode: 28006 website: http://www.csic.es contact info title: n.a. name: n.a. surname: n.a. function: n.a. email: n.a. telephone: n.a. fax: n.a.	ES (MADRID)	coordinator	2˙470˙519.00

Map

Project objective

Solid catalysts are key components of many industrial processes, offering advantages such as reuse and ease recovery. This research programme aims to develop a new concept and methodology for the synthesis of zeolite catalysts. Zeolites are solid, porous catalysts that have wide ranging industrial applications for gas adsorption, separation and catalysis. While a relatively large number of zeolites have been synthesised, zeolite selection as catalyst for a particular reaction still retains a large element of trial and error. Our objective is to design a zeolite synthesis methodology that creates pores and cavities in the resulting zeolite that approach a “molecular recognition” pattern to catalyze the desired reaction. The approach focuses on the study of the reactions transition states since it is accepted that the most efficient catalysts are those that lower the transition state energy in the reaction, boosting the catalytic activity and efficiency. We will study the transition state of the desired reaction and design and synthesise transition state mimics to be used as Organic Structure Directing Agents for the synthesis of zeolites. By maximizing the host-guest interactions between zeolite and transition state, the efficiency of the catalyst will be increased. We aim to obtain tailor made catalysts for a chosen spectrum of reactions that also have clear industrial applications. Synthesis of highly efficient catalysts for particular industrially relevant applications will lead to lower energy consumption, fewer by-products and lower consumption of reactants. In summary, this will result in more sustainable processes. In many industrial applications a 1% increase in selectivity can represent more than 3000Tm/year additional manufacturing in a single unit.

Publications

List of publications.
year	authors and title	journal	last update
2018	Chengeng Li, Manuel Moliner, Avelino Corma Building Zeolites from Precrystallized Units: Nanoscale Architecture published pages: 15330-15353, ISSN: 1433-7851, DOI: 10.1002/anie.201711422	Angewandte Chemie International Edition 57/47	2020-03-11
2018	Vicente J. Margarit, M. RocÃo DÃaz-Rey, M. Teresa Navarro, Cristina MartÃnez, Avelino Corma Direct Synthesis of Nano-Ferrierite along the 10-Ring-Channel Direction Boosts Their Catalytic Behavior published pages: 3459-3463, ISSN: 1433-7851, DOI: 10.1002/anie.201711418	Angewandte Chemie International Edition 57/13	2020-03-11
2018	Yosra Ghrib, Najoua Frini-Srasra, Ezzeddine Srasra, JoaquÃn MartÃnez-Triguero, Avelino Corma Synthesis of cocrystallized USY/ZSM-5 zeolites from kaolin and its use as fluid catalytic cracking catalysts published pages: 716-725, ISSN: 2044-4753, DOI: 10.1039/c7cy01477e	Catalysis Science & Technology 8/3	2020-03-11
2018	SebastiÃ¡n Llopis, Teresa GarcÃa, Ãngel CantÃn, Alexandra Velty, Urbano DÃaz, Avelino Corma Chiral hybrid materials based on pyrrolidine building units to perform asymmetric Michael additions with high stereocontrol published pages: 5835-5847, ISSN: 2044-4753, DOI: 10.1039/c8cy01650j	Catalysis Science & Technology 8/22	2020-03-11
2018	Marta Mon, Rosa Adam, JesÃºs Ferrandoâˆ’Soria, Avelino Corma, Donatella Armentano, Emilio Pardo, Antonio Leyvaâˆ’PÃ©rez Stabilized Ru[(H 2 O) 6 ] 3+ in Confined Spaces (MOFs and Zeolites) Catalyzes the Imination of Primary Alcohols under Atmospheric Conditions with Wide Scope published pages: 10401-10406, ISSN: 2155-5435, DOI: 10.1021/acscatal.8b03228	ACS Catalysis 8/11	2020-03-11
2018	EstefanÃa FernÃ¡ndez, Marta Moreno-GonzÃ¡lez, Manuel Moliner, Teresa Blasco, Mercedes Boronat, Avelino Corma Modeling of EPR Parameters for Cu(II): Application to the Selective Reduction of NOx Catalyzed by Cu-Zeolites published pages: 810-832, ISSN: 1022-5528, DOI: 10.1007/s11244-018-0929-y	Topics in Catalysis 61/9-11	2020-03-11
2018	Lichen Liu, Avelino Corma Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles published pages: 4981-5079, ISSN: 0009-2665, DOI: 10.1021/acs.chemrev.7b00776	Chemical Reviews 118/10	2020-03-11
2018	Chengeng Li, Cecilia Paris, JoaquÃn MartÃnez-Triguero, Mercedes Boronat, Manuel Moliner, Avelino Corma Synthesis of reactionâ€adapted zeolites as methanol-to-olefins catalysts with mimics of reaction intermediates as organic structureâ€directing agents published pages: 547-554, ISSN: 2520-1158, DOI: 10.1038/s41929-018-0104-7	Nature Catalysis 1/7	2020-03-11
2018	Urbano DÃaz, Avelino Corma Organic-Inorganic Hybrid Materials: Multi-Functional Solids for Multi-Step Reaction Processes published pages: 3944-3958, ISSN: 0947-6539, DOI: 10.1002/chem.201704185	Chemistry - A European Journal 24/16	2020-03-11
2018	Anderson Schwanke, Jhonny Villarroel-Rocha, Karim Sapag, Urbano DÃaz, Avelino Corma, Sibele Pergher Dandelion-Like Microspherical MCM-22 Zeolite Using BP 2000 as a Hard Template published pages: 6217-6223, ISSN: 2470-1343, DOI: 10.1021/acsomega.8b00647	ACS Omega 3/6	2020-03-11
2018	Lichen Liu, Dmitri N. Zakharov, Raul Arenal, Patricia Concepcion, Eric A. Stach, Avelino Corma Evolution and stabilization of subnanometric metal species in confined space by in situ TEM published pages: , ISSN: 2041-1723, DOI: 10.1038/s41467-018-03012-6	Nature Communications 9/1	2020-03-05
2019	Lichen Liu, Raul Arenal, Debora M. Meira, Avelino Corma Generation of gold nanoclusters encapsulated in an MCM-22 zeolite for the aerobic oxidation of cyclohexane published pages: 1607-1610, ISSN: 1359-7345, DOI: 10.1039/C8CC07185C	Chemical Communications 55/11	2020-03-05
2016	Manuel Moliner, Jadeene E. Gabay, Chris E. Kliewer, Robert T. Carr, Javier Guzman, Gary L. Casty, Pedro Serna, Avelino Corma Reversible Transformation of Pt Nanoparticles into Single Atoms inside High-Silica Chabazite Zeolite published pages: 15743-15750, ISSN: 0002-7863, DOI: 10.1021/jacs.6b10169	Journal of the American Chemical Society 138/48	2019-07-08
2015	Pedro Serna, Avelino Corma Transforming Nano Metal Nonselective Particulates into Chemoselective Catalysts for Hydrogenation of Substituted Nitrobenzenes published pages: 7114-7121, ISSN: 2155-5435, DOI: 10.1021/acscatal.5b01846	ACS Catalysis 5/12	2019-07-08
2017	A. Corma, E. Corresa, Y. Mathieu, L. Sauvanaud, S. Al-Bogami, M. S. Al-Ghrami, A. Bourane Crude oil to chemicals: light olefins from crude oil published pages: 12-46, ISSN: 2044-4753, DOI: 10.1039/C6CY01886F	Catal. Sci. Technol. 7/1	2019-07-08
2017	AidÃ© Gaona, Urbano DÃaz, Avelino Corma Functional Acid and Base Hybrid Catalysts Organized by Associated (Organo)aluminosilicate Layers for Câ€“C Bond Forming Reactions and Tandem Processes published pages: 1599-1612, ISSN: 0897-4756, DOI: 10.1021/acs.chemmater.6b04563	Chemistry of Materials 29/4	2019-07-08
2016	Jorge Simancas, Raquel Simancas, Pablo J. Bereciartua, Jose L. Jorda, Fernando Rey, Avelino Corma, Stavros Nicolopoulos, Partha Pratim Das, Mauro Gemmi, Enrico Mugnaioli Ultrafast Electron Diffraction Tomography for Structure Determination of the New Zeolite ITQ-58 published pages: 10116-10119, ISSN: 0002-7863, DOI: 10.1021/jacs.6b06394	Journal of the American Chemical Society 138/32	2019-07-08
2017	Nuria MartÃn, Cecilia Paris, Peter N.R. VennestrÃ¸m, Joakim R. ThÃ¸gersen, Manuel Moliner, Avelino Corma Cage-based small-pore catalysts for NH 3 -SCR prepared by combining bulky organic structure directing agents with modified zeolites as reagents published pages: 125-136, ISSN: 0926-3373, DOI: 10.1016/j.apcatb.2017.05.082	Applied Catalysis B: Environmental 217	2019-07-08
2016	Marta E. MartÃnez-Armero, Manuel Moliner, German Sastre, Fernando Rey, Cristina MartÃnez, Avelino Corma ITQ-39 zeolite, an efficient catalyst for the conversion of low value naphtha fractions into diesel fuel: The role of pore size on molecular diffusion and reactivity published pages: 127-138, ISSN: 0021-9517, DOI: 10.1016/j.jcat.2015.10.024	Journal of Catalysis 333	2019-07-08
2017	Lichen Liu, Urbano DÃaz, Raul Arenal, Giovanni Agostini, Patricia ConcepciÃ³n, Avelino Corma Generation of subnanometric platinum with high stability during transformation of a 2D zeolite intoÂ 3D published pages: 132-138, ISSN: 1476-1122, DOI: 10.1038/NMAT4757	Nature Materials 16/1	2019-07-08
2017	Nuria MartÃn, Peter N. R. VennestrÃ¸m, Joakim R. ThÃ¸gersen, Manuel Moliner, Avelino Corma Fe-Containing Zeolites for NH 3 -SCR of NO x : Effect of Structure, Synthesis Procedure, and Chemical Composition on Catalytic Performance and Stability published pages: 13404-13414, ISSN: 0947-6539, DOI: 10.1002/chem.201701742	Chemistry - A European Journal 23/54	2019-07-08
2016	Mogahid Osman, Sulaiman Al-Khattaf, Urbano DÃaz, Cristina MartÃnez, Avelino Corma Influencing the activity and selectivity of alkylaromatic catalytic transformations by varying the degree of delamination in MWW zeolites published pages: 3166-3181, ISSN: 2044-4753, DOI: 10.1039/C5CY01675D	Catal. Sci. Technol. 6/9	2019-07-08
2016	Anderson Joel Schwanke, Sibele Pergher, Urbano DÃaz, Avelino Corma The influence of swelling agents molecular dimensions on lamellar morphology of MWW-type zeolites active for fructose conversion published pages: , ISSN: 1387-1811, DOI: 10.1016/j.micromeso.2016.11.007	Microporous and Mesoporous Materials	2019-07-08
2016	Mercedes Boronat, Tirso LÃ³pez-Ausens, Avelino Corma The acidâ€“base and redox reactivity of CeO2 nanoparticles: Influence of the Hubbard U term in DFT+U studies published pages: 212-219, ISSN: 0039-6028, DOI: 10.1016/j.susc.2015.10.047	Surface Science 648	2019-07-08
2016	Avelino Corma Spiers Memorial Lecture : Heterogeneous catalysis: understanding the fundamentals for catalyst design published pages: 9-20, ISSN: 1359-6640, DOI: 10.1039/C6FD00066E	Faraday Discuss. 188	2019-07-08
2016	Raquel MartÃnez-Franco, Zhibin Li, JoaquÃn MartÃnez-Triguero, Manuel Moliner, Avelino Corma Improving the catalytic performance of SAPO-18 for the methanol-to-olefins (MTO) reaction by controlling the Si distribution and crystal size published pages: 2796-2806, ISSN: 2044-4753, DOI: 10.1039/C5CY02298C	Catal. Sci. Technol. 6/8	2019-07-08
2016	Raquel MartÃnez-Franco, Cecilia Paris, Marta E. MartÃnez-Armero, Cristina MartÃnez, Manuel Moliner, Avelino Corma High-silica nanocrystalline Beta zeolites: efficient synthesis and catalytic application published pages: 102-108, ISSN: 2041-6520, DOI: 10.1039/c5sc03019f	Chemical Science 7/1	2019-07-08
2016	G. Feng, P. Cheng, W. Yan, M. Boronat, X. Li, J.-H. Su, J. Wang, Y. Li, A. Corma, R. Xu, J. Yu Accelerated crystallization of zeolites via hydroxyl free radicals published pages: 1188-1191, ISSN: 0036-8075, DOI: 10.1126/science.aaf1559	Science 351/6278	2019-07-08
2016	Tirso LÃ³pez-Ausens, Mercedes Boronat, Patricia ConcepciÃ³n, Sandra Chouzier, Sergio Mastroianni, Avelino Corma A heterogeneous mechanism for the catalytic decomposition of hydroperoxides and oxidation of alkanes over CeO2 nanoparticles: A combined theoretical and experimental study published pages: 334-345, ISSN: 0021-9517, DOI: 10.1016/j.jcat.2016.09.032	Journal of Catalysis 344	2019-07-08
2017	Lichen Liu, Fei Gao, Patricia ConcepciÃ³n, Avelino Corma A new strategy to transform mono and bimetallic non-noble metal nanoparticles into highly active and chemoselective hydrogenation catalysts published pages: 218-225, ISSN: 0021-9517, DOI: 10.1016/j.jcat.2017.03.014	Journal of Catalysis 350	2019-07-08
2016	Lichen Liu, Toshiyuki Matsushita, Patricia ConcepciÃ³n, Antonio Leyva-PÃ©rez, Avelino Corma Facile Synthesis of Surface-Clean Monodispersed CuOx Nanoparticles and Their Catalytic Properties for Oxidative Coupling of Alkynes published pages: 2211-2221, ISSN: 2155-5435, DOI: 10.1021/acscatal.5b02935	ACS Catalysis 6/4	2019-07-08
2016	Pilar GarcÃa-GarcÃa, JosÃ© MarÃa Moreno, Urbano DÃaz, Marta Bruix, Avelino Corma Organicâ€“inorganic supramolecular solid catalyst boosts organic reactions in water published pages: 10835, ISSN: 2041-1723, DOI: 10.1038/ncomms10835	Nature Communications 7	2019-07-08
2017	Nuria MartÃn, Peter N. R. VennestrÃ¸m, Joakim R. ThÃ¸gersen, Manuel Moliner, Avelino Corma Iron-Containing SSZ-39 (AEI) Zeolite: An Active and Stable High-Temperature NH 3 -SCR Catalyst published pages: 1754-1757, ISSN: 1867-3880, DOI: 10.1002/cctc.201601627	ChemCatChem 9/10	2019-07-08
2016	Z. Li, M. T. Navarro, J. MartÃnez-Triguero, J. Yu, A. Corma Synthesis of nano-SSZ-13 and its application in the reaction of methanol to olefins published pages: 5856-5863, ISSN: 2044-4753, DOI: 10.1039/C6CY00433D	Catalysis Science & Technology 6/15	2019-07-08
2017	M. RocÃo DÃaz-Rey, Cecilia Paris, Raquel MartÃnez-Franco, Manuel Moliner, Cristina MartÃnez, Avelino Corma Efficient Oligomerization of Pentene into Liquid Fuels on Nanocrystalline Beta Zeolites published pages: 6170-6178, ISSN: 2155-5435, DOI: 10.1021/acscatal.7b00817	ACS Catalysis 7/9	2019-07-08
2016	Unai De-La-Torre, BeÃ±at Pereda-Ayo, Manuel Moliner, Juan R. GonzÃ¡lez-Velasco, Avelino Corma Cu-zeolite catalysts for NO x removal by selective catalytic reduction with NH 3 and coupled to NO storage/reduction monolith in diesel engine exhaust aftertreatment systems published pages: 419-427, ISSN: 0926-3373, DOI: 10.1016/j.apcatb.2016.01.020	Applied Catalysis B: Environmental 187	2019-07-08
2017	Eva MarÃa Gallego, M. Teresa Portilla, Cecilia Paris, Alejandro LeÃ³n-Escamilla, Mercedes Boronat, Manuel Moliner, Avelino Corma â€œAb initioâ€ synthesis of zeolites for preestablished catalytic reactions published pages: 1051-1054, ISSN: 0036-8075, DOI: 10.1126/science.aal0121	Science 355/6329	2019-07-08
2017	EvaÂ M. Gallego, Cecilia Paris, M. RocÃo DÃaz-Rey, Marta E. MartÃnez-Armero, JoaquÃn MartÃnez-Triguero, Cristina MartÃnez, Manuel Moliner, Avelino Corma Simple organic structure directing agents for synthesizing nanocrystalline zeolites published pages: 8138-8149, ISSN: 2041-6520, DOI: 10.1039/c7sc02858j	Chemical Science 8/12	2019-07-08
2016	JosÃ© MarÃa Moreno, Ismael Navarro, Urbano DÃaz, Jaime Primo, Avelino Corma Single-Layered Hybrid Materials Based on 1D Associated Metalorganic Nanoribbons for Controlled Release of Pheromones published pages: 11192-11196, ISSN: 0044-8249, DOI: 10.1002/ange.201602215	Angewandte Chemie 128/37	2019-07-08
2016	Nuria MartÃn, Zhibin Li, JoaquÃn MartÃnez-Triguero, Jihong Yu, Manuel Moliner, Avelino Corma Nanocrystalline SSZ-39 zeolite as an efficient catalyst for the methanol-to-olefin (MTO) process published pages: 6072-6075, ISSN: 1359-7345, DOI: 10.1039/C5CC09719C	Chemical Communications 52/36	2019-07-08
2016	Urbano DÃaz, Avelino Corma Ordered covalent organic frameworks, COFs and PAFs. From preparation to application published pages: 85-124, ISSN: 0010-8545, DOI: 10.1016/j.ccr.2015.12.010	Coordination Chemistry Reviews 311	2019-07-08

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