INDEN

New pincer-type complexes derived from 2-indenylidene ligands

 Coordinatore CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE 

 Organization address address: Rue Michel -Ange 3
city: PARIS
postcode: 75794

contact info
Titolo: Ms.
Nome: Armelle
Cognome: Barelli
Email: send email
Telefono: +33 5 61336080
Fax: +33 5 62172901

 Nazionalità Coordinatore France [FR]
 Totale costo 165˙645 €
 EC contributo 165˙645 €
 Programma FP7-PEOPLE
Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)
 Code Call FP7-PEOPLE-2009-IEF
 Funding Scheme MC-IEF
 Anno di inizio 2011
 Periodo (anno-mese-giorno) 2011-03-01   -   2013-02-28

 Partecipanti

# participant  country  role  EC contrib. [€] 
1    CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE

 Organization address address: Rue Michel -Ange 3
city: PARIS
postcode: 75794

contact info
Titolo: Ms.
Nome: Armelle
Cognome: Barelli
Email: send email
Telefono: +33 5 61336080
Fax: +33 5 62172901

FR (PARIS) coordinator 165˙645.60

Mappa


 Word cloud

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complexes    indenyl    ligands    indenylidene    original   

 Obiettivo del progetto (Objective)

'The group of D. Bourissou has recently reported a new family of indenyl-type ligands bearing one or two coordinating side-arms. These new ligands have allowed the preparation of several metal complexes (Zr, Rh, Pd) exhibiting original coordination modes: eta-1 indenyl and 2-indenylidene. In this project, we envision to take advantage of the strong sigma-donor character of such original 2-indenylidene pincer ligands (i) to stabilise oxo and peroxo complexes of late transition metals and (ii) to explore their activity in hydroamination reactions.'

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