RDC@CATALYSIS
Structure and dynamics of catalytically active species from Residual Dipolar Couplings
| Coordinatore | TECHNISCHE UNIVERSITAET DARMSTADT
Spiacenti, non ci sono informazioni su questo coordinatore. Contattare Fabio per maggiori infomrazioni, grazie. |
| Nazionalità Coordinatore | Germany [DE] |
| Totale costo | 1˙498˙200 € |
| EC contributo | 1˙498˙200 € |
| Programma | FP7-IDEAS-ERC
Specific programme: "Ideas" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013) |
| Code Call | ERC-2010-StG_20091028 |
| Funding Scheme | ERC-SG |
| Anno di inizio | 2010 |
| Periodo (anno-mese-giorno) | 2010-11-01 - 2016-04-30 |
Partecipanti
| # | ||||
|---|---|---|---|---|
| 1 |
TECHNISCHE UNIVERSITAET DARMSTADT
Organization address
address: Karolinenplatz 5 contact info |
DE (DARMSTADT) | hostInstitution | 1˙498˙200.00 |
| 2 |
TECHNISCHE UNIVERSITAET DARMSTADT
Organization address
address: Karolinenplatz 5 contact info |
DE (DARMSTADT) | hostInstitution | 1˙498˙200.00 |
Mappa
Word cloud
Esplora la "nuvola delle parole (Word Cloud) per avere un'idea di massima del progetto.
Obiettivo del progetto (Objective)
'The main goal of chemistry and material science is to create structures, which in turn exhibit specific functions. One class of functional molecules are catalysts. Although homogeneous catalysts are widely used in synthetic chemistry, there is very limited knowledge about the relationship between their activity and their structure and especially dynamics in solution. Based on a first investigation, in which we showed that only after investigating the structural and dynamic properties of a photoswitchable organocatalyst using residual dipolar couplings (RDCs), its reactivity could be understood, it shall be demonstrated within this project, that additional and more accurate structural information on catalytically active species is accessible from RDCs leading to an improved understanding of catalysis. This will finally allow rational catalyst design. The structure in solution and information about solution dynamics is usually obtained from solution state NMR spectroscopy. In contrast to the short-range structural information obtained from the conventional NMR parameters the information obtained from the recently introduced RDCs is global, which allows the relation of non-interacting parts of compounds. RDCs furthermore contain information on dynamics of the system investigated. Especially the time scale on motional information that is accessible is intriguing. With this unique quality of structural information from RDCs in hand, precise structural models for catalytically active species can be constructed. This will certainly lead to a better understanding of catalytic processes and in the end revolutionize catalyst design.'