SEQUENCES

New Strategies for Controlling Polymer Sequences

 Coordinatore CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE 

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 Nazionalità Coordinatore France [FR]
 Totale costo 1˙200˙000 €
 EC contributo 1˙200˙000 €
 Programma FP7-IDEAS-ERC
Specific programme: "Ideas" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013)
 Code Call ERC-2010-StG_20091028
 Funding Scheme ERC-SG
 Anno di inizio 2010
 Periodo (anno-mese-giorno) 2010-11-01   -   2014-10-31

 Partecipanti

# participant  country  role  EC contrib. [€] 
1    CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE

 Organization address address: Rue Michel -Ange 3
city: PARIS
postcode: 75794

contact info
Titolo: Dr.
Nome: Jean-François André Victor
Cognome: Lutz
Email: send email
Telefono: +33 3 88 41 40 00
Fax: +33 3 88 41 40 99

FR (PARIS) hostInstitution 1˙200˙000.00
2    CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE

 Organization address address: Rue Michel -Ange 3
city: PARIS
postcode: 75794

contact info
Titolo: Mr.
Nome: Gaelle
Cognome: Bujan
Email: send email
Telefono: +33 3 88 10 63 10
Fax: +33 3 88 10 60 95

FR (PARIS) hostInstitution 1˙200˙000.00

Mappa


 Word cloud

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polymers    science    monomer    indeed    polymerization    last    polymerizations    play    sequence    sequences    synthetic    polymer    materials   

 Obiettivo del progetto (Objective)

'Sequence-controlled polymerizations play a key role in Nature. Although formed from a rather modest library of monomers, sequence-defined macromolecules such as proteins or nucleic acids are largely responsible for the complexity and diversity of the biological world. By analogy, one may predict that synthetic sequence-defined polymers could play an important role in modern applied materials science. Paradoxically, very little effort has been spent within the last decades for developing sequence-specific polymerization methods.

In this scientific context, the target of the present proposal is to develop new approaches for controlling macromolecular sequences. In particular, new possibilities for controlling comonomer sequences in standard synthetic processes such as chain-growth polymerizations (e.g. controlled radical polymerization) and step-growth polymerizations will be investigated. The strategies for controlling sequences will be principally chemical (e.g. controlled monomer insertion, organocatalysis, sequential monomer additions) but physical (e.g. confinement, transient monomer complexation) and eventually biochemical (e.g. biocatalysis) routes will be also considered.

The essence of this project is indeed highly fundamental. Indeed, the control over polymer sequences remains one of the last holy grails in polymer science. Nevertheless, on a longer term, this research may be also extremely relevant for applications. Indeed, sequence-controlled polymers are most likely the key towards new generations of functional sub-nanometric materials.'

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